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We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , V. A. Dzuba , V. V. Flambaum

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

We evaluate the feasibility of using magnetic-dipole (M1) transitions in highly-charged ions as a basis of an optical atomic clockwork of exceptional accuracy. We consider a range of possibilities, including M1 transitions between clock…

Atomic Physics · Physics 2015-06-23 V. I. Yudin , A. V. Taichenachev , A. Derevianko

We review a number of highly charged ions which have optical transitions suitable for building extremely accurate atomic clocks. This includes ions from Hf$^{12+}$ to U$^{34+}$, which have the $4f^{12}$ configuration of valence electrons,…

Atomic Physics · Physics 2015-06-23 V. A. Dzuba , V. V. Flambaum

We examine energy level-crossings of fine-structure (FS) levels in the heavier highly charged ions (HCIs) with $d^6$ and $d^8$ configurations. From the analysis, we find that some of these HCIs are tailor-made for atomic clocks with quality…

Atomic Physics · Physics 2023-07-28 Yan-mei Yu , B. K. Sahoo

Recent experimental progress in cooling, trapping, and quantum logic spectroscopy of highly-charged ions (HCIs) made HCIs accessible for high resolution spectroscopy and precision fundamental studies. Based on these achievements, we explore…

We identify Ba$^{4+}$ (Te-like) as a promising candidate for a high-accuracy optical clock. The lowest-lying electronic states are part of a $^3P_J$ fine structure manifold with anomalous energy ordering, being non-monotonic in $J$. We…

Atomic Physics · Physics 2020-10-26 Kyle Beloy , Vladimir A. Dzuba , Samuel M. Brewer

Recent developments in frequency metrology and optical clocks have been based on electronic transitions in atoms and singly charged ions as references. These systems have enabled relative frequency uncertainties at a level of a few parts in…

Atomic Physics · Physics 2018-12-06 M. G. Kozlov , M. S. Safronova , J. R. Crespo López-Urrutia , P. O. Schmidt

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

We propose here a few selective highly charged ions (HCIs), namely Ni$^{12+}$ and Cu$^{13+}$, Pd$^{12+}$ and Ag$^{13+}$, that not only promise to be very high accurate optical clocks below $10^{-19}$ uncertainties, but also offer quality…

Atomic Physics · Physics 2018-04-25 Yan-mei Yu , B. K. Sahoo

We propose 10 highly-charged ions as candidates for the development of next generation atomic clocks, quantum information, and search for $\alpha$-variation. They have long-lived metastable states with transition frequencies to the ground…

Atomic Physics · Physics 2015-06-19 M. S. Safronova , V. A. Dzuba , V. V. Flambaum , U. I. Safronova , S. G. Porsev , M. G. Kozlov

Optical clocks are the apotheosis of precision measurement, but they require frequent maintenance by scientists. The supporting laser systems are a particularly demanding component of these instruments. To reduce complexity and increase…

Atomic Physics · Physics 2023-05-24 C. A. Holliman , M. Fan , A. M. Jayich

We perform detailed calculations of the electronic structure of the Os$^{16+}$ ion and demonstrate that it has several metastable states which can be used for very accurate optical clocks. The clocks are highly sensitive to manifestations…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

Level crossings in the ground state of ions occur when the nuclear charge Z and ion charge Z_ion are varied along an isoelectronic sequence until the two outermost shells are nearly degenerate. We examine all available level crossings in…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

We study the Ho$^{14+}$ ion as a candidate for extremely accurate and stable optical atomic clock which is sensitive to the time variation of the fine structure constant. We demonstrate that the proposed system has all desired features…

Atomic Physics · Physics 2015-03-05 V. A. Dzuba , V. V. Flambaum , Hidetoshi Katori

Highly charged ions (HCIs) are insensitive to external perturbations and are attractive for the development of ultrastable clocks. However, only a few HCI candidates are known to provide optical clock transitions. In this Letter, we show…

Atomic Physics · Physics 2025-01-07 Chunhai Lyu , Christoph H. Keitel , Zoltán Harman

Optical atomic clocks are the most accurate measurement devices ever constructed and have found many applications in fundamental science and technology. The use of highly charged ions (HCI) as a new class of references for highest accuracy…

We identify two metastable excited states in Sm$ ^{10+} $ highly charged ion as candidates for high accuracy optical clocks. Several atomic properties relevant to optical clock development are calculated using relativistic many-body…

High Energy Physics - Phenomenology · Physics 2024-09-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

The possibility of using neutral and double ionized erbium for atomic clocks of high precision is investigated. In both cases the narrow electric quadrupole clock transition between the ground and first exited state of the same…

Atomic Physics · Physics 2015-06-16 A. Kozlov , V. A. Dzuba , V. V. Flambaum

Highly charged ions (HCIs) are promising candidates for the next generation of atomic clocks, owing to their tightly bound electron cloud, which significantly suppresses the common environmental disturbances to the quantum oscillator. Here…

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