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We investigate geometric phase (GP) effects in nonadiabatic transitions through a conical intersection (CI) in an N-dimensional linear vibronic coupling (ND-LVC) model. This model allows for the coordinate transformation encompassing all…

Chemical Physics · Physics 2017-09-13 Jiaru Li , Loïc Joubert-Doriol , Artur F. Izmaylov

A comprehensive description of molecular electron transfer reactions is essential for our understanding of fundamental phenomena in bio-energetics and molecular electronics. Experimental studies of molecular systems in condensed-phase…

Quantum Physics · Physics 2021-02-04 Frank Schlawin , Manuel Gessner , Andreas Buchleitner , Tobias Schaetz , Spiros S Skourtis

Isolating neutral and charged particles from the environment is essential in precision experiments. For decades, this has been achieved by trapping ions with radio-frequency (rf) fields and neutral particles with optical fields. Recently,…

Atomic Physics · Physics 2021-05-05 Tobias Schaetz

Classically, wave interference is a phenomenon that can be explained by considering only the waves themselves, that is, without the need to consider the apparatus that monitors or observes them. Thus, in classical theories, interference can…

Quantum Physics · Physics 2025-08-12 Alexandre Cesar Ricardo , Ciro Micheletti Diniz , Celso Jorge Villas-Bôas

Conical intersections are crossing points or lines between two or more adiabatic electronic potential energy surfaces in the multi-dimensional coordinate space of colliding atoms and molecules. Conical intersections and corresponding…

Atomic Physics · Physics 2023-04-19 Hui Li , Ming Li , Alexander Petrov , Eite Tiesinga , Svetlana Kotochigova

The subtle and fundamental issue of indistinguishability and interference between independent pathways to the same target state is examined in the context of coherent control of atomic and molecular processes, with emphasis placed on…

Quantum Physics · Physics 2015-05-18 Jiangbin Gong , Paul Brumer

The coherent interaction with ultrashort light pulses is a powerful strategy for monitoring and controlling the dynamics of wave packets in all states of matter. As light presents an oscillation period of a few femtoseconds ($T=2.6$~fs in…

Coherent wave control exploits the interference among multiple waves impinging on a system to suppress or enhance outgoing signals based on their relative phase and amplitude. This process inherently requires non-Hermiticity, in order to…

The geometric phase (GP) is a fundamental quantum effect arising from conical intersections (CIs), with profound consequences for vibronic energy levels. Standard imaginary-time path integral molecular dynamics (PIMD) based on the…

Chemical Physics · Physics 2026-04-22 Yu Zhai , Youhao Shang , Jian Liu

Giant atoms, which couple to a waveguide through multiple spatially separated connection points beyond the dipole approximation, provide a versatile route for quantum information processing based on interference-induced bound states in the…

Quantum Physics · Physics 2026-05-19 Ji Qi , Xiaojun Zhang , Honngwei Yu , Zhihai Wang

Quantum geometrical molecular dynamics provides a quantum geometric picture for understanding reactive dynamics, especially excited-state conical intersection dynamics, and also a numerically exact method for strongly correlated…

Chemical Physics · Physics 2026-01-26 Mo Sha , Bing Gu

Many recent experimental ultrafast spectroscopy studies have hinted at non-adiabatic dynamics indicating the existence of conical intersections, but their direct observation remains a challenge. The rapid change of the energy gap between…

Chemical Physics · Physics 2021-05-05 Deependra Jadoun , Mahesh Gudem , Markus Kowalewski

Realizing systems that support robust, controlled interactions between individual photons is an exciting frontier of nonlinear optics. To this end, one approach that has emerged recently is to leverage atomic interactions to create strong…

Quantum Physics · Physics 2016-08-11 James S. Douglas , Tommaso Caneva , Darrick E. Chang

We observe energy-dependent angle-resolved diffraction patterns in protons from strong-field dissociation of the molecular hydrogen ion H$_2^+$. The interference is a characteristic of dissociation around a laser-induced conical…

Atomic and Molecular Clusters · Physics 2016-04-11 Adi Natan , Matthew R Ware , Vaibhav S. Prabhudesai , Uri Lev , Barry D. Bruner , Oded Heber , Philip H Bucksbaum

Many-body systems of quantum interacting particles in which time-reversal symmetry is broken give rise to a variety of rich collective behaviors, and are therefore a major target of research in modern physics. Quantum simulators can…

Quantum Physics · Physics 2022-05-24 Yotam Shapira , Tom Manovitz , Nitzan Akerman , Ady Stern , Roee Ozeri

Recent progress in coherent quantum interactions between free-electron pulses and laser-induced near-field light have revolutionized electron wavepacket shaping. Building on these advancements, we numerically explore the potential of…

Optics · Physics 2023-08-30 Fatemeh Chahshouri , Nahid Talebi

We apply geometric phase ideas to coherent states to shed light on interference phenomenon in the phase space description of continuous variable Cartesian quantum systems. In contrast to Young's interference characterized by path lengths,…

Quantum Physics · Physics 2018-12-19 Mayukh N. Khan , S. Chaturvedi , N. Mukunda , R. Simon

Irradiation with light provides a powerful tool to interrogate, control or induce new quantum states of matter out of equilibrium, however a microscopic understanding of light-matter coupling in interacting electron systems remains a…

Strongly Correlated Electrons · Physics 2023-03-06 Wai Ting Tai , Martin Claassen

The geometric phase provides important mathematical insights to understand the fundamental nature and evolution of the dynamic response in a wide spectrum of systems ranging from quantum to classical mechanics. While the concept of…

Applied Physics · Physics 2025-03-19 Mohit Kumar , Fabio Semperlotti

Condensed-phase spectral line shapes encode the strength and timescale of interactions between molecules and their environments, yet these ideas are often difficult to introduce at the undergraduate level due to their reliance on formal…

Chemical Physics · Physics 2026-03-20 Saba Mahmoodpour , Andrew M. Moran
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