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Although they were first synthesized in chemistry laboratories nearly fifty years ago, the physical properties of the metals PdCoO2, PtCoO2 and PdCrO2 have only more recently been studied in detail. The delafossite structure contains…

Strongly Correlated Electrons · Physics 2017-01-25 Andrew P Mackenzie

An electronic solid with itinerant carriers and localized magnetic moments represents a paradigmatic strongly correlated system. The electrical transport properties associated with the itinerant carriers, as they scatter off these local…

Strongly Correlated Electrons · Physics 2023-09-04 J. F. Mendez-Valderrama , Evyatar Tulipman , Elina Zhakina , Andrew P. Mackenzie , Erez Berg , Debanjan Chowdhury

Strange metal behavior appears across a variety of condensed matter settings and beyond, and achieving a universal understanding is an exciting prospect. The beyond-Landau quantum criticality of Kondo destruction has had considerable…

Strongly Correlated Electrons · Physics 2023-01-03 Xinwei Li , Junichiro Kono , Qimiao Si , Silke Paschen

Doping of a Mott insulator gives rise to a wide variety of exotic emergent states, from high-temperature superconductivity to charge, spin, and orbital orders. The physics underpinning their evolution is, however, poorly understood. A major…

There has been a long-standing debate on the coexistence between itinerant electrons and localized spins in the PdCrO$_2$ delafossite. By means of the charge self-consistent combination of density functional theory and dynamical mean-field…

Strongly Correlated Electrons · Physics 2018-08-21 Frank Lechermann

A variety of "strange metals" exhibit resistivity that decreases linearly with temperature as $T\rightarrow 0$, in contrast with conventional metals where resistivity decreases as $T^2$. This $T$-linear resistivity has been attributed to…

Strongly Correlated Electrons · Physics 2021-08-16 G. Grissonnanche , Y. Fang , A. Legros , S. Verret , F. Laliberté , C. Collignon , J. Zhou , D. Graf , P. Goddard , L. Taillefer , B. J. Ramshaw

The prototypical delafossite metal PdCoO$_2$ has been the subject of intense interest for hosting exotic transport properties. Using first-principles transport calculations and theoretical modeling, we reveal that the high electrical…

Materials Science · Physics 2024-12-17 Xiaoping Yao , Yechen Xun , Ziye Zhu , Shu Zhao , Wenbin Li

Delafossite PdCrO$_2$ is an intriguing material which displays nearly-free electron and Mott insulating behaviour in different layers. Both angle-resolved photoemission spectroscopy (ARPES) and Compton scattering measurements have…

Strongly Correlated Electrons · Physics 2023-01-06 Alyn D. N. James , David Billington , Stephen B. Dugdale

The delafossite metals PdCoO$_{2}$, PtCoO$_{2}$ and PdCrO$_{2}$ are among the highest conductivity materials known, with low temperature mean free paths of tens of microns in the best as-grown single crystals. A key question is whether…

Here we report a combined study of low-temperature scanning tunneling microscopy (STM) and dynamical mean-field theory (DMFT) on PdCrO$_2$, a delafossite metal with an antiferromagnetic order below ~37.5 K. First, on the CrO$_2$-terminated…

Strongly Correlated Electrons · Physics 2023-09-19 Chenhaoping Wen , Tian Qin , Xuefeng Zhang , Mingxin Zhang , Shiwei Shen , Zhongzheng Yang , Yanpeng Qi , Gang Li , Shichao Yan

Strange metal behavior refers to a linear temperature dependence of the electrical resistivity at temperatures below the Mott-Ioffe-Regel limit. It is seen in numerous strongly correlated electron systems, from the heavy fermion compounds,…

Strongly Correlated Electrons · Physics 2022-05-24 Mathieu Taupin , Silke Paschen

The delafossite series of layered oxides include some of the highest conductivity metals ever discovered. Of these, PtCoO2, with a room temperature resistivity of 1.8 microOhmcm for in-plane transport, is the most conducting of all. The…

Strongly Correlated Electrons · Physics 2020-05-06 F. Arnold , M. Naumann , H. Rosner , N. Kikugawa , D. Graf , L. Balicas , T. Terashima , S. Uji , H. Takatsu , S. Khim , A. P. Mackenzie , E. Hassinger

The origin of the quasi two-dimensional behavior of PdCoO2 and PtCoO2 is investigated by means of electronic structure calculations. They are performed using density functional theory in the generalized gradient approximation as well as the…

Materials Science · Physics 2008-03-18 Volker Eyert , Raymond Fresard , Antoine Maignan

High-quality single crystals of KCo$_2$As$_2$ with the body-centered tetragonal ThCr$_2$Si$_2$ structure were grown using KAs self flux. Structural, magnetic, thermal, and electrical transport were investigated. No clear evidence for any…

Strongly Correlated Electrons · Physics 2022-01-26 Abhishek Pandey , Y. Liu , Saroj L. Samal , Yevhen Kushnirenko , A. Kaminski , D. J. Singh , D. C. Johnston

High $T_c$ cuprate strange metals are noted for a DC-resistivity that scales linearly with $T$ from the onset of superconductivity to the crystal melting temperature, indicative of a Planckian dissipation life time $\tau_{\hbar}\simeq \hbar…

Understanding the role of electron correlations in strong spin-orbit transition-metal oxides is key to the realisation of numerous exotic phases including spin-orbit assisted Mott insulators, correlated topological solids, and prospective…

We present de Haas-van Alphen and resistivity data on single crystals of the delafossite PdCoO2. At 295 K we measure an in-plane resistivity of 2.6 \mu{\Omega}-cm, making PdCoO2 the most conductive oxide known. The low-temperature in-plane…

Strongly Correlated Electrons · Physics 2015-06-05 Clifford W. Hicks , Alexandra S. Gibbs , Andrew P. Mackenzie , Hiroshi Takatsu , Yoshiteru Maeno , Edward A. Yelland

The natural-heterostructure concept realized in delafossites highlights these layered oxides. While metallic, band- or Mott-insulating character may be associated with individual layers, inter-layer coupling still plays a decisive role. We…

Strongly Correlated Electrons · Physics 2021-07-30 Frank Lechermann

A model of magnetic interaction of CrO$_2$ and Pd hexagonal layers in PdCrO$_2$ is proposed. Since Cr-O-Pd bridges do not provide an interlayer magnetic coupling in case of a 120$^0$ magnetic ordering, a direct exchange interaction between…

Strongly Correlated Electrons · Physics 2020-06-11 Yu. B. Kudasov

In various "strange" metals, electrons undergo Planckian dissipation, a strong and anomalous scattering that grows linearly with temperature, in contrast to the quadratic temperature dependence expected from the standard theory of metals.…

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