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Highly charged ions of heavy actinides from uranium to einsteinium are studied theoretically to find optical transitions sensitive to the variation of the fine structure constant. A number of promising transitions have been found in ions…

Atomic Physics · Physics 2024-05-21 V. A. Dzuba , V. V. Flambaum

Divalent atoms and ions with a singlet $S$ ground state and triplet $P$ excited state form the basis of many high-precision optical atomic clocks. Along with the metastable $^{3}\mathrm{P}_{0}$ clock state, these atomic systems also have a…

We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel…

Atomic Physics · Physics 2020-04-29 C. Cheung , M. S. Safronova , S. G. Porsev , M. G. Kozlov , I. I. Tupitsyn , A. I. Bondarev

We perform calculations of electronic structure of Cm$^{15+}$ and Bk$^{16+}$ ions and demonstrate that they have transitions which combine the features of atomic optical clocks with the enhanced sensitivity to the variations of the fine…

Atomic Physics · Physics 2024-02-21 V. A. Dzuba , V. V. Flambaum

Optical clocks represent the most precise experimental devices, finding application in fields spanning from frequency metrology to fundamental physics. Recently, the first highly charged ions (HCI) based optical clock was demonstrated using…

The Ni$^{12+}$ ion features an electronic transition with a natural width of only 8 mHz, allowing for a highly stable optical clock. We predict that the energy of this strongly forbidden $3s^2 3p^4\, ^3\!P_2 \rightarrow 3s^2 3p^4 \,…

Our study is motivated by the prospect of several metastable states in the Sb$ ^{+} $, Au$ ^{+} $, and Hg$ ^{2+} $ ions being used as possible candidates for optical clocks. We calculate several atomic properties relevant to the development…

Atomic Physics · Physics 2023-06-21 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

We carried out detailed high-precision study of Ag-like Nd$^{13+}$, Sm$^{15+}$ and In-like Ce$^{9+}$, Pr$^{10+}$, Nd$^{11+}$, Sm$^{13+}$, Eu$^{14+}$ highly-charged ions. These ions were identified to be of particular interest to the…

Atomic Physics · Physics 2015-06-22 M. S. Safronova , V. A. Dzuba , V. V. Flambaum , U. I. Safronova , S. G. Porsev , M. G. Kozlov

An active optical clock based on highly charged Nd$^{9+}$ ion is proposed for the first time. The clock can offer ultra-narrow linewidth at the $\upmu$Hz-level which is more than two-order of magnitude below the currently recorded laser…

Atomic Physics · Physics 2021-07-23 Yan-mei Yu , Duo Pan , Shaolong Chen , Hua Guan , Kelin Gao , Jingbiao Chen

We consider transitions of electron holes (vacancies in otherwise filled shells of atomic systems) in multiply-charged ions that, due to level-crossing of the holes, have frequencies within the range of optical atomic clocks. Strong E1…

Atomic Physics · Physics 2011-07-21 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

We study a wide range of neutral atoms and ions suitable for ultra-precise atomic optical clocks with naturally suppressed black body radiation shift of clock transition frequency. Calculations show that scalar polarizabilities of clock…

Atomic Physics · Physics 2015-06-22 Alexander Kozlov , Vladimir Dzuba , Victor Flambaum

We investigate the feasibility of precision frequency metrology with large ion crystals. For clock candidates with a negative differential static polarisability, we show that micromotion effects should not impede the performance of the…

Quantum Physics · Physics 2016-10-25 Kyle Arnold , Elnur Haciyev , Eduardo Paez , Chern Hui Lee , John Bollinger , M. D. Barrett

A sharp resonance line that appears in three-photon transitions between the $^{1}S_{0}$ and $^{3}P_{0}$ states of alkaline earth and Yb atoms is proposed as an optical frequency standard. This proposal permits the use of the even isotopes,…

Optics · Physics 2007-05-23 Tao Hong , Claire Cramer , Warren Nagourney , E. N. Fortson

Today's most accurate clocks are based on laser spectroscopy of electronic transitions in single trapped ions and feature fractional frequency uncertainties below $1\times10^{-18}$. Scaling these systems to multiple, simultaneously…

We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available.…

Atomic Physics · Physics 2022-09-20 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Attempts are made to unify gravity with the other three fundamental forces of nature. As suggested by higher dimensional models, this unification may require space and time variation of some dimensionless fundamental constants. In this…

Atomic Physics · Physics 2023-02-15 Yan-Mei Yu , B. K. Sahoo , Bing-Bing Suo

Highly charged ions (HCIs) combine compact electronic structure with strong relativistic effects, offering both robustness against external perturbations and enhanced sensitivity to variations of the fine-structure constant. Recent advances…

Atomic Physics · Physics 2026-02-17 S. G. Porsev , M. S. Safronova

For the past 15 years, tremendous progress within the fields of laser stabilization, optical frequency combs and atom cooling and trapping have allowed the realization of optical atomic clocks with unrivaled performances. These instruments…

Atomic Physics · Physics 2018-04-09 Marion Delehaye , Clément Lacroûte

Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify…

Atomic Physics · Physics 2015-08-12 U. I. Safronova , V. V. Flambaum , M. S. Safronova

The 7.6(5) eV nuclear magnetic-dipole transition in a single 229Th3+ ion may provide the foundation for an optical clock of superb accuracy. A virtual clock transition composed of stretched states within the 5F5/2 electronic ground level of…

Atomic Physics · Physics 2015-05-30 C. J. Campbell , A. G. Radnaev , A. Kuzmich , V. A. Dzuba , V. V. Flambaum , A. Derevianko