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Recent advances in large-scale synthesis of graphene and other 2D materials have underscored the importance of local defects such as dislocations and grain boundaries (GBs), and especially their tendency to alter the electronic properties…

Grain boundaries (GBs) strongly influence thermal transport in crystalline solids by disrupting lattice periodicity and scattering phonons. Due to the atomic-level disorder and structural complexity, a fundamental understanding of how…

Understanding the impact of lattice imperfections on nanoscale thermal transport is crucial for diverse applications ranging from thermal management to energy conversion. Grain boundaries (GBs) are ubiquitous defects in polycrystalline…

Grain boundaries (GBs) are a prolific microstructural feature that dominates the functionality of a wide class of materials. The change in functionality at a GB is a direct result of unique local atomic arrangements, different from those in…

Since it is now possible to record vibrational spectra at nanometer scales in the electron microscope it is of interest to explore whether defects such as dislocations or grain boundaries will result in measurable changes of the spectra.…

Materials Science · Physics 2022-06-22 Peter Rez , Tara Boland , Christian Elsässer , Arunima Singh

Atomically resolved electron energy-loss spectroscopy experiments are commonplace in modern aberrationcorrected transmission electron microscopes. Energy resolution has also been increasing steadily with the continuous improvement of…

Materials Science · Physics 2014-03-10 R. Egoavil , N. Gauquelin , G. T. Martinez , S. Van Aert , G. Van Tendeloo , J. Verbeeck

In this study, sub-angstrom spatial resolution is achieved in mapping and spectroscopy of atoms and bonds within polygonal grain boundaries (GBs) of graphite using Scanning Tunneling Microscopy (STM). Robust van Hove singularities (VHS) are…

Mesoscale and Nanoscale Physics · Physics 2023-11-29 Nirjhar Sarkar , Prabhakar R. Bandaru , Robert C. Dynes

Grain boundaries (GBs) govern critical properties of polycrystals. Although significant advancements have been made in characterizing minimum energy GBs, real GBs are seldom found in such states, making it challenging to establish…

Materials Science · Physics 2025-01-22 Avanish Mishra , Sumit A. Suresh , Saryu J. Fensin , Nithin Mathew , Edward M. Kober

The electronic, optical, and magnetic properties of quantum solids are determined by their low-energy (< 100 meV) many-body excitations. Dynamical characterization and manipulation of such excitations relies on tools that combine…

Mesoscale and Nanoscale Physics · Physics 2018-03-28 E. Pomarico , I. Madan , G. Berruto , G. M. Vanacore , K. Wang , I. Kaminer , F. J. García de Abajo , F. Carbone

An experimental study of optical phonon modes, both normal and interface (IF) phonons, in bilayer strain-coupled InAs/GaAs_(1-x)Sb_x quantum dot heterostructures has been presented by means of low-temperature polarized Raman scattering. The…

Mesoscale and Nanoscale Physics · Physics 2024-09-17 Priyesh Kumar , Sudip Kumar Deb , Subhananda Chakrabarti , Jhuma Saha

Interfaces impede heat flow in micro/nanostructured systems. Conventional theories for interfacial thermal transport were derived based on bulk phonon properties of the materials making up the interface without explicitly considering the…

The breakdown of translational symmetry at heterointerfaces leads to the emergence of new phonon modes localized near the interface. These interface phonons play an essential role in thermal/electrical transport properties in devices…

Materials Science · Physics 2022-01-05 Ruishi Qi , Ruochen Shi , Yuanwei Sun , Yuehui Li , Mei Wu , Ning Li , Jinlong Du , Kaihui Liu , Chunlin Chen , Dapeng Yu , En-Ge Wang , Peng Gao

High energy electron beams can now be routinely focused to 1-2 {\AA} and offer the ability to obtain vibrational information from materials using monochromated electron energy-loss spectroscopy (EELS) in a scanning transmission electron…

Materials Science · Physics 2021-07-13 Kartik Venkatraman , Peter A. Crozier

The grain boundaries (GBs) of a graphene surface were extensively studied because GBs with specific defect configurations result in the formation of new curved structures, which can be treated as new carbon allotropes. We studied the…

Materials Science · Physics 2018-01-17 Jun Ma , Xiaying Li , Longjing Yin , Wenxiao Wang , Qi Sun , Yu Yang , Ping Zhang , Jiacai Nie , Changmin Xiong , Ruifen Dou

In spite of their importance for understanding phonon transport phenomena in thin films and polycrystalline solids, the effects of boundary roughness scattering on phonon specularity and coherence are poorly understood because there is no…

Mesoscale and Nanoscale Physics · Physics 2020-05-08 Zhun-Yong Ong , Georg Schusteritsch , Chris J. Pickard

Inspired by concepts developed for fermionic systems in the framework of condensed matter physics, topology and topological states are recently being explored also in bosonic systems. The possibility of engineering systems with…

Similar to electron waves, the phonon states in semiconductors can undergo changes induced by external boundaries. Modification of acoustic phonon spectrum in structures with periodically modulated elastic constant or mass density -…

Near the band edge of photonic crystal waveguides, localized modes appear due to disorder. We demonstrate a new method to elucidate spatial profile of the localized modes in such systems using precise local tuning. Using deconvolution with…

Optics · Physics 2016-11-03 J. Lian , S. Sokolov , E. Yüce , S. Combrié , A. De Rossi , A. P. Mosk , .

In silicon, lattice thermal conductivity plays an important role in a wide range of applications such as thermoelectric and microelectronic devices. Grain boundaries (GBs) in polycrystalline silicon can significantly reduce lattice thermal…

Computational Physics · Physics 2021-05-26 Susumu Fujii , Atsuto Seko

Direct measurement of local phonon dispersion in individual nanostructures can greatly advance our understanding of their electrical, thermal, and mechanical properties. However, such experimental measurements require extremely high…

Mesoscale and Nanoscale Physics · Physics 2021-03-02 Ruishi Qi , Ning Li , Jinlong Du , Ruochen Shi , Yang Huang , Xiaoxia Yang , Lei Liu , Zhi Xu , Qing Dai , Dapeng Yu , Peng Gao
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