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The possibility that metals may support ferroelectricity is an open issue. Anderson and Blount showed that certain martensitic transitions involve inversion symmetry breaking and the formal existence of a polar axis, so 'metallic…

Materials Science · Physics 2016-04-08 Alessio Filippetti , Vincenzo Fiorentini , Francesco Ricci , Pietro Delugas , Jorge Íñiguez

Polar metals are defined by the coexistence of metallicity and polar crystal structure. They have potential applications in non-linear optics, ferroelectric devices, and quantum devices. Meanwhile, ferroelectric-ferromagnetic (FE-FM)…

Strongly Correlated Electrons · Physics 2021-01-04 Xu Sheng , Yanni Gu , Xiao Shen

Polar metals are an intriguing class of materials in which electric polarisation and metallicity can coexist within a single phase. The unique properties of polar metals challenge expectations, making way for the exploration of exotic…

Strongly Correlated Electrons · Physics 2025-02-03 Evie Ladbrook , Urmimala Dey , Nicholas C. Bristowe , Robin S. Perry , Dominik Daisenberger , Mark R. Warren , Mark S. Senn

We examine the electronic properties of newly discovered "ferroelectric" metal LiOsO$_3$ combining density-functional and dynamical mean-field theories. We show that the material is close to a Mott transition and that electronic…

Materials Science · Physics 2015-08-26 Danilo Puggioni , Gianluca Giovannetti , Massimo Capone , James M. Rondinelli

This paper provides a brief introduction to the phenomenological aspects of the polarization in ferrroelectric materials, and then an analysis of a few selected topics related to the modelling of ferroelectrics. The description of…

Emerging Technologies · Computer Science 2023-11-08 David Esseni , Francesco Driussi , Daniel Lizzit , Marco Massarotto , Mattia Segatto

Polar metals are an intriguing class of materials that simultaneously host free carriers and polar structural distortions. Despite the name "polar metal," however, most well-studied polar metals are poor electrical conductors. Here, we…

Polar metals with ferroelectric-like displacements in metals have been achieved recently, half century later than Anderson and Blount's prediction. However, the genuine ferroelectricity with electrical dipolar switching has not yet been…

Flexoelectricity (coupling between polarization and strain gradients) is a property of all dielectric materials that has been theoretically known for decades, but it is only relatively recently that it has begun to attract experimental…

Materials Science · Physics 2018-10-17 P. Vales-Castro , Krystian Roleder , Lei Zhao , Jing-Feng Li , Dariusz Kajewski , Gustau Catalan

Since conduction electrons of a metal screen effectively the local electric dipole moments, it was widely believed that the ferroelectric-like distortion cannot occur in metals. Recently, metallic LiOsO3, was discovered to be the first…

Materials Science · Physics 2014-10-01 Hongjun Xiang

The polar metal is a material that hosts both polar distortion and metallicity. Such a material is expected to show exotic magneto-electric phenomena if superconducts. Here, we theoretically explore ferroelectric and superconducting…

Superconductivity · Physics 2021-05-26 Minjae Ghim , Nobuya Sato , Ryosuke Akashi , Seung-Hoon Jhi , Shinji Tsuneyuki

Ferroelectric-like metals are a relatively rare class of materials that have ferroelectric-like distortion and metallic conductivity. LiOsO$_3$ is the first demonstrated and the most investigated ferroelectric-like metal. The presence of…

Materials Science · Physics 2020-08-05 Rui-Chun Xiao , Ding-Fu Shao , Wenjuan Huang , Hua Jiang

Ferroelectricity-the switchable intrinsic electric polarization-has not yet been attained in a metal experimentally and is in fact generally deemed irreconcilable with free carriers, although polar metal has been achieved recently.…

Two different ferroelectric materials, Sr$_{0.95}$Ba$_{0.05}$TiO$_3$ and Sr$_{0.985}$Ca$_{0.015}$TiO$_3$, can be turned into polar metals with broken centrosymmetry via electron doping. Systematic substitution of Nb$^{5+}$ for Ti$^{4+}$ has…

Superconductivity · Physics 2022-12-02 Yasuhide Tomioka , Naoki Shirakawa , Isao H. Inoue

Strong coupling among spontaneous structural symmetric breaking, magnetism and metallicity in an intrinsic polar magnetic metal can give rise to novel physical phenomena and holds great promise for applications in spintronics. Here, we…

Materials Science · Physics 2025-11-04 Hong-Fei Huang , Houssam Sabri , Jiadong Zang , Jie-Xiang Yu

We demonstrate computationally the existence of magnetoelectric multipoles, arising from the second order term in the multipole expansion of a magnetization density in a magnetic field, in noncentrosymmetric magnetic metals. While…

Materials Science · Physics 2021-03-09 Florian Thöle , Nicola A. Spaldin

We review the phenomenology of coupled magnetic and electric order parameters for systems in which ferroelectric and incommensurate magnetic order occur simultaneously. We discuss the role that such materials might play in fabricating novel…

Materials Science · Physics 2007-05-23 A. B. Harris , G. Lawes

Ferroelectrics with spontaneous electric polarization play an essential role in today's device engineering, such as capacitors and memories. Their physical properties are further enriched by suppressing the long-range polar order, as is…

Materials Science · Physics 2017-03-14 H. Sakai , K. Ikeura , M. S. Bahramy , N. Ogawa , D. Hashizume , J. Fujioka , Y. Tokura , S. Ishiwata

The recent quest for improved functional materials like high permittivity dielectrics and/or multiferroics has triggered an intense wave of research. Many materials have been checked for their dielectric permittivity or their polarization…

Materials Science · Physics 2009-11-13 Mario Maglione , M. A. Subramanian

Recent advances in the synthesis of polar molecular materials have produced practical alternatives to ferroelectric ceramics, opening up exciting new avenues for their incorporation into modern electronic devices. However, in order to…

Metals cannot exhibit ferroelectricity because static internal electric fields are screened by conduction electrons, but in 1965, Anderson and Blount predicted the possibility of a ferroelectric metal, in which a ferroelectric-like…