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Going beyond the bistability paradigm of the charge polarizations in ferroelectrics is highly desired for ferroelectric (FE) memory devices toward ultra-high-density information storage. Here, we propose to build multistates by combining…

Materials Science · Physics 2025-03-03 Chuhan Tang , Zhiqiang Tian , Tao Ouyang , Anlian Pan , Mingxing Chen

Van der Waals "sliding" ferroelectric bilayers, whose electric polarization is locked to the interlayer alignment, show promise for future non-volatile memory and other nanoelectronic devices. These applications require a fuller…

Statistical Mechanics · Physics 2025-09-19 Benjamin Remez , Moshe Goldstein

The interlayer coupling is emerging as a new parameter for tuning the physical properties of two-dimensional (2D) van der Waals materials. When two identical semiconductor monolayers are stacked with a twist angle, the periodic interlayer…

Mesoscale and Nanoscale Physics · Physics 2022-09-16 Jing Liang , Dongyang Yang , Jingda Wu , Jerry I Dadap , Kenji Watanabe , Takashi Taniguchi , Ziliang Ye

Vertically stacked layers derived from non-ferroelectric monolayers offer a promising route to two-dimensional (2D) ferroelectrics, where polarization switching occurs via interlayer sliding at sub-unit cell scales. Here, we develop a…

Materials Science · Physics 2025-03-03 Byeoksong Lee , Minki Lee , Joongoo Kang

Electric polarization and metallicity are long believed not to coexist until the emergence of exceptionally rare material examples including the bulk polar metals and more recently two-dimensional (2D) van der Waals (vdW) materials such as…

Mesoscale and Nanoscale Physics · Physics 2025-10-13 Zhou Zhou , Xiyao Peng , Jianfeng Bi , Fei Xue , Jie Jiang , Huizhen Wu , Zhiwen Shi , Haoliang Qian , Toshikaze Kariyado , Sihan Zhao

Two-dimensional materials with ferroelectric properties break the size effect of conventional ferroelectric materials and unlock unprecedented potentials of ferroelectric-related application at small length scales. In this work, using…

Materials Science · Physics 2022-03-25 Bo Xu , Junkai Deng , Xiangdong Ding , Jun Sun , Jefferson Zhe Liu

According to the recent studies on sliding/moire ferroelectricity, most 2D van der Waals nonferroelectric monolayers can become ferroelectric via multilayer stacking. In this paper we propose that similar strategy can be used to induce…

Materials Science · Physics 2025-07-24 Yuxuan Sheng , Junwei Liu , Jia Zhang , Menghao Wu

Through stacking engineering of two-dimensional (2D) materials, a switchable interface polarization can be generated through interlayer sliding, so called sliding ferroelectricity, which is advantageous over the traditional ferroelectricity…

Materials Science · Physics 2024-08-01 Qingrong Liang , Guozhong Zheng , Liu Yang , Shoujun Zheng

Twisted heterostructures of two-dimensional crystals offer almost unlimited scope for the design of novel metamaterials. Here we demonstrate a room-temperature ferroelectric semiconductor that is assembled using mono- or few- layer MoS2.…

Vertical ferroelectricity where a net dipole moment appears as a result of in-plane ionic displacements has gained enormous attention following its discovery in transition metal dichalcogenides. Based on first-principles calculations, we…

Materials Science · Physics 2021-10-29 Xiaonan Ma , Chang Liu , Wei Ren , Sergey A. Nikolaev

The so-called interlayer-sliding ferroelectricity was recently proposed as an unconventional route to pursuit electric polarity in van der Waals multi-layers, which was already experimentally confirmed in WTe$_2$ bilayer even though it is…

Materials Science · Physics 2021-08-17 Ning Ding , Jun Chen , Churen Gui , Haipeng You , Xiaoyan Yao , Shuai Dong

Van der Waals (vdW) materials have greatly expanded our design space of heterostructures by allowing individual layers to be stacked at non-equilibrium configurations, for example via control of the twist angle. Such heterostructures not…

Mesoscale and Nanoscale Physics · Physics 2022-02-04 Xirui Wang , Kenji Yasuda , Yang Zhang , Song Liu , Kenji Watanabe , Takashi Taniguchi , James Hone , Liang Fu , Pablo Jarillo-Herrero

Sliding ferroelectricity in bilayer van der Waals materials exhibits ultrafast switching speed and fatigue resistance during the polarization switching, offering an avenue for the design of memories and neuromorphic devices. The unique…

Materials Science · Physics 2025-02-21 Yubai Shi , Yuxiang Gao , Ri He , Hua Wang , Binwen Zhang , Zhicheng Zhong

2D intercorrelated ferroelectrics, exhibiting a coupled in-plane and out-of-plane ferroelectricity, is a fundamental phenomenon in the field of condensed-mater physics. The current research is based on the paradigm of bi-directional…

Materials Science · Physics 2020-11-24 Yan Liang , Shiying Shen , Baibiao Haung , Ying Dai , Yandong Ma

Two-dimensional (2D) van der Waals (vdW) materials and their bilayers have stimulated enormous interests in fundamental researches and technological applications. Recently, a group of 2D vdW III2-VI3 materials with out-of-plane…

Materials Science · Physics 2021-12-13 Junlei Zhao , Xinyu Wang , Haohao Chen , Zhaofu Zhang , Mengyuan Hua

The combination of metallicity and ferroelectricity breaks traditional boundaries, paving new avenues for innovative electronic materials and devices. This breakthrough is particularly notable, as metallicity and ferroelectricity have…

Materials Science · Physics 2024-04-09 Jiagang Zhang , Ting Zhang

Van der Waals (vdW) layered materials have rather weaker interlayer bonding than the intra-layer bonding, therefore the exfoliation along the stacking direction enables the achievement of monolayer or few layers vdW materials with emerging…

Sliding ferroelectricity is a unique type of polarity recently observed in a properly stacked van der Waals bilayer. However, electric-field control of sliding ferroelectricity is hard and could induce large coercive electric fields and…

Materials Science · Physics 2024-03-13 Jian Wang , Xu Li , Xingyue Ma , Lan Chen , Jun-Ming Liu , Chun-Gang Duan , Jorge Íñiguez-González , Di Wu , Yurong Yang

The bistability of charge polarization in ferroelectric materials has long been the basis of ferroelectric devices. However, the ferroelectricity tends to be vanishing as the thickness of materials is reduced to a few nanometers or thinner…

Materials Science · Physics 2023-12-22 Guoliang Yu , Shengxian Li , Anlian Pan , Mingxing Chen , Zhenyu Zhang

Two-dimensional (2D) ferroelectric semiconductors present opportunities for integrating ferroelectrics into high-density ultrathin nanoelectronics. Among the few synthesized 2D ferroelectrics, $\alpha$-In$_2$Se$_3$, known for its…

Materials Science · Physics 2024-02-29 Liyi Bai , Changming Ke , Zhongshen Luo , Tianyuan Zhu , Lu You , Shi Liu