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We present dynamic light scattering (DLS) measurements of soft polymethyl-methacrylate (PMMA) and polyacrylamide(PA) polymer gels prepared with trapped bodies (latex spheres or maghemite nanoparticles). We show that the anomalous…

Soft Condensed Matter · Physics 2015-06-10 Alvaro V. N. C. Teixeira , Erik Geissler , Pedro Licinio

We have used the Scheutjens-Fleer self-consistent field (SF-SCF) method to predict the self-assembly of triblock copolymers with a solvophilic middle block and sufficiently long solvophobic outer blocks. We model copolymers consisting of…

We study the freezing kinetics of colloidal polycrystals made of micelles of Pluronic F108, a thermosensitive copolymer, to which a small amount of silica nanoparticles of size comparable to that of the micelles are added. We use rheology…

Soft Condensed Matter · Physics 2013-03-18 A. Louhichi , E. Tamborini , N. Ghofraniha , F. Caton , D. Roux , J. Oberdisse , L. Cipelletti , L. Ramos

The micellization process of the aqueous mixed system Triton X-100 (TX100)-Dodecyltrimethylammonium Bromide (DTAB) was studied with a battery of procedures: surface tension, static and dynamic light scattering and ion-selective electrodes.…

Microgels are soft colloids that, in virtue of their polymeric nature, can react to external stimuli such as temperature or pH by changing their size. The resulting swelling/deswelling transition can be exploited in fundamental research as…

Soft Condensed Matter · Physics 2019-02-15 Lorenzo Rovigatti , Nicoletta Gnan , Emanuela Zaccarelli

In this study, we investigate dynamic light scattering (DLS) from both randomly diffusing silica particles and acousto-responsive microgels in aqueous dispersions under ultrasonic vibration. Employing high-frequency ultrasound (US) with low…

Soft Condensed Matter · Physics 2024-01-23 Sebastian Stock , Regine von Klitzing , Amin Rahimzadeh

Many industrial soft materials often include oil-in-water (O/W) emulsions at the core of their formulations. By using tuneable interface stabilizing agents, such emulsions can self-assemble into complex structures. DNA has been used for…

We present a comprehensive investigation of polymer diffusion in the semidilute regime by fluorescence correlation spectroscopy (FCS) and dynamic light scattering (DLS). Using single-labeled polystyrene chains, FCS leads to the…

Nanotechnology has revolutionized the fabrication of hybrid species with tailored functionalities. A milestone in this field is the DNA conjugation of nanoparticles, introduced almost 30 years ago, which typically exploits the affinity…

Colloidal building blocks with re-configurable shapes and dynamic interactions can exhibit unusual self-assembly behaviors and pathways. In this work, we consider the phase behavior of colloids coated with surface-mobile polymer brushes…

Soft Condensed Matter · Physics 2024-05-16 Yaxin Xu , Prabhat Jandhyala , Sho C. Takatori

We present molecular dynamics (MD) simulations results for dense fluids of ultrasoft, fully-penetrable particles. These are a binary mixture and a polydisperse system of particles interacting via the generalized exponential model, which is…

Soft Condensed Matter · Physics 2012-12-24 Daniele Coslovich , Marco Bernabei , Angel J. Moreno

Soft materials possessing tunable rheological properties are desirable in applications ranging from 3D printing to biological scaffolds. Here, we use a telechelic, triblock copolymer polystyrene-b-poly(ethylene oxide)-b-polystyrene (SEOS)…

Soft Condensed Matter · Physics 2023-05-05 Daniel P. Keane , Colby J. Constantine , Matthew D. Mellor , Ryan Poling-Skutvik

We study bottlebrush macromolecules in a good solvent by small-angle neutron scattering (SANS), static light scattering (SLS), and dynamic light scattering (DLS). These polymers consist of a linear backbone to which long side chains are…

Soft Condensed Matter · Physics 2009-11-13 S. Bolisetty , C. Airaud , Y. Xu , A. H. E. Mueller , L. Harnau , S. Rosenfeldt , P. Lindner , M. Ballauff

While the realistically modeling of the thermodynamic behavior of fluids usually demands elaborated atomistic models, much have been learned from simplified ones. Here, we investigate a model where point-like particles (with activity $z_0$)…

Soft Condensed Matter · Physics 2019-07-15 Nathann T. Rodrigues , Tiago J. Oliveira

The dynamical properties of classical fluids at pico-liter scale attract experimentally and theoretically much attention in the soft-matter and biophysics communities, due to the appearance of the microfluidics, also called 'lab-on-a-chip',…

Statistical Mechanics · Physics 2007-05-23 F. Penna , P. Tarazona

Active materials capable of autonomously modulating their mechanical properties are foundational to the development of next-generation soft technologies. Here, we introduce a novel class of extensible biohybrid hydrogels powered by living…

Following up a recent paper on grafted sliding polymer layers (Macromolecules 2005, 38, 1434-1441), we investigated the influence of the sliding degree of freedom on the self-assembly of sliding polymeric surfactants that can be obtained by…

Soft Condensed Matter · Physics 2007-05-23 Vladimir A. Baulin , N. -K. Lee , Albert Johner , Carlos M. Marques

This study utilizes self-consistent field theory to characterize various features of cononsolvency-driven spherical micelles formed by double hydrophilic block copolymers (DHBCs). Micelles are observed only at an intermediate cosolvent…

Soft Condensed Matter · Physics 2025-04-07 Xiangyu Zhang , Jing Zong , Dong Meng

Using molecular dynamics simulations we investigate the finite-size dependence of the dynamical properties of a diatomic supercooled liquid. The simplicity of the molecule permits us to access the microsecond time scale. We find that the…

Soft Condensed Matter · Physics 2017-12-06 Sonia Taamalli , Julia Hinds , Samuel Migirditch , Victor Teboul

Nanoparticle sintering remains a critical challenge in heterogeneous catalysis. In this work, we present a unified deep potential (DP) model for Cu nanoparticles on three Al$_2$O$_3$ surfaces ($\gamma$-Al$_2$O$_3$(100),…

Materials Science · Physics 2025-01-30 Jiayan Xu , Shreeja Das , Amar Deep Pathak , Abhirup Patra , Sharan Shetty , Detlef Hohl , Roberto Car