Related papers: Mpemba Effect in Crystallization of Polybutene-1
The quantum Pontus-Mpemba effect (QPME) is a counterintuitive phenomenon wherein a quantum system relaxes more rapidly through a two-step evolution protocol than through direct evolution under a symmetric Hamiltonian alone. In this…
Motivated by a recent work on the metabolism of carbohydrates in bacteria, we study the kinetics and thermodynamics of two classic models for reversible polymerization, one preserving the total polymer concentration and the other one not.…
In the present work, crystallization in melts and poor-solvent solutions of semiflexible polymers with different concentration was studied by means of dissipative particle dynamics simulation technique. We use a coarse-grained polymer model…
Molecular dynamics simulations were performed for a polymer melt. In quiescent states, the inter-chain interaction energy supported by each particle takes relatively large values persistently for long times if the particle is close to an…
We discuss the crystallization process from the supersaturated melt in terms of its non-equilibrium properties. In particular, we quantify the amount of heat that is produced irreversibly when a suspension of hard spheres crystallizes. This…
Polymers with both soluble and insoluble blocks typically self-assemble into micelles, aggregates of a finite number of polymers where the soluble blocks shield the insoluble ones from contact with the solvent. Upon increasing…
$YbInCu_{4}$ and its alloys present discontinuous, first order iso-structural transitions at pressure dependent temperatures $T_V(P)$, where a local moment phase coexist with a renormalized Fermi liquid phase. We show that along the…
Slow relaxation processes spanning widely separated timescales pose fundamental challenges for probing steady-state properties and engineering functional quantum systems, such as quantum heat engines and quantum computing devices. We…
We demonstrate that the Mpemba paradox arises intrinsically from the release rate of energy initially stored in the covalent H-O part of the O:H-O bond in water albeit experimental conditions. Generally, heating raises the energy of a…
Inverse melting, in which a crystal reversibly transforms into a liquid or amorphous phase upon decreasing the temperature, is considered to be very rare in nature. The search for such an unusual equilibrium phenomenon is often hampered by…
We perform a direct numerical simulation (DNS) of the forced, incompressible two-dimensional Navier-Stokes equation coupled with the FENE-P equations for the polymer-conformation tensor. The forcing is such that, without polymers and at low…
We investigate the quantum Mpemba effect in a dissipative Dicke model, which consists of a spin-1/2 ensemble coupled to a bosonic mode, which in turn is coupled to a bosonic bath. We derive a sufficient criterion for occurrence of the…
Anomalous thermalization, particularly the crossings of temperature trajectories from different initial states termed Mpemba crossings (MPCs), have intrigued scientists for decades. While recent studies in quantum systems suggest that…
We enumerate all minimal energy packings (MEPs) for small single linear and ring polymers composed of spherical monomers with contact attractions and hard-core repulsions, and compare them to corresponding results for monomer packings. We…
Simulations are used to examine the microscopic origins of strain hardening in polymer glasses. While stress-strain curves for a wide range of temperature can be fit to the functional form predicted by entropic network models, many other…
Molecular dynamics simulations have been employed to study the formation of a physical (thermoreversible) gel by amphiphilic A-B-A triblock copolymers in aqueous solution. In order to mimic the structure of hydrogel-forming polypeptides…
Quantum Mpemba effect occurs when a quantum system, residing far away from the steady state, relaxes faster than a relatively nearer state. We look for the presence of this highly counterintuitive effect in the relaxation dynamics of the…
We report results of molecular-dynamics simulations of a model polymer melt consisting of short non-entangled chains in the supercooled state above the critical temperature of mode-coupling theory (MCT). To analyse the dynamics of the…
We examine nonequilibrium features of collapse behavior in model polymers with competing crystallization and glass transitions using extensive molecular dynamics simulations. By comparing to "colloidal" systems with no covalent bonds but…
The freeze-thaw cycling of particle-stabilised emulsions can alter the emulsion structure and stability. This could have significant consequences for using particle stabilisation in industrial applications where increased stability is…