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A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…

Quantum Physics · Physics 2007-10-25 Dorje C. Brody , Daniel W. Hook , Lane P. Hughston

Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…

chao-dyn · Physics 2008-02-03 J. Kumicak , X. de Hemptinne

By computing the local energy expectation values with respect to some local measurement basis we show that for any quantum system there are two fundamentally different contributions: changes in energy that do not alter the local von Neumann…

Quantum Physics · Physics 2008-08-04 Hendrik Weimer , Markus J. Henrich , Florian Rempp , Heiko Schröder , Günter Mahler

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

The purpose of this work is to discuss recent progress in deriving the fundamental laws of thermodynamics (0th, 1st and 2nd-law) from nonequilibrium quantum statistical mechanics. Basic thermodynamic notions are clarified and different…

Mathematical Physics · Physics 2007-05-23 Walid K. Abou Salem

Quantum thermalization describes how closed quantum systems can effectively reach thermal equilibrium, resolving the apparent incongruity between the reversibility of Schr\"odinger's equation and the second law of thermodynamics. Despite…

Quantum Physics · Physics 2026-01-08 Saúl Pilatowsky-Cameo , Soonwon Choi

We discuss how the thermalization of an elementary quantum system is modified when the system is placed in an environment out of thermal equilibrium. To this aim we provide a detailed investigation of the dynamics of an atomic system placed…

Quantum Physics · Physics 2013-01-16 Bruno Bellomo , Riccardo Messina , Didier Felbacq , Mauro Antezza

Further formulas are presented involving quantum mechanics, thermodynamics, and integrable systems. Modifications of dispersionless theory are developed.

High Energy Physics - Theory · Physics 2007-05-23 Robert Carroll

We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…

Statistical Mechanics · Physics 2008-07-30 Antonin Coutant , S. G. Rajeev

Underlying the classical thermodynamic principles are analogous microscopic laws, arising from the fundamental axioms of quantum mechanics. These define quantum thermodynamic variables such as quantum work and heat and characterize the…

Quantum Physics · Physics 2023-05-03 Roie Dann , Ronnie Kosloff

This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized…

Quantum Physics · Physics 2015-08-14 Marius Krumm

A renormalized version of the von Neumann quantum entropy (which is finite and continuous in general, infinite dimensional case) and which obeys several of the natural physical demands (as expected for a "good" measure of entanglement in…

Quantum Physics · Physics 2022-11-11 Roman Gielerak

New exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system, its environment, and correlations between them.…

Statistical Mechanics · Physics 2021-05-05 Paul M. Riechers , Mile Gu

Quantum decoherence is seen as an undesired source of irreversibility that destroys quantum resources. Quantum coherences seem to be a property that vanishes at thermodynamic equilibrium. Away from equilibrium, quantum coherences challenge…

Quantum Physics · Physics 2013-08-13 César A. Rodríguez-Rosario , Thomas Frauenheim , Alán Aspuru-Guzik

We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…

Quantum Physics · Physics 2018-01-30 Jen-Tsung Hsiang , C. H. Chou , Y. Subaşi , B. L. Hu

The underlying probabilistic theory for quantum mechanics is non-Kolmogorovian. The order in which physical observables will be important if they are incompatible (non-commuting). In particular, the notion of conditioning needs to be…

Quantum Physics · Physics 2019-07-30 John E. Gough

The balance equations for thermodynamic quantities are derived from the nonlocal quantum kinetic equation. The nonlocal collisions lead to molecular contributions to the observables and currents. The corresponding correlated part of the…

Statistical Mechanics · Physics 2018-06-19 Klaus Morawetz

The von Neumann entropy of various quantum dissipative models is calculated in order to discuss the entanglement properties of these systems. First, integrable quantum dissipative models are discussed, i.e., the quantum Brownian motion and…

Quantum Physics · Physics 2009-11-11 T. Stauber , F. Guinea

The usual paradigm of open quantum systems falls short when the environment is actually coupled to additional fields or components that drive it out of equilibrium. Here we explore the simplest such scenario, by considering a two level…

Quantum Physics · Physics 2020-09-08 Andreu Anglés-Castillo , Mari Carmen Bañuls , Armando Pérez , Inés De Vega

We propose a method to interpolate dynamics of von Neumann and classical master equations with an arbitrary mixing parameter to investigate the thermal effects in quantum dynamics. The two dynamics are mixed by intervening to continuously…

Quantum Physics · Physics 2018-02-13 Tadashi Kadowaki
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