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We introduce a novel computational framework for excited-states molecular quantum dynamics simulations driven by quantum computing-based electronic-structure calculations. This framework leverages the fewest-switches surface-hopping method…

Quantum Physics · Physics 2024-02-26 Anthony Gandon , Alberto Baiardi , Pauline Ollitrault , Ivano Tavernelli

Heterogeneous catalysts based on sub-nanometer metal clusters often exhibit strongly size-dependent properties, and the addition or removal of a single atom can make all the difference. Identifying the most active species and deciphering…

We propose a novel method to describe realistically ionization processes with absorbing boundary conditions in basis expansion within the formalism of the so-called Non-Adiabatic Quantum Molecular Dynamics. This theory couples…

Quantum Physics · Physics 2015-06-26 Mathias Uhlmann , Thomas Kunert , Ruediger Schmidt

Azo-dye-doped liquid crystal elastomers (LCEs) are known to show a strong photomechanical response. We report on experiments that suggest that photothermal heating is the underlying mechanism in surface-constrained geometry. In particular,…

The coupling of excited states and ionic dynamics is the basic and challenging point for the materials response at extreme conditions. In laboratory, the intense laser produces transient nature and complexity with highly nonequilibrium…

Computational Physics · Physics 2023-11-27 Qiyu Zeng , Bo Chen , Shen Zhang , Dongdong Kang , Han Wang , Xiaoxiang Yu , Jiayu Dai

Thermo-osmotic flows, generated by applying a thermal gradient along a liquid-solid interface, could be harnessed to convert waste heat into electricity. While this phenomenon has been known for almost a century, there is a crucial need to…

Soft Condensed Matter · Physics 2024-07-15 Mehdi Ouadfel , Samy Merabia , Yasutaka Yamaguchi , Laurent Joly

Interfaces play a crucial role in energy transport at the nanoscale. However, direct experimental observations of interfacial thermal conductance across molecular junctions have remained challenging due to the high spatiotemporal resolution…

Chemical Physics · Physics 2025-12-23 Md. Shahriar Hossain Shuvo , Xing He , Mithun Ghosh , Ding-Shyue Yang

Molecular aggregates on plasmonic nanoparticles have emerged as attractive systems for the studies of cavity quantum electrodynamics. They are highly tunable, scalable, easy to synthesize and offer sub-wavelength confinement, all while…

Based on the van der Waals density functional theory (vdW-DFT)+U scheme, we carry out the ab initio molecular dynamics (AIMD) study of the interaction dynamics for H$_{2}$ impingement against the stoichiometric PuO$_{2}$(111), the reduced…

Materials Science · Physics 2015-06-19 Bo Sun , Haifeng Liu , Haifeng Song , Guangcai Zhang , Hui Zheng , Xian-Geng Zhao , Ping Zhang

The molecular photo cell, i.e., a single molecule donor-acceptor complex, beside being technologically important, is a paradigmatic example of a many-body system operating in strong non-equilibrium. The quantum transport and the…

Mesoscale and Nanoscale Physics · Physics 2020-07-06 Subhajit Sarkar , Yonatan Dubi

Ultrafast laser measurements probe the non-equilibrium dynamics of excited electrons in metals with increasing temporal resolution. Electronic structure calculations can provide a detailed microscopic understanding of hot electron dynamics,…

Computational Physics · Physics 2016-08-12 Ana M. Brown , Ravishankar Sundararaman , Prineha Narang , William A. Goddard , Harry A. Atwater

The use of nanoplasmonics to control light and heat close to the thermodynamic limit enables exciting opportunities in the field of plasmonic catalysis. The decay of plasmonic excitations creates highly nonequilibrium distributions of hot…

The influence of static stress and alternating loading direction on the potential energy and mechanical properties of amorphous alloys is investigated using molecular dynamics simulations. The model glass is represented via a binary mixture…

Soft Condensed Matter · Physics 2021-02-09 Nikolai V. Priezjev

Plasmonic excitations decay within femtoseconds, leaving non-thermal (often referred to as "hot") charge carriers behind that can be injected into molecular structures to trigger chemical reactions that are otherwise out of reach -- a…

Materials Science · Physics 2025-01-28 Jakub Fojt , Paul Erhart , Christian Schäfer

We investigate the ultrafast nonlinear dynamics of light emitted in an active plasmonic waveguide composed of a thin film of gold sandwiched by two silicon layers immersed in externally pumped Al$_2$O$_3$:Er$^{3+}$. We model optical…

Optics · Physics 2019-07-31 Ambaresh Sahoo , Andrea Marini , Samudra Roy

Fluid dynamics simulations of melting and crater formation at the surface of a copper cathode exposed to high plasma heat fluxes and pressure gradients are presented. The predicted deformations of the free surface and the temperature…

Computational Physics · Physics 2020-08-10 L. Vignitchouk , A. Khodak , S. Ratynskaia , I. D. Kaganovich

Photoinduced ultrafast phenomena in materials exhibiting nonequilibrium behavior can lead to the emergence of exotic phases beyond the limits of thermodynamics, presenting opportunities for femtosecond photoexcitation. Despite extensive…

We have performed multicanonical chain-growth simulations of a polymer interacting with an adsorbing surface. The polymer, which is not explicitly anchored at the surface, experiences a hierarchy of phase transitions between conformations…

Statistical Mechanics · Physics 2009-11-11 Michael Bachmann , Wolfhard Janke

Light-driven plasmonic enhancement of chemical reactions on metal catalysts is a promising strategy to achieve highly selective and efficient chemical transformations. The study of plasmonic catalyst materials has traditionally focused on…

Materials Science · Physics 2021-06-16 Oscar A. Douglas-Gallardo , Connor L. Box , Reinhard J. Maurer

In this work we study the electromagnetic response induced by axions in a magnetized plasma, focusing specifically on characterizing energy transfer and energy losses from the ambient axion field in highly inhomogeneous and strongly varying…

High Energy Physics - Phenomenology · Physics 2026-03-31 Fabrizio Corelli , Estanis Utrilla Ginés , Enrico Cannizzaro , Andrea Caputo , Samuel J. Witte