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Nonadiabatic dynamics methods are an essential tool for investigating photochemical processes. In the context of employing first principles electronic structure techniques, such simulations can be carried out in a practical manner using…

Chemical Physics · Physics 2024-05-08 Jonathan R. Mannouch , Aaron Kelly

Photoresponse of bimetallic Au-Ag nanoparticle embedded soda glass (Au-Ag@SG) substrate is reported for surface plasmon assisted optical switching using 808 nm excitation. Au-Ag@SG system is made by an ion beam technique where Ag^+ is…

Materials Science · Physics 2015-09-01 Sandip Dhara , C. -Y. Lu , P. Magudapathy , Y. -F. Huang , W. -S. Tu , K. -H. Chen

Molecular adsorbates on metal surfaces exchange energy with substrate phonons and low-lying electron-hole pair excitations. In the limit of weak coupling, electron-hole pair excitations can be seen as exerting frictional forces on…

Materials Science · Physics 2016-09-28 Reinhard J. Maurer , Mikhail Askerka , Victor S. Batista , John C. Tully

We use computer simulations to study the microscopic dynamics of an athermal assembly of soft particles near the fluid-to-solid, jamming transition. Borrowing tools developed to study dynamic heterogeneity near glass transitions, we…

Materials Science · Physics 2010-06-24 Claus Heussinger , Ludovic Berthier , Jean-Louis Barrat

Recent experiments (R. A. Baragiola and C. A. Dukes, Phys. Rev. Lett. {\bf 76}, 2547 (1996)) with slow ions incident at grazing angle on metal surfaces have shown that bulk plasmons are excited under conditions where the ions do not…

Materials Science · Physics 2009-10-31 A. Bergara , J. M. Pitarke , R. H. Ritchie

Mixed-quantum-classical molecular dynamics simulation implies an effective measurement on the electronic states owing to continuously tracking the atomic forces.Based on this insight, we propose a quantum trajectory mean-field approach for…

Chemical Physics · Physics 2014-08-08 Wei Feng , Luting Xu , Xin-Qi Li , Weihai Fang , YiJing Yan

We examine electron-electron mediated relaxation following excitation of a correlated system by an ultrafast electric field pump pulse. The results reveal a dichotomy in the temporal evolution as one tunes through a Mott metal-to-insulator…

Strongly Correlated Electrons · Physics 2013-08-20 B. Moritz , A. F. Kemper , M. Sentef , T. P. Devereaux , J. K. Freericks

Metal nanoparticle surfaces comprise of multiple planes with various atomic arrangements that interact with gases differently1,2. Identification of gas adsorption properties on all facets is an essential prerequisite for rational design of…

Materials Science · Physics 2015-07-28 Pin Ann Lin , Jonathan Winterstein , John Kohoutek , Henri Lezec , Renu Sharma

A high-dimensional potential energy surface (PES) for CO interaction with the Au(111) surface is developed using a machine-learning algorithm. Including both molecular and surface coordinates, this PES enables the simulation of the recent…

Chemical Physics · Physics 2019-12-04 Meng Huang , Xueyao Zhou , Yaolong Zhang , Linsen Zhou , Maite Alducin , Bin Jiang , Hua Guo

An important process for antimatter experiments is the cooling of particles in a Penning-Malmberg trap to experimentally useful temperatures. A non-neutral plasma of one species (e.g. antiprotons) can be collisionally cooled on another…

Plasma Physics · Physics 2025-11-13 James C. Welch , Louis Jose , Timothy D. Tharp , Scott D. Baalrud

Active learning (AL) can drastically accelerate materials discovery; its power has been shown in various classes of materials and target properties. Prior efforts have used machine learning models for the optimal selection of physical…

Materials Science · Physics 2021-10-18 David E. Farache , Juan C. Verduzco , Zachary D. McClure , Saaketh Desai , Alejandro Strachan

Available simulation methods, suitable to describe solid-solid phase transitions occurring upon increasing of presssure and/or temperature, are based on empirical interatomic potentials: this restriction reduces the predictive power, and…

Condensed Matter · Physics 2016-08-31 P. Focher , G. L. Chiarotti , M. Bernasconi , E. Tosatti , M. Parrinello

A new approach to simulating warm and hot dense matter that combines density functional theory based calculations of the electronic structure to classical molecular dynamics simulations with pair interaction potentials is presented. The new…

Plasma Physics · Physics 2015-06-22 C. E. Starrett , J. Daligault , D. Saumon

We propose a method to directly couple molecular dynamics, finite element method and particle-in-cell techniques to simulate metal surface response to high electric fields. We use this method to simulate the evolution of a field emitting…

Computational Engineering, Finance, and Science · Computer Science 2020-05-27 Mihkel Veske , Andreas Kyritsakis , Kyrre Ness Sjobak , Vahur Zadin , Alvo Aabloo , Flyura Djurabekova

The dynamics of several light filaments (spatial optical solitons) propagating in an optically nonlinear and non-local random medium is investigated using the paradigms of the physics of complexity. Cluster formation is interpreted as a…

Optics · Physics 2007-05-23 Claudio Conti

In the context of Frenkel exciton dynamics in aggregated molecules the polaron transformation technique facilitates a treatment where diagonal elements attributed to electronic excited-state populations are decoupled from fluctuations…

Chemical Physics · Physics 2021-08-30 Joachim Seibt , Oliver Kühn

Metallic nanoparticles embedded in dielectrics permit enhanced capture of light at specific wavelengths through excitation of plasmons, i.e. the quanta of coherent and collective oscillations of large concentrations of nearly free…

Materials Science · Physics 2010-01-19 J. Trice , C. Favazza , H. Garcia , R. Sureshkumar , R. Kalyanaraman

Catalyzing capping layers on top of metal hydrides are often employed to enhance the hydrogenation kinetics of metal-hydride based systems such as hydrogen sensors. Here, we experimentally study the hydrogenation kinetics of capping layers…

Materials Science · Physics 2021-04-26 Lars Bannenberg , Herman Schreuders

Molecular dynamics simulations are a powerful tool to study diffusion processes in battery electrolyte and electrode materials. From a single molecular dynamics simulation many properties relevant to diffusion can be obtained, including the…

Chemical Physics · Physics 2018-07-09 Niek J. J. de Klerk , Eveline van der Maas , Marnix Wagemaker

The transfer of charges, including electrons and holes, is a key step in heterogeneous catalysis, taking part in the reduction and oxidation of adsorbate species on catalyst surfaces. In plasmonic catalysis, electrons can transfer from…

Materials Science · Physics 2024-08-13 Robin E. Moorby , Valentina Parravicini , Thomas-C. Jagau , Maristella Alessio