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Related papers: Engineering long-range molecular potentials by ext…

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We report the creation of ultralong-range Sr$_2$ molecules comprising one ground-state $5s^2$ $^1S_0$ atom and one atom in a $5sns$ $^3S_1$ Rydberg state for $n$ ranging from 29 to 36. Molecules are created in a trapped ultracold atomic gas…

We show the existence of ultra-long-range giant dipole molecules formed by a neutral alkali ground state atom that is bound to the decentered electronic wave function of a giant dipole atom. The adiabatic potential surfaces emerging from…

Atomic Physics · Physics 2012-03-14 Markus Kurz , Michael Mayle , Peter Schmelcher

The formation of ultralong-range Rydberg molecules is a result of the attractive interaction between Rydberg electron and polarizable ground state atom in an ultracold gas. In the nondegenerate case the backaction of the polarizable atom on…

Atomic Physics · Physics 2015-07-10 A. Gaj , A. T. Krupp , P. Ilzhöfer , R. Löw , S. Hofferberth , T. Pfau

We explore the feasibility of optically forming long-range tetratomic and larger polyatomic molecules in their ground electronic state from ultracold pairs of polar molecules aligned by external fields. Depending on the relative orientation…

Atomic Physics · Physics 2021-06-16 Marko Gacesa , Jason N. Byrd , Jonathan Smucker , John A. Montgomery, , Robin Côté

We investigate the quantum dynamics of ultra-long-range trilobite molecules exposed to homogeneous electric fields. A trilobite molecule consists of a Rydberg atom and a ground-state atom, which is trapped at large internuclear distances in…

Atomic Physics · Physics 2021-02-24 Frederic Hummel , Kevin Keiler , Peter Schmelcher

Using the multipolar expansion of electrostatic and magnetostatic potential energies, we characterize the long-range interactions between two weakly-bound diatomic molecules, taking as an example the paramagnetic Er$_2$ Feshbach molecules…

Atomic Physics · Physics 2017-04-11 Maxence Lepers , Goulven Quéméner , Eliane Luc-Koenig , Olivier Dulieu

The interaction between a Rydberg electron and a neutral atom situated inside its extended orbit is described via contact interactions for each atom-electron scattering channel. In ultracold environments, these interactions lead to…

Atomic Physics · Physics 2017-05-10 Matthew T Eiles , Chris H Greene

The term "long-range interactions" refers to electrostatic and magnetostatic potential energies between atoms and molecules with mutual distances ranging from a few tens to a few hundreds Bohr radii. The involved energies are much smaller…

Quantum Physics · Physics 2017-04-11 Maxence Lepers , Olivier Dulieu

Ultralong-range Rydberg molecules provide an exciting testbed for molecular physics at exaggerated scales. In the so-called trilobite and butterfly Rydberg molecules, the Born-Oppenheimer approximation can fail due to strong non-adiabatic…

Atomic Physics · Physics 2023-02-23 Frederic Hummel , Peter Schmelcher , Matthew T. Eiles

The adiabatic potential energy curves of Rb$_2$ in the long-range Rydberg electronic states are calculated using the two-electron \textit{R}-matrix method [M. Tarana, R. \v{C}ur\'{i}k, Phys. Rev. A \textbf{93}, 012515 (2016)] for the…

Atomic Physics · Physics 2020-12-03 Michal Tarana

We investigate the structure and features of an ultralong-range triatomic Rydberg molecule formed by a Rb Rydberg atom and a KRb diatomic molecule. In our numerical description, we perform a realistic treatment of the internal rotational…

We explore the electronic structure and rovibrational properties of an ultralong-range triatomic Rydberg molecule formed by a Rydberg atom and a ground state heteronuclear diatomic molecule. We focus here on interaction of Rb($27s$) Rydberg…

Atomic Physics · Physics 2015-06-22 Rosario González-Férez , H. R. Sadeghpour , Peter Schmelcher

Long-range Rydberg molecules are typically bound in wells formed in their oscillatory potential energy curves. In alkaline Rydberg molecules, bound vibrational states exist even when these potential wells are disrupted by level repulsion…

Atomic Physics · Physics 2024-08-28 Aileen A. T. Durst , Milena Simić , Neethu Abraham , Matthew T. Eiles

We discuss techniques to engineer effective long-range interactions between polar molecules using external static electric and microwave fields. We consider a setup where molecules are trapped in a two-dimensional pancake geometry by a…

Quantum Physics · Physics 2009-11-13 A. Micheli , G. Pupillo , H. P. Büchler , P. Zoller

In this article we extend the theory of ultra-long-range giant dipole molecules, formed by an atom in a giant dipole state and a ground-state alkali atom, by angular-momentum couplings known from recent works on Rydberg molecules. In…

Atomic Physics · Physics 2018-02-14 Thomas Stielow , Stefan Scheel , Markus Kurz

We present an overview of our recent investigations of long-range interactions in an ultracold Cs Rydberg gas. These interactions are studied by high-resolution photoassociation spectroscopy, using excitation close to one-photon transitions…

Atomic Physics · Physics 2016-07-15 Heiner Saßmannshausen , Johannes Deiglmayr , Frédéric Merkt

We have calculated long-range molecular potentials of the $0_g^{+}$, $0_u^{-}$ and $1_u$ symmetries between highly-excited rubidium atoms. Strong $np+np$ potentials characterized by these symmetries are important in describing…

Atomic Physics · Physics 2009-11-13 J. Stanojevic , R. Côté , D. Tong , E. E. Eyler , P. L. Gould

We describe a technique that enables a strong, coherent coupling between isolated neutral atoms and mesoscopic conductors. The coupling is achieved by exciting atoms trapped above the surface of a superconducting transmission line into…

Quantum Physics · Physics 2009-11-10 Anders S. Sorensen , Caspar H. van der Wal , Lilian Childress , Mikhail D. Lukin

We predict the existence of a class of ultracold giant molecules formed from trapped ultracold Rydberg atoms and polar molecules. The interaction which leads to the formation of such molecules is the anisotropic charge-dipole interaction…

Atomic Physics · Physics 2015-05-18 Seth T. Rittenhouse , H. R. Sadeghpour

We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…