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Lead-free halide double perovskites with the formula of quaternary A$_2^+$B'B'$^{3+}$X$_6^-$ have recently attracted intense interest as alternatives to lead-halide-perovskite-based optoelectronic materials for their non-toxicity and…

Materials Science · Physics 2018-08-17 Tianshu Li , Xingang Zhao , Dongwen Yang , Mao-Hua Du , Lijun Zhang

Halide perovskites have emerged as revolutionary materials for high performance photovoltaics and optoelectronics due to their superior optoelectronic properties. The physical origin for the superior optoelectronic properties of halide…

Applied Physics · Physics 2023-08-04 Xiaoming Wen , Baohua Jia

Light-matter interactions in semiconductor systems are uniformly treated within the electric dipole (ED) approximation, as multipolar interactions are considered "forbidden". Here, we demonstrate that this approximation inadequately…

Perovskite quantum dots (PQDs) provide a robust solution-based approach to efficient solar cells, bright light-emitting devices, and quantum sources of light. Quantifying heterogeneity and understanding coupling between dots is critical for…

Perovskite light-emitting diodes (PeLEDs) have emerged as a strong contender for next-generation display and information technologies. However, similar to perovskite solar cells, the poor operational stability remains the main obstacle…

Halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them several crystallize in low symmetry lattice structures like trigonal, hexagonal, orthorhombic…

Materials Science · Physics 2017-11-15 A. Koliogiorgos , S. Baskoutas , I. Galanakis

In this paper we analyze the band-structure of two-dimensional (2D) halide perovskites by considering structures related to the simpler case of the series, (BA)$_2$PbI$_4$, in which PbI$_4$ layers are intercalated with butylammonium…

Materials Science · Physics 2023-07-24 Efstratios Manousakis

The spectacular performance of halide perovskites in optoelectronic devices is rooted in their tolerance to defects. Previous studies showed that defects in these materials generate shallow electronic states. However, how these shallow…

Materials Science · Physics 2025-05-20 Frederico P. Delgado , Frederico Simões , Leeor Kronik , Waldemar Kaiser , David A. Egger

Abundant chemical diversity and structural tunability make organic-inorganic hybrid perovskites (OIHPs) a rich ore for ferroelectrics. However, compared with their inorganic counterparts such as BaTiO$_3$, their ferroelectric key…

Materials Science · Physics 2023-05-22 Kun Ding , Haoshen Ye , Changyuan Su , Yu-An Xiong , Guowei Du , Yu-Meng You , Zhi-Xu Zhang , Shuai Dong , Yi Zhang , Da-Wei Fu

Halide perovskites are a promising class of materials for optoelectronic and photovoltaic applications, exhibiting high power conversion efficiency due to strong light absorption and long carrier diffusion lengths. While various aspects of…

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

Materials Science · Physics 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao

As the field of metal halide perovskites (MHP) matures, state-of-the-art techniques to measure basic properties such as the band gap and exciton binding energy continue to produce inconsistent values. This issue is persistent even for 2D…

Mesoscale and Nanoscale Physics · Physics 2021-09-21 Kameron R. Hansen , C. Emma McClure , John S. Colton , Luisa Whittaker-Brooks

It has been long known that numerous halide and oxide perovskites can have non-ideal octahedra, showing tilting, rotation, and metal atom displacements. It has also been known that compounds that have at low temperatures a single structural…

Materials Science · Physics 2020-05-06 Xingang Zhao , Gustavo M. Dalpian , Zhi Wang , Alex Zunger

Organic-inorganic hybrid halide perovskites have ignited tremendous interests for photovoltaic applications. However, their nonlinear optical response has not been studied although many of these structures lack the centrosymmetry and…

Materials Science · Physics 2020-02-14 Wenshen Song , Guang-Yu Guo , Su Huang , Lan Yang , Li Yang

Metal halide perovskites are attracting tremendous interest for a variety of optoelectronic applications. The ability to tune the perovskite bandgap by tweaking the chemical compositions opens up new applications as coloured emitters and as…

It is unmistakably paradoxical that the weakest point of the photoactive organic-inorganic hybrid perovskite is its instability against light. Why and how perovskites break down under light irradiation and what happens at the atomistic…

Materials Science · Physics 2017-09-14 Kwisung Kwak , Eunhak Lim , Namyoung Ahn , Jiyoung Heo , Kijoon Bang , Seong Keun Kim , Mansoo Choi

The temperature-dependent phase transitions in Ruddlesden-Popper oxides with perovskite bilayers have been under increased scrutiny in recent years due to the so-called hybrid improper ferroelectricity that some chemical compositions…

Materials Science · Physics 2021-12-08 Gabriel Clarke , Dominik Daisenberger , X. Luo , S. W. Cheong , Nicholas C. Bristowe , Mark S. Senn

We describe a first open-access database of experimentally investigated hybrid organic-inorganic materials with two-dimensional (2D) perovskite-like crystal structure. The database includes 515 compounds, containing 180 different organic…

Solvent-solute interactions in precursor solutions of lead halide perovskites (LHP) critically impact the quality of solution-processed materials, as they lead to the formation of a variety of poly-iodoplumbates that act as building blocks…

Materials Science · Physics 2021-03-10 Ana M. Valencia , Oleksandra Shargaieva , Richard Schier , Eva Unger , Caterina Cocchi

The use of mixed cation absorber composition was considered as an efficient strategy to mitigate the degradation effects in halide perovskite solar cells. Despite the reports about partial stabilization at elevated temperatures, unfavorable…