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Related papers: Diffusiophoresis in the presence of a pH gradient

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Diffusiophoresis of charged particles in the presence of electrolytes has been extensively studied in the literature. However, in these setups, particles typically move in a single direction, either up or down the electrolyte gradient.…

Soft Condensed Matter · Physics 2025-06-09 Ethan Coleman , Ankur Gupta

Electrolytic diffusiophoresis refers to directional migration of colloids due to interfacial forces that develop in response to local electrolytic concentration ($c$) gradients. This physicochemical transport provides an efficient…

Soft Condensed Matter · Physics 2025-06-27 Kushagra Tiwari , Jitendra Dhakar , Kapil Upadhyaya , Akash Choudhary

The separation of colloidal particles based solely on their surface properties is a highly challenging task. This study demonstrates that diffusiophoresis and diffusioosmosis enable the continuous separation of carboxylate polystyrene…

In this letter, we show that pore-scale diffusiophoresis of colloidal particles along local salt gradients manifests in the macroscopic dispersion of particles in a porous medium. Despite is transient character, this microscopic phenomenon…

Soft Condensed Matter · Physics 2023-03-16 Mamta Jotkar , Pietro de Anna , Marco Dentz , Luis Cueto-Felgueroso

We study the diffusiophoretic self-propulsion of a colloidal catalytic particle due to a surface chemical reaction in a vicinity of a solid wall. Diffusiophoresis is a chemico-mechanical transduction mechanism in which a concentration…

Soft Condensed Matter · Physics 2016-06-22 Ali Mozaffari , Nima Sharifi-Mood , Joel Koplik , Charles Maldarelli

Diffusiophoresis (DP) refers to the migration of particles driven by a solute concentration gradient in a liquid. Observations in the case of molecular neutral solutes are rather scarce, due to the low drift velocities in dilute solutions,…

We present the diffusiophoresis of ellipsoidal particles induced by ionic solute gradients. Contrary to the common expectation that diffusiophoresis is shape independent, here we show experimentally that this assumption breaks down when the…

Soft Condensed Matter · Physics 2023-05-31 Viet Sang Doan , Dong-Ook Kim , Craig Snoeyink , Ying Sun , Sangwoo Shin

We report an experimental study on the manipulation of colloidal particles in a drop sitting on a hydrogel. The manipulation is achieved by diffusiophoresis, which describes a directed motion of particles induced by solute gradients. By…

Soft Condensed Matter · Physics 2017-10-17 François Boulogne , Sangwoo Shin , Julien Dervaux , Laurent Limat , Howard A. Stone

In the presence of a chemically active particle, a nearby chemically inert particle can respond to a concentration gradient and move by diffusiophoresis. The nature of the motion is studied for two cases: first, a fixed reactive sphere and…

Soft Condensed Matter · Physics 2018-06-25 Shang Yik Reigh , Prabha Chuphal , Snigdha Thakur , Raymond Kapral

A migration of charged particles relative to a solvent, caused by a gradient of salt concentration and termed a diffusiophoresis, is of much interest being exploited in many fields. Existing theories deal with diffusiophoresis of passive…

Soft Condensed Matter · Physics 2024-10-15 Evgeny S. Asmolov , Olga I. Vinogradova

Diffusiophoretic motion induced by gradients of dissolved species has enabled the manipulation of colloids over large distances, spanning hundreds of microns. Nonetheless, studies have primarily focused on simple geometries that feature 1D…

Soft Condensed Matter · Physics 2024-04-12 Carlos A. Silvera Batista , Kun Wang , Hannah Blake , Vivian Nwosu-Madueke , Sophie Marbach

Electro- and diffusio- phoresis of particles correspond respectively to the transport of particles under electric field and solute concentration gradients. Such interfacial transport phenomena take their origin in a diffuse layer close to…

Soft Condensed Matter · Physics 2020-04-22 Sophie Marbach , Hiroaki Yoshida , Lydéric Bocquet

We suppose that a rigid spherical particle is put into a binary fluid mixture with the critical composition in the homogeneous phase near the demixing critical point. A short-range interaction is assumed between each component and the…

Fluid Dynamics · Physics 2022-05-26 Youhei Fujitani

Microparticles migrate in response to gradients in solute concentration through diffusiophoresis and diffusioosmosis. Merging streams of fluid with distinct solute concentrations is a common strategy for producing a steady concentration…

Fluid Dynamics · Physics 2023-06-01 Robben E. Migacz , Guillaume Durey , Jesse T. Ault

Colloidal spheres with a partial platinum surface coating perform auto-phoretic motion when suspended in hydrogen peroxide solution. We present a theoretical analysis of the self-propulsion velocity of these particles using a continuum…

Soft Condensed Matter · Physics 2015-02-12 Joost de Graaf , Georg Rempfer , Christian Holm

By means of a matched asymptotic expansions approach the electrophoretic velocity and zeta potential of a catalytic particle that uniformly releases ions have been investigated. Attention is focused on large, compared to diffuse layer,…

Soft Condensed Matter · Physics 2024-10-15 Evgeny S. Asmolov , Victoria A. Vasileva , Olga I. Vinogradova

The more we learn about the cytoplasm of cells, the more we realise that the cytoplasm is not uniform but instead is highly inhomogeneous. In any inhomogeneous solution, there are concentration gradients, and particles move either up or…

Subcellular Processes · Quantitative Biology 2019-04-03 Richard P. Sear

The influence of a fluid-fluid interface on self-phoresis of chemically active, axially symmetric, spherical colloids is analyzed. Distinct from the studies of self-phoresis for colloids trapped at fluid interfaces or in the vicinity of…

Soft Condensed Matter · Physics 2018-01-22 P. Malgaretti , M. N. Popescu , S. Dietrich

We theoretically and numerically investigate the instabilities driven by diffusiophoretic flow, caused by a solutal concentration gradient along a reacting surface. The important control parameter is the Peclet number Pe, which quantifies…

Fluid Dynamics · Physics 2021-06-09 Yibo Chen , Kai Leong Chong , Luoqin Liu , Roberto Verzicco , Detlef Lohse

We examine a mechanism of locomotion of active particles whose surface is uniformly coated with mobile enzymes. The enzymes catalyze a reaction that drives phoretic flows but their homogeneous distribution forbids locomotion by symmetry. We…

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