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We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

We present photo-excitation of ultra-long-range Rydberg molecules as a probe of spatial correlations in quantum gases. Rydberg molecules can be created with well-defined internuclear spacing, set by the radius of the outer lobe of the…

Feshbach resonances in ultra-cold atomic gases have led to some of the most important advances in atomic physics. They did not only enable ground breaking work in the BEC-BCS crossover regime [1], but are also widely used for the…

Atomic Physics · Physics 2018-07-04 Oliver Thomas , Carsten Lippe , Tanita Eichert , Herwig Ott

We propose an improved photoassociation scheme to produce ultracold molecules in their vibronic ground state for the generic case where non-adiabatic effects facilitating transfer to deeply bound levels are absent. Formation of molecules is…

Atomic Physics · Physics 2008-10-28 Christiane P. Koch , Robert Moszynski

We have produced ultracold heteronuclear YbRb$^*$ molecules in a combined magneto-optical trap by photoassociation. The formation of electronically excited molecules close to the dissociation limit was observed by trap loss spectroscopy in…

Quantum Physics · Physics 2016-01-20 N. Nemitz , F. Baumer , F. Münchow , S. Tassy , A. Görlitz

We present a comprehensive study of the diverse properties of heteronuclear Rydberg molecules, placing a special emphasis on those composed of the light alkali atoms, Li, Na, and K. Electron-atom scattering phase shifts, which determine the…

Atomic Physics · Physics 2019-02-13 Matthew T. Eiles

Vibrational properties of ultralong Rydberg Cs$_2$ molecules are investigated on corresponding potential curves obtained by perturbation theory. The Rydberg Cs$_2$ molecules are associated by a Rydberg Cs($nS/nP$) atom $(n=30-70)$ and a…

Atomic Physics · Physics 2016-09-07 Xiaomeng Liu , Yonggang Yang , Jianming Zhao , Liantuan Xiao , Suotang Jia

We use molecules to couple light into and out of microscale plasmonic waveguides. Energy transfer, mediated by surface plasmons, from donor molecules to acceptor molecules over ten micrometer distances is demonstrated. Also surface plasmon…

We propose a Rydberg molecule dressing scheme to create strong and long-ranged interactions at selective distances. This is achieved through laser coupling ground-state atoms off-resonantly to an attractive molecular curve of two…

Quantum Physics · Physics 2022-06-16 Huaizhi Wu , Xin-Yu Lin , Zong-Xing Ding , Shi-Biao Zheng , Igor Lesanovsky , Weibin Li

The optomechanical character of molecules was discovered by Raman about one century ago. Today, molecules are promising contenders for high-performance quantum optomechanical platforms because their small size and large energy-level…

Quantum Physics · Physics 2021-09-22 Burak Gurlek , Vahid Sandoghdar , Diego Martin-Cano

We propose an implementation of a universal quantum gate between pairs of spatially separated atoms in a microwave cavity at finite temperature. The gate results from reversible laser excitation of Rydberg states of atoms interacting with…

Quantum Physics · Physics 2015-09-24 Lőrinc Sárkány , József Fortágh , David Petrosyan

We study the effect of resonances associated with complex molecular interaction of Rydberg atoms on Rydberg blockade. We show that densely-spaced molecular potentials between doubly-excited atomic pairs become unavoidably resonant with the…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , Péter Kómár , Turker Topcu , Ronen M. Kroeze , Mikhail D. Lukin

Theory of long-range interactions between an atom in its ground S state and a linear molecule in a degenerate state with a non-zero projection of the electronic orbital angular momentum is presented. It is shown how the long-range…

Chemical Physics · Physics 2015-05-20 Wojciech Skomorowski , Robert Moszynski

The coupling of an isolated quantum state to a continuum is typically associated with decoherence and decreased lifetime. Here, we demonstrate that Rydberg macrodimers, weakly bound pairs of Rydberg atoms, can overcome this dissipative…

Controlling molecular binding at the level of single atoms is one of the holy grails of quantum chemistry. Rydberg macrodimers -- bound states between highly excited Rydberg atoms -- provide a novel perspective in this direction. Resulting…

Atomic Physics · Physics 2023-06-14 Simon Hollerith , Johannes Zeiher

We investigate the dynamics of Rydberg electrons excited from the ground state of ultracold atoms trapped in an optical lattice. We first consider a lattice comprising an array of double-well potentials, where each double well is occupied…

Other Condensed Matter · Physics 2009-11-13 B. Vaucher , S. J. Thwaite , D. Jaksch

Atoms with a highly excited electron, called Rydberg atoms, can form unusual types of molecular bonds. The bond differs from the well known ionic and covalent bonds not only by its binding mechanism, but also by its bond length ranging up…

Atomic Physics · Physics 2022-05-20 N. Zuber , V. S. V. Anasuri , M. Berngruber , Y. -Q. Zou , F. Meinert , R. Löw , T. Pfau

Doubly polar molecules, possessing an electric dipole moment and a magnetic dipole moment, can strongly couple to both an external electric field and a magnetic field, providing unique opportunities to exert full control of the system…

Atomic Physics · Physics 2019-11-06 Hui Li , Goulven Quéméner , Jean-François Wyart , Olivier Dulieu , Maxence Lepers

Rydberg molecules, Rydberg-atom or Rydberg-molecule, are an essential ingredient of cold molecular sciences. However, due to the richness of Rydberg-neutral interactions, new kinds of Rydberg molecules and binding mechanisms are still to be…

Atomic Physics · Physics 2025-02-18 Mateo Londoño , Vanessa C. Olaya-Agudelo , Felipe Herrera , Jesús Pérez-Ríos

We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…

Atomic Physics · Physics 2026-03-17 Felix Giering , Rohan Srikumar , Peter Schmelcher