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The relative energies of different phases or polymorphs of molecular solids can be small, less than a kiloJoule/mol. Reliable description of such energy differences requires high quality treatment of electron correlations, typically beyond…

Chemical Physics · Physics 2024-02-19 Khanh Ngoc Pham , Marcin Modrzejewski , Jiří Klimeš

Chemical accuracy serves as an important metric for assessing the effectiveness of the numerical method in Kohn--Sham density functional theory. It is found that to achieve chemical accuracy, not only the Kohn--Sham wavefunctions but also…

Computational Physics · Physics 2023-10-25 Yang Kuang , Yedan Shen , Guanghui Hu

A simple systematic rule, inspired by high-temperature series expansion (HTSE) results, is proposed for optimizing the expression for thermodynamic observables of ferromagnets exhibiting critical behavior at $\Tc$. This ``extended scaling''…

Statistical Mechanics · Physics 2009-11-11 I. A. Campbell , K. Hukushima , H. Takayama

We investigate a novel approach to approximate tensor-network contraction via the exact, matrix-free decomposition of full tensor-networks. We study this method as a means to eliminate the propagation of error in the approximation of…

Chemical Physics · Physics 2025-06-23 Karl Pierce

A new perturbative approach to canonical equation-of-motion coupled-cluster theory is presented using coupled-cluster perturbation theory. A second-order M{\o}ller-Plesset partitioning of the Hamiltonian is used to obtain the well known…

Chemical Physics · Physics 2015-07-09 Jason N. Byrd , Varun Rishi , Ajith Perera , Rodney J. Bartlett

We present second-order molecular cluster perturbation theory (MCPT(2)), a linear scaling methodology to calculate arbitrarily large systems with explicit calculation of individual wavefunctions in a coupled-cluster framework. This new…

The emergence of second-generation high temperature superconducting tapes has favored the development of large-scale superconductor systems. The mathematical models capable of estimating electromagnetic quantities in superconductors have…

Applied Physics · Physics 2019-03-01 Edgar Berrospe-Juarez , Victor M R Zermeno , Frederic Trillaud , Francesco Grilli

Unitary coupled cluster (UCC) theory offers a promising Hermitian alternative to conventional coupled cluster (CC) theory, but its practical implementation is hindered by the non-truncating nature of the Baker-Campbell-Hausdorff (BCH)…

Chemical Physics · Physics 2025-05-05 Justin T. Phillips , Lauren N. Koulias , Stephen H. Yuwono , A. Eugene DePrince

In quantum chemistry, one of the most important challenges is the static correlation problem when solving the electronic Schr\"odinger equation for molecules in the Born--Oppenheimer approximation. In this article, we analyze the tailored…

Numerical Analysis · Mathematics 2019-11-21 Fabian M. Faulstich , Andre Laestadius , Örs Legeza , Reinhold Schneider , Simen Kvaal

In this article, we propose a MUSCL-Hancock-type second-order scheme for the discretization of a general class of non-local conservation laws and present its convergence analysis. The main difficulty in designing a MUSCL-Hancock-type scheme…

Numerical Analysis · Mathematics 2025-06-05 Nikhil Manoj , G. D. Veerappa Gowda , Sudarshan Kumar K

The plasmon excitations in proposed single- and double-component helical liquid (HL) models are investigated within the random-phase approximation, by calculating the density-density, spin-density and spin-spin waves. The effect due to…

Materials Science · Physics 2015-06-03 O. Roslyak , Godfrey Gumbs , D. H. Huang

We present a high-accuracy procedure for electronic structure calculations of strongly correlated materials. To address limitations in current electronic structure methods, we employ density functional theory in combination with the…

Despite decades of practice, finite-size errors in many widely used electronic structure theories for periodic systems remain poorly understood. For periodic systems using a general Monkhorst-Pack grid, there has been no comprehensive and…

Computational Physics · Physics 2023-11-16 Xin Xing , Xiaoxu Li , Lin Lin

Tensor Train~(TT) decomposition is widely used in the machine learning and quantum physics communities as a popular tool to efficiently compress high-dimensional tensor data. In this paper, we propose an efficient algorithm to accelerate…

Data Structures and Algorithms · Computer Science 2024-06-07 Vivek Bharadwaj , Beheshteh T. Rakhshan , Osman Asif Malik , Guillaume Rabusseau

Spectral clustering and co-clustering are well-known techniques in data analysis, and recent work has extended spectral clustering to square, symmetric tensors and hypermatrices derived from a network. We develop a new tensor spectral…

Social and Information Networks · Computer Science 2016-03-02 Tao Wu , Austin R. Benson , David F. Gleich

The stochastic resolution of identity (sRI) approximation significantly reduces the computational scaling of CC2 from O(N^5) to O(N^3), where N is a measure of system size. However, the inherent stochastic noise, while controllable, can…

Chemical Physics · Physics 2025-10-01 Chongxiao Zhao , Wenjie Dou

We propose a sampling-based method for computing the tensor ring (TR) decomposition of a data tensor. The method uses leverage score sampled alternating least squares to fit the TR cores in an iterative fashion. By taking advantage of the…

Numerical Analysis · Mathematics 2021-07-12 Osman Asif Malik , Stephen Becker

We present a low-complexity algorithm to calculate the correlation energy of periodic systems in second-order M\o ller-Plesset perturbation theory (MP2). In contrast to previous approximation-free MP2 codes, our implementation possesses a…

Chemical Physics · Physics 2017-03-16 Tobias Schäfer , Benjamin Ramberger , Georg Kresse

Canonical Polyadic (CP) tensor decomposition is a fundamental technique for analyzing high-dimensional tensor data. While the Alternating Least Squares (ALS) algorithm is widely used for computing CP decomposition due to its simplicity and…

Methodology · Statistics 2025-05-30 Runshi Tang , Julien Chhor , Olga Klopp , Anru R. Zhang

Light hypernuclei with an $\alpha$ cluster substructure of the core nucleus are studied using an accurate cluster approach (the Hyper-THSR wave function) in combination with a density-dependent $\Lambda$ hyperon-nuclear interaction derived…

Nuclear Theory · Physics 2014-01-10 Emiko Hiyama , Yasuro Funaki , Norbert Kaiser , Wolfram Weise