English
Related papers

Related papers: Testing Koopmans spectral functionals on the analy…

200 papers

One of the potential applications of a quantum computer is solving quantum chemical systems. It is known that one of the fastest ways to obtain somewhat accurate solutions classically is to use approximations of density functional theory.…

Quantum Physics · Physics 2020-11-18 Thomas E. Baker , David Poulin

We present a substantial extension of our constraint-based approach for development of orbital-free (OF) kinetic-energy (KE) density functionals intended for the calculation of quantum-mechanical forces in multi-scale molecular dynamics…

Materials Science · Physics 2015-05-13 V. V. Karasiev , R. S. Jones , S. B. Trickey , Frank E. Harris

We re-adapt a spectral renormalization method, introduced in nonlinear optics, to solve the Kohn-Sham (KS) equations of density functional theory (DFT), with a focus on functionals based on the strictly-correlated electrons (SCE) regime,…

Strongly Correlated Electrons · Physics 2020-04-23 Juri Grossi , Ziad H. Musslimani , Michael Seidl , Paola Gori-Giorgi

We compare two different approaches to investigations of many-electron systems. The first is the Hartree-Fock (HF) method and the second is the Density Functional Theory (DFT). Overview of the main features and peculiar properties of the HF…

Materials Science · Physics 2009-11-07 M. Ya. Amusia , A. Z. Msezane , V. R. Shaginyan

The Koopman operator is a powerful approach to global stability analysis of nonlinear systems, which provides a systematic procedure for Lyapunov function design. In this framework, Lyapunov functions are obtained through the eigenfunctions…

Dynamical Systems · Mathematics 2026-04-13 François-Grégoire Bierwart , Alexandre Mauroy

The spectral function for finite nuclei is computed within the framework of the Local Density Approximation, starting from nuclear matter spectral functions obtained with a realistic nucleon-nucleon interaction. The spectral function is…

Nuclear Theory · Physics 2008-11-26 D. Van Neck , A. E. L. Dieperink , E. Moya de Guerra

A quantum electrodynamical time-dependent density functional theory framework is applied to describe strongly coupled light--matter interactions in cavity environments. The formalism utilizes a tensor product approach, coupling real-space…

Chemical Physics · Physics 2025-11-27 Yetmgeta Aklilu , Matthew Shepherd , Cody L. Covington , Kalman Varga

In orbital-free density functional theory the kinetic potential (KP), the functional derivative of the kinetic energy density functional, appears in the Euler equation for the electron density and may be more amenable to simple…

Other Condensed Matter · Physics 2015-05-13 Jeng-Da Chai , Vincent L. Ligneres , Gregory Ho , Emily A. Carter , John D. Weeks

Under the Franck-Condon approximation, we systematically validated the performance of density functional theory (DFT) and the effects of anharmonicity in simulating C/N/O K-edge vibrationally-resolved X-ray spectra of common diatomic…

Chemical Physics · Physics 2025-01-06 Lu Zhang , Minrui Wei , Guoyan Ge , Weijie Hua

Ground and excited states of a confined negative Hydrogen ion has been pursued under Kohn-Sham density functional approach by invoking a physically motivated work-function-based exchange potential. The exchange-only results are of near…

Atomic Physics · Physics 2022-05-23 Sangita Majumdar , Neetik Mukherjee , Amlan K. Roy

We study single electron spectral functions in a quantum dimer model introduced by Punk, Allais and Sachdev (Ref. [1]). The Hilbert space of this model is spanned by hard-core coverings of the square lattice with two types of dimers:…

Strongly Correlated Electrons · Physics 2018-02-27 Sebastian Huber , Johannes Feldmeier , Matthias Punk

This work is concerned with the convex analysis of functions defined on (not necessarily finite-dimensional) Hilbert spaces whose values depend solely on a certain ``spectrum'' of the arguments, a class we term ``spectral functions.'' We…

Optimization and Control · Mathematics 2026-03-11 Hòa T. Bùi , Minh N. Bùi , Christian Clason

Spectral Mackey functors are homotopy-coherent versions of ordinary Mackey functors as defined by Dress. We show that they can be described as excisive functors on a suitable infinity-category, and we use this to show that universal…

Algebraic Topology · Mathematics 2014-06-03 C. Barwick

The electronic band structures of two-dimensional materials are significantly different from those of their bulk counterparts, due to quantum confinement and strong modifications of electronic screening. An accurate determination of…

Mesoscale and Nanoscale Physics · Physics 2020-07-08 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

Energy functionals of the Green's function can simultaneously provide spectral and thermodynamic properties of interacting electrons' systems. Though powerful in principle, these formulations need to deal with dynamical…

Materials Science · Physics 2024-05-28 Tommaso Chiarotti , Andrea Ferretti , Nicola Marzari

A recently developed density functional method, within Hohenberg-Kohn-Sham framework, is used for faithful description of atoms, molecules in Cartesian coordinate grid, by using an LCAO-MO ansatz. Classical Coulomb potential is obtained by…

Chemical Physics · Physics 2013-07-16 Amlan K. Roy

We develop a formalism based on a time-dependent wave-function ansatz to study correlations of photons emitted from a collection of two-level quantum emitters. We show how to simulate the system dynamics and evaluate the intensity of the…

The Koopman framework is a popular approach to transform a finite dimensional nonlinear system into an infinite dimensional, but linear model through a lifting process, using so-called observable functions. While there is an extensive…

Systems and Control · Electrical Eng. & Systems 2023-12-18 Lucian Cristian Iacob , Maarten Schoukens , Roland Tóth

By introducing a set of auxiliary equations representing a many-body system, we have derived an extension of the Kohn-Sham scheme for the density functional theory. These equations consist of a Kohn-Sham-type equation determining…

Materials Science · Physics 2009-11-07 Koichi Kusakabe

We study the properties of the Hooke's law correlation energy ($\Ec$), defined as the correlation energy when two electrons interact {\em via} a harmonic potential in a $D$-dimensional space. More precisely, we investigate the $^1S$ ground…

Other Condensed Matter · Physics 2010-04-20 Pierre-François Loos