Related papers: Mpemba Effect in Crystallization of Polybutene-1
Crystallization within the discrete spheres of a block copolymer mesophase was studied by time-resolved x-ray scattering. The cubic packing of microdomains, established by self-assembly in the melt, is preserved throughout crystallization…
We present results of temperature dependent measurements of dynamics of micellar nanoparticle - polymer composites of fixed volume fraction and variable polymer chain grafting density. For nanoparticles with lower grafting density we…
We address two central open problems in the theory of anomalous Mpemba-like relaxations: their extension beyond one spatial dimension and their consistent formulation in the thermodynamic limit. Our framework is the antiferromagnetic Ising…
Temperature changes during the growth of lamellar polymer crystals give rise to steps on the surface of the crystals. It has recently been suggested that these steps could provide important insights into the mechanism of polymer…
The ordering kinetics of standing cylinder-forming polystyrene-block-poly (methyl methacrylate) block copolymers (molecular weight: 39 kg/mol) close to the order-disorder transition is experimentally investigated following the temporal…
Experimental and modeling/simulation studies of phase equilibrium and growth morphologies of novel polymer-dispersed liquid crystal (PDLC) mixtures of PS (polystyrene) and liquid crystals that exhibit a direct isotropic/smectic-A (lamellar)…
The time evolution of a homogeneous bidisperse granular suspension is studied in the context of the Enskog kinetic equation. The influence of the surrounding viscous gas on the solid particles is modeled via a deterministic viscous drag…
We present experimental evidence for a first-order freezing/melting phase transition in a nonequilibrium system -- an oscillated two-dimensional isobaric granular fluid. The steady-state transition occurs between a gas and a crystal and is…
The features for the unsteady process of thermal equilibration ("the fast motions") in a one-dimensional harmonic crystal lying in a viscous environment (e.g., a gas) are under investigation. It is assumed that initially the displacements…
We present simulation results for a model polymer melt, consisting of short, nonentangled chains, in the supercooled state. The analysis focuses on the monomer dynamics, which is monitored by the incoherent intermediate scattering function.…
It has been revealed by mean-field theories and computer simulations that the nature of the collapse transition of a polymer is influenced by its bending stiffness $\epsilon_{\rm b}$. In two dimensions, a recent analytical work demonstrated…
Molecular process of polymer collapse was reproduced by isothermal molecular dynamics simulation. The initial polymer chains were obtained by mean of random walks in continuum space. Two potential models were considered to represent short…
In this work we analyze a non--interacting one dimensional polymer Bose--Einstein condensate in an harmonic trap within the semiclassical approximation. We use an effective Hamiltonian coming from the polymer quantization that arises in…
The Empemba effect (ME) is investigated in the context of ubiquitous quantum oscillating and two-level systems (TLS) using a novel approach (DOI 10.1088/1402-4896/ad97f1). Exact reduced density matrices for various initial states are…
We study the unfolding of a single polymer chain due to an external force. We use a simplified model which allows to perform all calculations in closed form without assuming a Boltzmann-Gibbs form for the equilibrium distribution.…
The beam-plasma instability, i.e. the response of the plasma bulk to the injection of supra thermal charged-particle beams, results to be appropriately characterized by a long-range interaction system. This physical system hosts a number of…
We study at- and out-of-equilibrium dynamics of a single homopolymer chain at low temperature using molecular dynamics simulations. The main quantities of interest are the average root mean square displacement of the monomers below the…
We study the non-equilibrium dynamics of bosons in a two-dimensional optical lattice after a sudden quench from the superfluid phase to the free-boson regime. The initial superfluid state is described approximately using both the Bogoliubov…
Four series of tensile loading-unloading tests are performed on isotactic polypropylene in the sub-yield domain of deformations at room temperature. In the first series, injection-molded specimens are used as produced, whereas in the other…
Based upon kinetic Monte Carlo simulations of crystallization in a simple polymer model we present a new picture of the mechanism by which the thickness of lamellar polymer crystals is constrained to a value close to the minimum…