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We investigate photoisomerization (PI), the shape change of a molecule upon photoabsorption, in a dissipative environment using a simple spin-boson model. We identify two classes of environment depending on whether it "entangles" with the…

Materials Science · Physics 2007-05-23 Chang-Qin Wu , Jian-Xin Li , Dung-Hai Lee

We consider here the bremsstrahlung emission of photons at low and intermediate energies $ E_{lab}\le 1000 MeV/u$ of the projectile. and derive expressions more general than previous results obtained by Neuhauser which were limited to the…

High Energy Physics - Phenomenology · Physics 2010-11-01 L. V. Razumov , R. M. Weiner

We study theoretically the photoabsorption spectra of an attosecond XUV pulse by a laserdressed atomic system. A weak XUV excites an autoionizing state which is strongly coupled to another autoionizing state by a laser. The theory was…

Atomic Physics · Physics 2012-05-23 Wei-Chun Chu , C. D. Lin

Two-photon excitation spectroscopy is a nonlinear technique that has gained rapidly in interest and significance for studying the complex energy-level structure and transition probabilities of materials. While the conventional spectroscopy…

Quantum Physics · Physics 2022-11-23 Yuanyuan Chen , Roberto de J. León-Montiel , Lixiang Chen

Transition metals with their densely confined and strongly coupled valence electrons are key constituents of many materials with unconventional properties, such as high-Tc superconductors, Mott insulators and transition-metal…

Atomic Physics · Physics 2020-01-08 M. Volkov , S. A. Sato , F. Schlaepfer , L. Kasmi , N. Hartmann , M. Lucchini , L. Gallmann , A. Rubio , U. Keller

The route towards manipulation of the optoelectronic properties of matter beyond the current limits of electronics starts from a comprehensive study of the ultrafast dynamics triggered by interaction with light. Among them, a fundamental…

We study ionization of atoms in strong orthogonal two-color ($\omega,2\omega$) (OTC) laser fields numerically and analytically. The calculated photoelectron momentum distribution shows two typical structures: a rectangular-like structure…

Atomic Physics · Physics 2023-06-21 J. N. Wu , J. Y. Che , F. B. Zhang , C. Chen , W. Y. Li , G. G. Xin , Y. J. Chen

We investigate dynamics of atomic and molecular systems exposed to intense, shaped chaotic fields and a weak femtosecond laser pulse theoretically. As a prototype example, the photoionization of a hydrogen atom is considered in detail. The…

Quantum Physics · Physics 2015-05-18 Kamal P Singh , Jan M Rost

Autoionization, which results from the interference between direct photoionization and photoexcitation to a discrete state decaying to the continuum by configuration interaction, is a well known example of the important role of electron…

Photoelectron angular distributions of the two-photon ionization of neutral atoms are theoretically investigated. Numerical calculations of two-photon ionization cross sections and asymmetry parameters are carried out within the…

Atomic Physics · Physics 2020-10-22 J. Hofbrucker , L. Eiri , A. V. Volotka , S. Fritzsche

We study ultrafast ionization dynamics using orthogonally polarized two-color (OTC) laser pulses involving the resonant "first plus second" ($\omega+2\omega$) scheme. The scheme is illustrated by numerical simulations of the time-dependent…

Atomic Physics · Physics 2019-12-16 Hicham Agueny

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

Chemical Physics · Physics 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

The coherence of light from independent ensembles of elementary atomic emitters plays a paramount role in diverse areas of modern optics. We demonstrate the interference of photons scattered from independent ensembles of warm atoms in…

Quantum Physics · Physics 2026-02-19 Jaromír Mika , Stuti Joshi , Lukáš Lachman , Robin Kaiser , Lukáš Slodička

The dissociation of excited electron-hole pairs is a microscopic process that is fundamental to the performance of photovoltaic systems. For this process to be successful, the oppositely charged electron and hole must overcome an…

Mesoscale and Nanoscale Physics · Physics 2017-08-14 Liang Shi , Chee Kong Lee , Adam P. Willard

Quantum coherence plays a fundamental role in the study and control of ultrafast dynamics in matter. In the case of photoionization, entanglement of the photoelectron with the ion is a well known source of decoherence when only one of the…

Two-photon excitation is an attractive means for controlling chemistry in both space and time. Isoenergetic one- and two-photon excitations (OPE and TPE) in non-centrosymmetric molecules are often assumed to reach the same excited state…

We study the optical response of a binary system of identical atoms in which one of them is excited by an incoherent pump. %We study the properties of photon scattering, absorption and emission, together with the time evolution of the…

Quantum Physics · Physics 2025-06-27 L. Acevedo , J. Sánchez-Cánovas , M. Donaire

We calculate the photoionization cross-section of a molecular endohedral. We limit ourselves to two-atomic molecules. The consideration is much more complex than for atomic endohedrals because the system even for almost spherical fullerenes…

Atomic and Molecular Clusters · Physics 2019-09-04 M. Ya. Amusia , L. V. Chernysheva , S. K. Semenov

Molecular hydrogen ions are of metrological relevance due to the possibility of precise theoretical evaluation of their spectrum and of external-field-induced shifts. In homonuclear molecular ions the electric dipole $E1$ transitions are…

Atomic Physics · Physics 2021-01-20 P. Danev , D. Bakalov , V. I. Korobov , S. Schiller

We theoretically study saturation effects induced by an external static electric field on photoassociation (PA) of a heteronuclear atom pair. A static electric field influences scattering wave-function of two heteronuclear atoms as…

Atomic Physics · Physics 2012-06-06 Debashree Chakraborty , Bimalendu Deb