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A deep understanding of molecular photo-transformations is challenging because of the complex interaction between the configurations of electrons and nuclei. An initial optical excitation dissipates energy into electronic and structural…

Hydrogen-release by photoexcitation, excited-state- hydrogen-transfer (ESHT), is one of the important photo- chemical processes that occur in aromatic acids and is responsible for photoprotection of biomolecules. The mecha- nism is…

In 2003 we have measured the absolute frequency of the $(1S, F=1, m_F=\pm 1) \leftrightarrow (2S, F'=1, m_F'=\pm 1)$ two-photon transition in atomic hydrogen. We observed a variation of $(-29\pm 57)$ Hz over a 44 months interval separating…

We present experimental results for dissociative electron attachment to acetylene near the 3 eV $^2\Pi_g$ resonance. In particular, we use an ion-momentum imaging technique to investigate the dissociation channel leading to C$_2$H$^-$…

Chemical Physics · Physics 2014-10-29 M. Fogle , D. J. Haxton , A. L. Landers , A. E. Orel , T. N. Rescigno

The comprehension of nonadiabatic dynamics in polyatomic systems relies heavily on the simultaneous advancements in theoretical and experimental domains. The gas-phase electron diffraction (GUED) technique has attracted widespread attention…

Chemical Physics · Physics 2024-02-15 Jiawei Peng , Hong Liu , Zhenggang Lan

The boundary problem of linear classical optics about the interaction of electromagnetic radiation with a thin dielectric film has been solved under explicit consideration of its discrete structure. The main attention has been paid to the…

Optics · Physics 2009-11-07 S. V. Sukhov , K. V. Krutitsky

Streaking of photoelectrons has long been used for the temporal characterization of attosecond extreme ultraviolet pulses. When the time-resolved photoelectrons originate from a coherent superposition of electronic states, they carry an…

Chemical Physics · Physics 2016-07-27 Markus Kowalewski , Kochise Bennett , Jérémy R. Rouxel , Shaul Mukamel

A low pressure discharge sustained in molecular hydrogen with help of the electron cyclotron resonance heating at a frequency of 2.45 GHz is simulated using a fully electromagnetic implicit charge- and energy-conserving…

Abrupt time variations of the properties of optical materials have been at the center of intense research efforts in recent years, with the prospect of enabling extreme wave transformations and of leveraging time as a degree of freedom for…

The epitaxial growth of complex oxide thin films provide three avenues to generate unique properties: the ability to influence the 3-dimensional structure of the film, the presence of a surface, and the generation of an interface. In all…

Materials Science · Physics 2010-05-31 N. J. C. Ingle , A. Yuskauskas , R. Wicks , M. Paul , S. Leung

We present a density-functional theory based molecular-dynamics study of the structural, dynamical, and electronic properties of liquid methanol under ambient conditions. The calculated radial distribution functions involving the oxygen and…

Chemical Physics · Physics 2009-11-07 Jan-Willem Handgraaf , Titus S. van Erp , Evert Jan Meijer

The ultrafast time-dependence of the energy absorption of covalent solids upon excitation with femtosecond laser pulses is theoretically analyzed. We use a microscopic theory to describe laser induced structural changes and their influence…

Materials Science · Physics 2007-05-23 H. O. Jeschke , M. E. Garcia , K. H. Bennemann

We construct an electron optical system to investigate Bragg diffraction (the crystal lattice plane, $10^{-2}$-$10^{-3}$ rad) with the objective lens turned off by adjusting the current in the intermediate lenses. A crossover was located on…

Materials Science · Physics 2019-11-06 Hiroshi Nakajima , Atsuhiro Kotani , Ken Harada , Shigeo Mori

The Fraunhofer diffraction of quantum particles from materials with sharp electron-density edges or symmetric bond structures is ubiquitous. In contrast, diffraction from atoms with characteristic asymptotically-diffused electron…

We introduce new classes of hydrodynamic theories inspired by the recently discovered fracton phases of quantum matter. Fracton phases are characterized by elementary excitations (fractons) with restricted mobility. The hydrodynamic…

Strongly Correlated Electrons · Physics 2020-07-29 Andrey Gromov , Andrew Lucas , Rahul M. Nandkishore

We have explored the light induced dynamics in superfluid helium nanodroplets with wide-angle scattering in a pump-probe measurement scheme. The droplets are doped with xenon atoms to facilitate the ignition of a nanoplasma through…

We study the ultrafast structural dynamics, in response to electronic excitations, in heterostructures composed of Au$_{923}$ nanoclusters on thin-film substrates with the use of femtosecond electron diffraction. Various forms of atomic…

Using a new technique to directly detect current induced on a nearby electrode, we measure plasma oscillations in ultracold plasmas, which are influenced by the inhomogeneous and time-varying density and changing neutrality. Electronic…

Plasma Physics · Physics 2012-02-10 K. A. Twedt , S. L. Rolston

Hydrogen bonding is essential in electron transfer processes at water-electrode interfaces. We study the impact of the H-bonding of water as a solvent molecule on real-time electron transfer dynamics across a Cs+-Cu(111) ion-metal interface…

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