English

Confined H$^-$ ion within a density functional framework

Atomic Physics 2022-05-23 v1 Quantum Physics

Abstract

Ground and excited states of a confined negative Hydrogen ion has been pursued under Kohn-Sham density functional approach by invoking a physically motivated work-function-based exchange potential. The exchange-only results are of near Hartree-Fock quality. Local parameterised Wigner-type, and gradient- and Laplacian-dependent non-local Lee-Yang-Parr functionals are chosen to investigate the electron correlation effects. Eigenfunctions and eigenvalues are extracted by using a generalized pseudospectral method obeying Dirichlet boundary condition. Energy values are reported for 1s2^{2} (1^{1}S), 1s2s (3,1^{3,1}S) and 1s2p (3,1^{3,1}P) states. Performance of the correlation functionals in the context of confinement is examined critically. The present results are in excellent agreement with available literature. Additionally, Shannon entropy and Onicescu energy are offered for ground and low lying singly excited 1s2s (3^{3}S) and 1s2p (3^{3}P) states. The influence of electron correlation is more predominant in the weaker confinement limit and it decays with an increase in confinement strength. In essence, energy and some information measures are estimated using a newly formulated density functional strategy.

Keywords

Cite

@article{arxiv.2205.10314,
  title  = {Confined H$^-$ ion within a density functional framework},
  author = {Sangita Majumdar and Neetik Mukherjee and Amlan K. Roy},
  journal= {arXiv preprint arXiv:2205.10314},
  year   = {2022}
}

Comments

25 pages, 6 figures, 8 tables

R2 v1 2026-06-24T11:23:44.295Z