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Robust heteroclinic cycles are known to change stability in resonance bifurcations, which occur when an algebraic condition on the eigenvalues of the system is satisfied and which typically result in the creation or destruction of a…

Chaotic Dynamics · Physics 2019-10-03 Vivien Kirk , Claire Postlethwaite , Alastair M. Rucklidge

We characterize completely the capacity for (nondegenerate) multistationarity of mass action reaction networks with one-dimensional stoichiometric subspace in terms of reaction structure. Specifically, we show that networks with two or more…

Dynamical Systems · Mathematics 2022-08-15 Casian Pantea , Galyna Voitiuk

Oscillatory chemical reactions are functional components in a variety of biological contexts. In chemistry, the construction and identification of even rudimentary oscillators remain elusive and lack a general framework. Using…

Molecular Networks · Quantitative Biology 2025-10-10 Alexander Blokhuis , Peter F. Stadler , Nicola Vassena

Biochemical oscillations are prevalent in living organisms. Systems with a small number of constituents cannot sustain coherent oscillations for an indefinite time because of fluctuations in the period of oscillation. We show that the…

Statistical Mechanics · Physics 2017-06-29 Andre C Barato , Udo Seifert

In most natural sciences there is currently the insight that it is necessary to bridge gaps between different processes which can be observed on different scales. This is especially true in the field of chemical reactions where the…

Molecular Networks · Quantitative Biology 2008-03-03 L. Sbano , M. Kirkilionis

The global behavior of solutions is described for the smallest chemical reaction system that exhibits a Hopf bifurcation, discovered in \cite{WH1}. This three-dimensional system is a competitive system and a monotone cyclic feedback system.…

Dynamical Systems · Mathematics 2011-09-27 Hal L. Smith

Network theory is rapidly changing our understanding of complex systems, but the relevance of topological features for the dynamic behavior of metabolic networks, food webs, production systems, information networks, or cascade failures of…

Disordered Systems and Neural Networks · Physics 2007-05-23 Dirk Helbing , Ulrich Witt , Stefan Laemmer , Thomas Brenner

We show that if a chemical reaction network (CRN) admits nondegenerate (resp., linearly stable) oscillation, and we add new reversible reactions involving new species to this CRN, then the new CRN so created also admits nondegenerate…

Dynamical Systems · Mathematics 2021-06-14 Murad Banaji

We demonstrate that chimera behavior can be observed in small networks consisting of three identical oscillators, with mutual all-to-all coupling. Three different types of chimeras, characterized by the coexistence of two coherent…

Chaotic Dynamics · Physics 2017-02-01 Yuri Maistrenko , Serhiy Brezetsky , Patrycja Jaros , Roman Levchenko , Tomasz Kapitaniak

Cellular decision-making (CDM) is a dynamic phenomenon often controlled by regulatory networks defining interactions between genes and transcription factor proteins. Traditional studies have focussed on molecular switches such as positive…

Molecular Networks · Quantitative Biology 2024-04-09 Akriti Srivastava , Mubasher Rashid

We present a systematic understanding of the rotational structure of a long-range (vibrationally highly-excited) diatomic molecule. For example, we show that depending on a quantum defect, the least-bound vibrational state of a diatomic…

Atomic Physics · Physics 2009-11-10 Bo Gao

A classical microscopic theory of rovibrational motion at high angular momenta in symmetrical non-linear molecules AB$_2$ is derived within the framework of small oscillations near the stationary states of a rotating molecule. The…

chem-ph · Physics 2009-10-28 I. N. Kozin , I. M. Pavlichenkov

The framework of mutually coupled oscillators on a network has served as a convenient tool for investigating the impact of various parameters on the dynamics of real-world systems. Compared to large networks of oscillators, minimal networks…

Adaptation and Self-Organizing Systems · Physics 2024-05-28 Andrea Elizabeth Biju , Sneha Srikanth , Krishna Manoj , Samadhan A. Pawar , R. I. Sujith

We study networks of biochemical reactions modelled by continuous-time Markov processes. Such networks typically contain many molecular species and reactions and are hard to study analytically as well as by simulation. Particularly, we are…

Molecular Networks · Quantitative Biology 2018-05-22 Daniele Cappelletti , Carsten Wiuf

For three typical sets of small reaction networks (networks with two reactions, one irreversible and one reversible reaction, or two reversible-reaction pairs), we completely answer the challenging question: what is the smallest subset of…

Molecular Networks · Quantitative Biology 2021-01-29 Xiaoxian Tang , Hao Xu

We present a systematic mathematical analysis of the qualitative steady-state response to rate perturbations in large classes of reaction networks. This includes multimolecular reactions and allows for catalysis, enzymatic reactions,…

Dynamical Systems · Mathematics 2017-11-22 Bernhard Brehm , Bernold Fiedler

A reaction network is a chemical system involving multiple reactions and chemical species. Stochastic models of such networks treat the system as a continuous time Markov chain on the number of molecules of each species with reactions as…

Probability · Mathematics 2007-05-23 Karen Ball , Thomas G. Kurtz , Lea Popovic , Greg Rempala

A codimension-three bifurcation, characterized by a pair of purely imaginary eigenvalues and a nonsemisimple double zero eigenvalue, arises in the study of a pair of weakly coupled nonlinear oscillators with Z_2 + Z_2 symmetry. The…

Analysis of PDEs · Mathematics 2016-09-07 William F. Langford , Kaijun Zhan

A 1:2 internally resonant mechanical system can undergo secondary Hopf (Neimark-Sacker) bifurcations, resulting in a quasi-periodic response when the system is subject to harmonic excitation. While these quasi-periodic orbits have been…

Chaotic Dynamics · Physics 2024-12-30 Hongming Liang , Shobhit Jain , Mingwu Li

A classification of critical behavior is provided in systems for which the renormalization group equations are control-parameter dependent. It describes phase transitions in networks with a recursive, hierarchical structure but appears to…

Statistical Mechanics · Physics 2015-05-12 Stefan Boettcher , Trent Brunson