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The existence of heterogeneity in the dynamics of supercooled liquids is believed to be one of the hallmarks of the glass transition. Intense research has been carried out in the past to understand the origin of this heterogeneity in…

Soft Condensed Matter · Physics 2020-07-01 Indrajit Tah , Smarajit Karmakar

We examined dynamic heterogeneity in a model tetrahedral network glass-forming liquid. We used four-point correlation functions to extract dynamic correlation lengths xi_4^a(t) and susceptibilities chi_4^a(t) corresponding to structural…

Soft Condensed Matter · Physics 2016-01-20 Hannah Staley , Elijah Flenner , Grzegorz Szamel

Clusters of fast and slow correlated particles, identified as dynamical heterogeneities (DHs), con-stitute a central aspect of glassy dynamics. A key ingredient of the glass transition scenario is asignificant increase of the cluster size…

Soft Condensed Matter · Physics 2015-09-11 Rémy Colin , Ahmed Alsayed , Cyprien Gay , Bérengère Abou

Kinetically constrained spin models are schematic coarse-grained models for the glass transition which represent an efficient theoretical tool to study detailed spatio-temporal aspects of dynamic heterogeneity in supercooled liquids. Here,…

Statistical Mechanics · Physics 2009-11-11 Sébastien Léonard , Ludovic Berthier

We perform molecular dynamics simulations of a model glass-forming liquid to measure the size of kinetic heterogeneities, using a dynamic susceptibility $\chi_{\rm ss}(a, t)$ that quantifies the number of particles whose dynamics are…

Soft Condensed Matter · Physics 2014-04-04 T. K. Haxton , A. J. Liu

In two recent interesting letters evidence was presented for the existence of a growing dynamic correlation length when we approach the glass transition from the liquid phase (a similar divergence is present also in the off-equilibrium…

Statistical Mechanics · Physics 2007-05-23 S. Franz , G. Parisi

Dynamic heterogeneity in glass-formers has been related to their static structure using the concept of dynamic propensity. We re-examine this relationship by analyzing dynamical fluctuations in two atomistic glass-formers and two…

Statistical Mechanics · Physics 2009-08-25 Ludovic Berthier , Robert L. Jack

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

Soft Condensed Matter · Physics 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

We test a hypothesis for the origin of dynamical heterogeneity in slowly relaxing systems, namely that it emerges from soft (Goldstone) modes associated with a broken continuous symmetry under time reparametrizations. We do this by…

Disordered Systems and Neural Networks · Physics 2013-10-30 Karina E. Avila , Horacio E. Castillo , Azita Parsaeian

We study theoretically and numerically a family of multi-point dynamic susceptibilities that quantify the strength and characteristic lengthscales of dynamic heterogeneities in glass-forming materials. We use general theoretical arguments…

The effects of randomly pinning particles in a model glass-forming fluid are studied, with a focus on the dynamically heterogeneous relaxation in the presence of pinning. We show how four-point dynamical correlations can be analysed in real…

Statistical Mechanics · Physics 2013-10-30 Robert L. Jack , Christopher J. Fullerton

We study concentrated binary colloidal suspensions, a model system which has a glass transition as the volume fraction $\phi$ of particles is increased. We use confocal microscopy to directly observe particle motion within dense samples…

Soft Condensed Matter · Physics 2011-05-20 Takayuki Narumi , Scott V. Franklin , Kenneth W. Desmond , Michio Tokuyama , Eric R. Weeks

We study the simplest model of dynamic heterogeneities in glass forming liquids: one-spin facilitated kinetic Ising model introduced by Fredrickson and Andersen [G.H. Fredrickson and H.C. Andersen, Phys. Rev. Lett. 53, 1244 (1984); J. Chem.…

Statistical Mechanics · Physics 2009-11-10 Grzegorz Szamel

Slow relaxation and plastic deformation in disordered materials such as metallic glasses and supercooled liquids occur at dynamical heterogeneities, or neighboring particles that rearrange in a correlated, cooperative manner. Dynamical…

Statistical Mechanics · Physics 2022-05-20 Charles K. C. Lieou , Takeshi Egami

We investigate a binary Lennard-Jones mixture with molecular dynamics simulations. We consider first a system cooled linearly in time with the cooling rate gamma. By varying gamma over almost four decades we study the influence of the…

Statistical Mechanics · Physics 2015-06-25 K. Vollmayr-Lee , W. Kob , K. Binder , A. Zippelius

Using molecular dynamics simulations, we have determined that the nature of dynamical heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly attractive systems differ little from dense hard-sphere and…

Soft Condensed Matter · Physics 2007-05-23 David R. Reichman , Eran Rabani , Phillip L. Geissler

We investigate the heterogeneity of dynamics, the breakdown of the Stokes-Einstein relation and fragility in a model glass forming liquid, a binary mixture of soft spheres with a harmonic interaction potential, for spatial dimensions from 3…

Soft Condensed Matter · Physics 2021-08-20 Monoj Adhikari , Smarajit Karmakar , Srikanth Sastry

We examine the dynamics of hard spheres and discs at high packing fractions in two and three dimensions, modeling the simplest systems exhibiting a glass transition. As it is well known, cooperativity and dynamic heterogeneity arise as…

Soft Condensed Matter · Physics 2007-05-23 Burkhard Doliwa , Andreas Heuer

We review the phenomena of dynamical heterogeneity in glass-forming systems and its description within replica and mean-field theories of the glass transition.

Disordered Systems and Neural Networks · Physics 2022-09-08 Giulio Biroli , Kunimasa Miyazaki , David R. Reichman

We present a simple lattice model showing a glassy behavior. $R$ matrix analysis predicts critical termination of the super-cooled fluid branch at density $\rho_g=0.1717$. This prediction is confirmed by dynamical numerical simulations,…

Statistical Mechanics · Physics 2010-08-26 Z. Rotman , E. Eisenberg