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Spin current generators are critical components for spintronics-based information processing. In this work, we theoretically and computationally investigate the bulk spin photovoltaic (BSPV) effect for creating DC spin current under light…

Materials Science · Physics 2021-07-20 Haowei Xu , Hua Wang , Jian Zhou , Ju Li

We study the bulk photovoltaic effect (BPVE) in Dirac and Weyl semimetals under two-frequency light irradiation. We show that the BPVE emerges for centrosymmetric Dirac and Weyl semimetals in the presence of light fields with frequencies…

Mesoscale and Nanoscale Physics · Physics 2025-01-15 Yuya Ikeda , Sota Kitamura , Takahiro Morimoto

We compute the shift current bulk photovoltaic effect (BPVE) in bulk BaTiO$_3$ and two-dimensional monochalcogenide SnSe considering quasi-particle corrections and exciton effects. We explore changes in shift current peak position and…

Materials Science · Physics 2020-01-15 Ruixiang Fei , Liang Z. Tan , Andrew M. Rappe

Recently, atomically thin PdSe$_2$ semiconductors with rare pentagonal Se-Pd-Se monolayers were synthesized and were also found to possess superior properties such as ultrahigh air stability, and high carrier mobility, thus offering a new…

Materials Science · Physics 2021-09-21 Vijay Kumar Gudelli , Guang-Yu Guo

Converting light into steady currents and spin-currents in two-dimensional (2D) platform is essential for future energy harvesting and spintronics. We show that the giant and modulable bulk photovoltaic effects (BPVEs) can be achieved in…

Materials Science · Physics 2023-01-10 Liang Liu , Weikang Liu , Bin Cheng , Bin Cui , Jifan Hu

Noncentrosymmetric bulk crystals generate photocurrent without any bias voltage. One of the dominant mechanisms, shift current, comes from a quantum interference of electron wave functions being distinct from classical current caused by…

Materials Science · Physics 2018-12-17 M. Nakamura , H. Hatada , Y. Kaneko , N. Ogawa , Y. Tokura , M. Kawasaki

The bulk photovoltaic effect that is intimately associated with crystalline symmetry has been extensively studied in various nonmagnetic materials, especially ferroelectrics with a switchable electric polarization. In order to further…

Materials Science · Physics 2022-12-28 Chunmei Zhang , Ping Guo , Jian Zhou

The bulk photovoltaic (BPV) effect that converts light into electric current is highly sensitive to the system symmetry and its electronic Bloch wavefunction. To create a sizable net electric current, it is necessary to break the…

Materials Science · Physics 2024-07-08 Chunmei Zhang , Jian Zhou

We employ first-principles calculations to investigate the ferroelectric properties and the bulk photovoltaic effect (BPVE) of antimony sulfur iodide (SbSI). The BPVE enables direct sunlight-to-electricity conversion in homogeneous…

Materials Science · Physics 2025-06-13 Giuseppe Cuono , Subhadeep Bandyopadhyay , Andrea Droghetti , Silvia Picozzi

Photogalvanic effect (PGE) occurs in materials with non-centrosymmetric structures when irradiated by linearly or circularly polarized light. Here, using non-equilibrium Green's function combined with density functional theory (NEGF-DFT),…

Materials Science · Physics 2023-05-26 Li-Wen Zhang , Ya-Qing Yang , Jun Chen , Lei Zhang

Broadband, efficient and fast conversion of light to electricity is crucial for sensing and clean energy. Here we reveal the largest observed bulk photo-voltaic effect (BPVE), an intrinsic mechanism predicted to be ultrafast and exceed the…

DC photoelectrical currents can be generated purely as a non-linear effect in uniform media lacking inversion symmetry without the need for a material junction or bias voltages to drive it, in what is termed photogalvanic effect. These…

Mesoscale and Nanoscale Physics · Physics 2016-08-17 F. Hipolito , Thomas G. Pedersen , Vitor M. Pereira

Bulk photovoltaic effect, which arises from crystal symmetry-driven charge carrier separation, is an intriguing physical phenomenon that has attracted extensive interest in photovoltaic application due to its junction-free photovoltaic and…

Materials Science · Physics 2023-08-22 Xiaojuan Chen , Kang Xu , Tingxiao Qin , Yubin Wang , Yuzhong Chen , Haiyun Liu , Qihua Xiong

The bulk photovoltaic effect (BPE) leads to the generation of a photocurrent from an asymmetric material. Despite drawing much attention due to its ability to generate photovoltages above the band gap ($E_g$), it is considered a weak effect…

The bulk photovoltaic effect generates intrinsic photocurrents in materials without inversion symmetry. Shift current is one of the bulk photovoltaic phenomena related to the Berry phase of the constituting electronic bands: photo-excited…

Materials Science · Physics 2020-07-17 Banasree Sadhukhan , Yang Zhang , Rajyavardhan Ray , Jeroen van den Brink

Hybrid halide perovskites exhibit nearly 20% power conversion efficiency, but the origin of their high efficiency is still unknown. Here, we compute the shift current, a dominant mechanism of bulk photovoltaic (PV) effect for ferroelectric…

Materials Science · Physics 2014-10-14 Fan Zheng , Hiroyuki Takenaka , Fenggong Wang , Nathan Z. Koocher , Andrew M. Rappe

The bulk photovoltaic effect (BPVE) leads to directed photo-currents and photo-voltages in bulk materials. Unlike photo-voltages in p-n junction solar cells that are limited by carrier recombination to values below the bandgap energy of the…

Applied Physics · Physics 2023-03-17 Andreas Pusch , Udo Römer , Dimitrie Culcer , Nicholas J. Ekins-Daukes

The bulk photovoltaic effect provides a fundamental pathway for direct light-to-current conversion in quantum materials. However, these nonlinear currents are often strictly constrained or forbidden by crystal symmetries, hindering their…

Mesoscale and Nanoscale Physics · Physics 2026-05-25 Zhuocheng Lu , Zhuang Qian , Zhichao Guo , Likun Shi , Shi Liu , Hua Wang , Kai Chang

The bulk photovoltaic effect (BPVE) has attracted an increasing interest due to its potential to overcome the efficiency limit of traditional photovoltaics, and much effort has been devoted to understanding its underlying physics. However,…

Materials Science · Physics 2022-01-05 Zhenbang Dai , Andrew M. Rappe

Bulk photovoltaic (BPV) effect, a second order nonlinear process that generates static current under light irradiation, requires centrosymmetric broken systems as its application platform. In order to realize measurable BPV photocurrent in…

Materials Science · Physics 2023-01-05 Xingchi Mu , Qianqian Xue , Yan Sun , Jian Zhou