Related papers: Optical Activity of Solids from First Principles
In the nonrelativistic many-electron approximation of the theory of photoionization of the atom in the formalism of secondary quantization and the theory of irreducible tensor operators, analytical structures for the quadrupole transition…
The orbital and spin magnetic moments, and the X-ray-magnetic circular-dichroism (XMCD) spectra at the $M_{4,5}$ edges of the U atoms in a UAs/Co multilayer and in an $\alpha$-U film are calculated within the framework of the…
Crystal field (CF) excitations in the ground multiplet $^3H_6$ of Tm$^{3+}$ ions were investigated using terahertz transmission spectra of magnetoelectric TmAl$_3$(BO$_3$)$_4$ and Tm$_{0.05}$Yb$_{0.1}$Y$_{0.85}$Al$_3$(BO$_3$)$_4$. These…
We report the dynamics and control of the orientational and positional order of ensembles of gold nanorods suspended in air at standard temperature and pressure using externally applied electric fields, demonstrating an active aerosol.…
We report extremely strong optical activity and circular dichroism exhibited by subwavelength arrays of four-start-screw holes fabricated with one-pass focused ion beam milling of freely suspended silver films. Having the fourth order…
We extend a microscopic theory of polarization and magnetization to include the spin degree of freedom of the electrons, introducing a general spin orbit coupling and Zeeman interaction term in the Hamiltonian. At finite frequencies and…
We use the nuclear density functional theory to determine nuclear electric quadrupole and magnetic dipole moments in all one-particle and one-hole neighbours of eight doubly magic nuclei. We align angular momenta along the intrinsic…
We consider the magnetic circular dichroism spectrum of a crystal with broken time-reversal symmetry in the electric-dipole approximation. Using the Kubo-Greenwood formula for the absorptive part of the antisymmetric optical conductivity,…
Nonlinear optics is essential for many recent photonic technologies. Here, we introduce a novel multi-scale approach to simulate the nonlinear optical response of molecular nanomaterials combining ab initio quantum-chemical and classical…
Twisted light beams, or optical vortices, have been used to drive the circular motion of microscopic particles in optical tweezers and have been shown to generate vortices in quantum gases. Recent studies have established that electric…
We establish a general unified formulation which, using the optical theorem of electromagnetic helicity, shows that dichorism is a phenomenon arising in any scattering -or diffraction- process, elastic or not, of chiral electromagnetic…
Optical activity, the power of a medium to rotate the polarization of a light beam, has contributed significantly to molecular structure assessments in stereochemistry, biomolecular science and crystallography. Thus far, it is commonly…
The optical manifold method to compute the one-loop effective action in a static space-time is extended from the massless scalar field to the Maxwell field in any Feynman-like covariant gauge. The method is applied to the case of the…
The phenomenon of molecular optical activity manifests itself as the rotation of the plane of linear polarization when light passes through chiral media. Measurements of optical activity and its wavelength dependence, optical rotatory…
A general formula for the orbital magnetic moment of interacting electrons in solids is derived using the many-electron Green function method. The formula factorizes into two parts, a part that contains the information about the…
For a system with a fixed number of electrons, the total optical sum is a constant, independent of many-body interactions, of impurity scattering and of temperature. For a single band in a metal, such a sum rule is no longer independent of…
Spectroscopic and optical properties of nanosystems and point defects are discussed within the framework of Green's function methods. We use an approach based on evaluating the self-energy in the so-called GW approximation and solving the…
The momentum-dependent orbital character in crystalline solids, referred to as orbital texture, is of capital importance in the emergence of symmetry-broken collective phases such as charge density waves as well as superconducting and…
It is commonly believed that electromagnetic spectra of atoms and molecules can be fully described by interactions of electric and magnetic multipoles. However, it has recently become clear that interactions between light and matter also…
Magneto-optical response, i.e. optical response in the presence of a magnetic field, is commonly used for characterization of materials and in optical communications. However, quantum mechanical description of electric and magnetic fields…