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We investigate the electronic and structural changes at the nanoscale in vanadium dioxide (VO2) in the vicinity of its thermally driven phase transition. Both electronic and structural changes exhibit phase coexistence leading to…

We report the simultaneous measurement of the structural and electronic components of the metal-insulator transition of VO$_2$ using electron and photoelectron spectroscopies and microscopies. We show that these evolve over different…

Strongly Correlated Electrons · Physics 2014-11-18 J. Laverock , S. Kittiwatanakul , A. A. Zakharov , Y. R. Niu , B. Chen , S. A. Wolf , J. W. Lu , K. E. Smith

The temperature-induced structural and electronic transformation in VO$_2$ between the monoclinic M1 and tetragonal rutile phases was studied by means of \textit{ab initio} molecular dynamics, based on density functional theory with Hubbard…

Materials Science · Physics 2017-10-11 Dušan Plašienka , Roman Martoňák , Marcus C. Newton

We use apertureless scattering near-field optical microscopy (SNOM) to investigate the nanoscale optical response of vanadium dioxide (VO2) thin films through a temperature-induced insulator-to-metal transition (IMT). We compare images of…

Mesoscale and Nanoscale Physics · Physics 2018-10-24 H. T. Stinson , A. Sternbach , O. Najera , R. Jing , A. S. Mcleod , T. V. Slusar , A. Mueller , L. Anderegg , H. T. Kim , M. Rozenberg , D. N. Basov

Direct imaging and quantification of actuation in nanostructures that undergo structural phase transitions could advance our understanding of collective phenomena in the solid state. Here, we demonstrate visualization of structural phase…

Materials Science · Physics 2013-06-18 Viswanath Balakrishnan , Shriram Ramanathan

The debate about whether the insulating phases of vanadium dioxide (VO2) can be described by band theory or must be described by a theory of strong electron correlations remains unresolved even after decades of research. Energy-band…

Materials Science · Physics 2017-03-15 Sheng Xu , Xiao Shen , Kent A. Hallman , Richard F. Haglund , Sokrates T. Pantelides

The insulator-to-metal transition (IMT) of the simple binary compound of vanadium dioxide VO$_2$ at $\sim 340$ K has been puzzling since its discovery more than five decades ago. A wide variety of photon and electron probes have been…

Strongly Correlated Electrons · Physics 2014-12-18 Brian T. O'Callahan , Joanna M. Atkin , Andrew C. Jones , Jae Hyung Park , David Cobden , Markus B. Raschke

A theory of the metal-insulator transition in vanadium dioxide from the high-temperature rutile to the low- temperature monoclinic phase is proposed on the basis of cluster dynamical mean field theory, in conjunction with the density…

Strongly Correlated Electrons · Physics 2009-11-10 S. Biermann , A. Poteryaev , A. I. Lichtenstein , A. Georges

We have investigated the charge dynamics of VO2 by optical reflectivity measurements. Optical conductivity clearly shows a metal-insulator transition. In the metallic phase, a broad Drude-like structure is observed. On the other hand, in…

Strongly Correlated Electrons · Physics 2009-11-11 K. Okazaki , S. Sugai , Y. Muraoka , Z. Hiroi

We report modulation of a reversible phase transition in VO2 films by hydrogen doping. A metallic phase and a new insulating phase are successively observed at room temperature as the doping concentration increases. It is suggested that the…

Strongly Correlated Electrons · Physics 2017-09-27 Shi Chen , Zhaowu Wang , Lele Fan , Yuliang Chen , Hui Ren , Heng Ji , Douglas Natelson , Yingying Huang , Jun Jiang , Chongwen Zou

An electrical study of thin $VO_{2}$ films in the vicinity of the structural phase transition at $68^{0}C$ shows (a) that the electrical resistance $R$ follows $log (R)$ $\propto$ $-T$ over the $T$-range, $20 < T < 80 ^{0}C$ covering both…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 R. G. Mani , S. Ramanathan

Vanadium dioxide, an archetypal correlated-electron material, undergoes an insulator-metal transition near room temperature that exhibits electron-correlation-driven and structurally-driven physics. Using ultrafast optical spectroscopy and…

Vanadium dioxide (VO$_2$) has received significant interest in the context of nanophotonic metamaterials and memories owing to its reversible insulator-metal transition associated with significant changes in its optical and electronic…

Mesoscale and Nanoscale Physics · Physics 2025-02-25 Peter Kepič , Michal Horák , Jiří Kabát , Vlastimil Křápek , Andrea Konečná , Tomáš Šikola , Filip Ligmajer

The insulator-to-metal transition (IMT) in strongly correlated materials, such as vanadium dioxide (VO2), offers a transformative platform for next-generation adaptive electronics and neuromorphic computing. However, harnessing this…

Materials Science · Physics 2026-04-22 Siyuan Huang , Shuaishuai Sun , Yin Shi , Wentao Wang , Chunhui Zhu , Huanfang Tian , Huaixin Yang , Jun Li , Jianqi Li

We investigated nonlinear conduction in bulk single crystals of VO2 with precise temperature control. Two distinct nonequilibrium phenomena were identified: a gradual reduction of the charge gap and a current-induced insulator-metal…

Strongly Correlated Electrons · Physics 2025-05-13 Akitoshi Nakano , Masato Imaizumi , Ichiro Terasaki

Using light to control transient phases in quantum materials is an emerging route to engineer new properties and functionality, with both thermal and non-thermal phases observed out of equilibrium. Transient phases are expected to be…

The metal insulator transition of nano-scaled $VO_2$ devices is drastically different from the smooth transport curves generally reported. The temperature driven transition occurs through a series of resistance jumps ranging over 2 decades…

Mesoscale and Nanoscale Physics · Physics 2008-10-31 Amos Sharoni , Juan Gabriel Ramírez , Ivan K. Schuller

Thin films of VO$_2$ on different substrates, Al$_2$O$_3$ and SiO$_2$/Si, have been prepared and characterized from room temperature up to 360 K. From the band structure in the rutile metallic phase and in the monoclinic insulating phase…

Strongly Correlated Electrons · Physics 2016-09-21 Tobias Peterseim , Martin Dressel , Marc Dietrich , Angelika Polity

Vanadium dioxide is currently considered as one of the most promising metarials for oxide elcteronics. Both planar and sandwich thin-film MOM devices based on VO2 exhibit electrical switching with an S-shaped I-V characteristic, and this…

The metal-insulator transition (MIT) in vanadium dioxide (VO2) has the potential to lead to a number of disruptive technologies, including ultra-fast data storage, optical switches, and transistors which move beyond the limitations of…

Strongly Correlated Electrons · Physics 2018-02-28 T. J. Huffman , D. J. Lahneman , S. L. Wang , T. Slusar , Bong-Jun Kim , Hyun-Tak Kim , M. M. Qazilbash