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We report studies on the vibrational and elastic behavior of lithium oxide, Li2O around its superionic transition temperature. Phonon frequencies calculated using the ab-initio and empirical potential model are in excellent agreement with…

Materials Science · Physics 2012-06-04 M. K. Gupta , Prabhatasree Goel , R. Mittal , N. Choudhury , S. L. Chaplot

Crystalline materials at elevated temperatures and pressures can exhibit properties more reminiscent of simple liquids than ideal crystalline materials. Superionic crystalline materials having a liquid-like conductivity {\sigma} are…

Materials Science · Physics 2019-05-22 Hao Zhang , Xinyi Wang , Alexandros Chremos , Jack F. Douglas

We use molecular dynamics with a first-principles based shell model potential to study pyroelec- tricity in lithium niobate. We find that the primary pyroelectric effect is dominant, and pyroelec- tricity can be understood simply from the…

Materials Science · Physics 2011-11-01 Qing Peng , R. E. Cohen

We present a study of the magnetic properties of YNiO$_{3}$ in the paramagnetic range, above and below the metal-insulator (MI) transition. The dc susceptibility, $\chi_{dc}$ (measured up to 1000 K) is a decreasing function of T for $T…

Strongly Correlated Electrons · Physics 2016-08-16 M. T. Causa , R. D. Sánchez , M. Tovar , J. A. Alonso , M. J. Martínez-Lope

We study the normal state electronic structure of the recently discovered infinite-layer nickelate superconductor, Nd$_{1-x}$Sr$_x$NiO$_2$. Using SrNiO$_2$ as a reference, we find that Nd$_{1-x}$Sr$_x$NiO$_2$ is a multi-orbital electronic…

Strongly Correlated Electrons · Physics 2020-11-04 Y. Wang , C. -J. Kang , H. Miao , G. Kotliar

We report a density functional theory plus dynamical mean field theory (DFT+DMFT) study of an oxide heterostructure of LaNiO$_3$ (LNO) bilayers in [111] direction interleaved with four atomic monolayers of LaAlO$_3$. DFT+$U$ optimizations…

Strongly Correlated Electrons · Physics 2019-09-20 Oleg Janson , Karsten Held

We report a comprehensive study of magnetic correlations in LaNiO$_{2}$, a parent compound of the recently discovered family of infinite-layer (IL) nickelate superconductors, using multiple experimental and theoretical methods. Our specific…

To investigate the detailed magnetic properties of a recently discovered superconducting nickelate Nd6Ni5O12, we performed the first-principles electronic structure calculation based on density functional theory. The band dispersion,…

Superconductivity · Physics 2024-10-02 Terri Yoon , Myung Joon Han

The recent discovery of superconductivity in Sr-doped NdNiO$_2$ films grown on SrTiO$_3$ started a novel field within unconventional superconductivity. To understand the similarities and differences between nickelate and cuprate layers on…

Strongly Correlated Electrons · Physics 2020-11-13 Yang Zhang , Ling-Fang Lin , Wenjun Hu , Adriana Moreo , Shuai Dong , Elbio Dagotto

We study a model for the metal-insulator (MI) transition in the rare-earth nickelates RNiO$_3$, based upon a negative charge transfer energy and coupling to a rock-salt like lattice distortion of the NiO$_6$ octahedra. Using exact…

Strongly Correlated Electrons · Physics 2014-03-12 Steve Johnston , Anamitra Mukherjee , Ilya Elfimov , Mona Berciu , George A. Sawatzky

Nickel oxide (NiO) is a binary compound with a lot of applications in the present technology. NiO thin films were deposited by reactive sputtering magnetron under several voltage biases applied in the glass substrates (0, 50, 100, 200, 300,…

Materials Science · Physics 2016-07-26 Javier García Molleja , Bruna Regalado , Julien Keraudy , Graciela Salum , Pierre-Yves Jouan

Using DFT+DMFT we study the normal-state electronic structure and magnetic correlations of the recently discovered alternating single-layer bilayer Raddlesden-Popper nickelate La$_5$Ni$_3$O$_{11}$ (1212-LNO). Our results exhibit qualitative…

Strongly Correlated Electrons · Physics 2026-04-30 I. V. Leonov

We present a combined study of Ni $K$-edge resonant x-ray scattering and density functional calculations to probe and distinguish electronically driven ordering and lattice distortions in nickelate heterostructures. We demonstrate that due…

The investigation of the structural phase transition in the vicinity of the Curie temperature $T_c$ of LiNb$_{1-x}$Ta$_x$O$_3$ crystals is motivated by the expected combination of advantageous high-temperature properties of LiNbO$_3$ and…

The search for oxide materials with physical properties similar to the cuprate high Tc superconductors, but based on alternative transition metals such as nickel, has grown and evolved over time. The recent discovery of superconductivity in…

Motivated by the recently discovered superconductivity in Sr-doped nickelate oxides NdNiO$_2$, we predict a material BiNiO$_2$ that provides an opportunity to study the intertwined ferroelectricity, metallicity, and magnetism in a crystal…

Strongly Correlated Electrons · Physics 2024-04-22 Hu Zhang , RuiFeng Zhang , Lulu Zhao , Chendong Jin , Ruqian Lian , Peng-Lai Gong , RuiNing Wang , JiangLong Wang , Xing-Qiang Shi

Recently, signatures of superconductivity with critical temperature from 20 to 30 K have been reported in pressured trilayer nickelate La$_4$Ni$_3$O$_{10}$ through a pressure-induced structure transition. Here we explore the evolution of…

Strongly Correlated Electrons · Physics 2024-06-18 Peng-Fei Tian , Hao-Tian Ma , Xing Ming , Xiao-Jun Zheng , Huan Li

The bilayer nickelate La$_3$Ni$_2$O$_7$ (LNO) exhibits a remarkably high-temperature superconductivity of approximately 80 K under pressure, sparking considerable attentions. However, the nature of the spin, charge, and orbital order in LNO…

Superconductivity · Physics 2024-07-29 Binhua Zhang , Changsong Xu , Hongjun Xiang

Ternary Li halides, such as Li$_3$MeX$_6$ with, e.g., Me = In, Sc, Y and X = Cl, Br, are in the center of attention for battery applications as these materials might serve as ionic electrolytes. To fulfill their function, such electrolytes…

Materials Science · Physics 2024-01-12 Florian Stainer , H. Martin R. Wilkening

We study the temporal stability of stripe-type spin order in a layered nickelate with X-ray photon correlation spectroscopy and observe fluctuations on time scales of tens of minutes over a wide temperature range. These fluctuations show an…