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We study quasi-freestanding bilayer graphene on silicon carbide intercalated by calcium. The intercalation, and subsequent changes to the system, were investigated by low-energy electron diffraction, angle-resolved photoemission…

The successful application of titanium oxide-graphene hybrids in the fields of photocatalysis, photovoltaics and photodetection strongly depends on the interfacial contact between both materials. The need to provide a good coupling between…

We use first-principles calculation within the density functional theory (DFT) to explore the electronic properties on stage-1 Li- and Li+-graphite-intercalation compounds (GIC) for different concentrations, LiCx/Li+Cx with x= 6,12,18,24,32…

Materials Science · Physics 2020-06-24 Wei-Bang Li , Shih-Yang Lin , Ngoc Thanh Thuy Tran , Kuang-I Lin , Ming-Fa Lin

In recent years, conjugated polymers such as graphitic Carbon Nitride (g-C3N4) attracts major attention to the researchers for the harnessing of renewable energy and environmental remediation through photocatalytic water splitting. Its…

Materials Science · Physics 2019-02-14 Soumik Kumar Kundu , Samit Karmakar , G. S. Taki

We report a study of the temperature dependence of the surface resistance RS in the graphite intercalated compound (GIC) CaC6, where superconductivity at 11.5 K was recently discovered. Experiments are carried out using a copper…

Superconductivity · Physics 2009-11-11 G. Cifariello , E. Di Gennaro , G. Lamura , A. Andreone , N. Emery , C. Herold , J. F. Mareche , P. Lagrange

High-pressure powder x-ray diffraction experiments have revealed that sodium and gold react at room temperature and form new Na-Au intermetallic compounds under high pressure. We have identified four intermetallic phases up to 60 GPa. The…

Materials Science · Physics 2015-05-28 K. Takemura , H. Fujihisa

We present a detailed in-situ Raman analysis of stage-1 KC8, CaC6, and LiC6 graphite intercalation compounds (GIC) to unravel their intrinsic finger print. Four main components were found between 1200 cm-1 and 1700 cm-1, and each of them…

Optics · Physics 2013-10-08 J. C. Chacón-Torres , A. Y. Ganin , M. J. Rosseinsky , T. Pichler

The market quest for fast-charging, safe, long-lasting and performant batteries drives the exploration of new energy storage materials, but also promotes fundamental investigations of materials already widely used. Presently, revamped…

The authors report on synthesis and thermal properties of the electrically-conductive thermal interface materials with the hybrid graphene-metal particle fillers. The thermal conductivity of resulting composites was increased by ~500% in a…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Vivek Goyal , Alexander A. Balandin

Modeling layered intercalation compounds from first principles poses a problem, as many of their properties are determined by a subtle balance between van der Waals interactions and chemical or Madelung terms, and a good description of van…

Materials Science · Physics 2014-10-30 E. Hazrati , G. A. de Wijs , G. Brocks

We use angle-resolved photoemission spectroscopy to investigate the electronic structure of bilayer graphene at high n-doping and extreme displacement fields, created by intercalating epitaxial monolayer graphene on silicon carbide with…

In their comment Calandra \textit{et al} \cite{Calandra}, assert two points: (1) the estimate of charge transfer from Li to graphene layers in LiC$_6$ in our letter \cite{Pan2011c} is incorrect because of the three dimensional (3D)…

Superconductivity · Physics 2012-04-10 Z. -H. Pan , A. V. Fedorov , C. A. Howard , M. Ellerby , T. Valla

The effects of ion beam induced atomic mixing and subsequent thermal treatment in Si/C multilayer structures are investigated by use of the technique of grazing incidence X-ray diffraction (GIXRD) and Raman spectroscopy. The [Si (3.0 nm) /…

Materials Science · Physics 2007-05-23 Ram Prakash , S. Amirthapandian , D. M. Phase , S. K. Deshpande , R. Kesavamoorthy , K. G. M. Nair

We have measured optical absorption in mid-infrared spectral range on hydrogen intercalated epitaxial graphene grown on silicon face of SiC. We have used attenuated total reflection geometry to enhance absorption related to the surface and…

Materials Science · Physics 2018-01-08 Jan Kunc , Martin Rejhon , Pavel Hlídek

The structure of the SiC(000-1) surface, the C-face of the {0001} SiC surfaces, is studied as a function of temperature and of pressure in a gaseous environment of disilane (Si2H6). Various surface reconstructions are observed, both with…

Mesoscale and Nanoscale Physics · Physics 2019-08-28 Jun Li , Qingxiao Wang , Guowei He , Michael Widom , Lydia Nemec , Volker Blum , Moon Kim , Patrick Rinke , Randall M. Feenstra

Recently deiscovered superconductivity in YbC$_6$ and CaC$_6$ at temperatures substantially higher than previously known for intercalated graphites, raised several new questions: (1) Is the mechanism considerably different from the…

Superconductivity · Physics 2009-11-11 I. I. Mazin

Graphite is one of the most chemically inert materials. Its elementary constituent, monolayer graphene, is generally expected to inherit most of the parent material's properties including chemical inertness. Here we show that, unlike…

Recently we have reported the direct observation of two-dimensional (2D) Ca-Cl crystals on reduced graphene oxide (rGO) membranes, in which the calcium ions are only about monovalent (i.e. ~+1) and metallic rather than insulating properties…

Graphite is the thermodynamically stable form of carbon, and yet is remarkably difficult to synthesise. A key step in graphite formation is the removal of defects at high temperature ($>$2300~$^{\circ}$C) that allow graphenic fragments to…

A two-dimensional layer of oxide reveals itself as a essential element to drive the photocatalytic activity in a nanostructured hybrid material, which combines high-quality epitaxial graphene and titanium dioxide nanoparticles. In…

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