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Related papers: Stereodynamical control of cold collisions between…

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The H$_2$+H$_2$ system has long been considered as a benchmark system for ro-vibrational energy transfer in bimolecular collisions. However, most studies thus far have focused on collisions involving H$_2$ molecules in the ground…

Chemical Physics · Physics 2022-12-20 James F. E. Croft , Pablo G. Jambrina , F. Javier Aoiz , Hua Guo , N. Balakrishnan

Quantum control of molecular collision dynamics is an exciting emerging area of cold collisions. Co-expansion of collision partners in a supersonic molecular beam combined with precise control of their quantum states and…

Chemical Physics · Physics 2021-09-29 Pablo G. Jambrina , James F. E. Croft , Naduvalath Balakrishnan , F. Javier Aoiz

In recent experiments using the Stark-induced Adiabatic Raman Passage (SARP) technique, Zhou et al. measured the product's angular distribution for the collisions between He and aligned D2 molecules at cold collision energies. The…

Stereodynamic control of resonant molecular collisions has emerged as a new frontier in cold molecule research. Recent experimental studies have focused on weakly interacting molecular systems such as HD collisions with H$_2$, D$_2$ and He.…

Chemical Physics · Physics 2020-07-22 Masato Morita , Qian Yao , Changjian Xie , Hua Guo , Naduvalath Balakrishnan

Stereodynamics of cold collisions has become a fertile ground for quantized studies of molecular collisions and control of the collision outcome. A benchmark process for stereodynamic control is rotational transition in He+HD collisions.…

Chemical Physics · Physics 2020-09-04 Masato Morita , Naduvalath Balakrishnan

Cold collisions of light molecules are often dominated by a single partial wave resonance. For the rotational quenching of HD(v=1,j=2) by collisions with ground state para-H2, the process is dominated by a single L=2 partial wave resonance…

This paper deals with the theory of collisions between two ultracold particles with a special focus on molecules. It describes the general features of the scattering theory of two particles with internal structure, using a time-independent…

Atomic Physics · Physics 2017-03-28 Goulven Quéméner

When hydrogen molecules collide with a surface, they can either scatter away from the surface or stick to the surface through a dissociation reaction which leaves two H atoms adsorbed on the surface. The relative probabilities of these two…

Chemical Physics · Physics 2024-10-03 H. Chadwick , G. Zhang , C. J. Baker , P. L. Smith , G. Alexandrowicz

Measuring inelastic rates with partial wave resolution requires temperatures close to a Kelvin or below, even for the lightest molecule. In a recent experiment Perreault et al. [1] studied collisional relaxation of excited HD molecules in…

Chemical Physics · Physics 2018-09-19 James F. E. Croft , Naduvalath Balakrishnan , Meng Huang , Hua Guo

We show that the precise preparation of a quantum superposition between three rotational states of an ultracold dipolar molecule generates controllable interferences in their two-body scattering dynamics and collisional rate coefficients,…

Quantum Gases · Physics 2024-06-21 Thibault Delarue , Goulven Quéméner

We theoretically investigate the collisions between ultracold polar molecules in the presence of two lasers ensuring a Raman resonant transition on individual molecules to suppress photon scattering, taking the example of bosonic…

We use numerically exact quantum dynamics calculations to demonstrate universal stereoselectivity of cold collisions of $^2\Pi$ molecules with $^1$S-state atoms in an external electric field. We show that cold collisions of OH molecules in…

Atomic Physics · Physics 2021-06-29 Timur V. Tscherbul , Jacek Kłos

We develop an analytic model of thermal state-to-state rotationally inelastic collisions of asymmetric-top molecules with closed-shell atoms in electric fields, and apply it to the Ar--H$_2$O collision system. The predicted cross sections…

Chemical Physics · Physics 2010-01-05 Mikhail Lemeshko , Bretislav Friedrich

We present a theory for manipulation of d-wave interaction of cold atoms with two lasers strongly driving two photoassociative transitions. The theory predicts the occurrence of a coherence between two excited ro-vibrational bound states…

Quantum Gases · Physics 2012-12-19 Bimalendu Deb

The charge transfer reaction Ar+ + N2 --> Ar + N2+ has been investigated in a crossed beam experiment in combination with three-dimensional velocity map imaging. Angular differential state-to-state cross sections were determined as a…

Chemical Physics · Physics 2015-06-12 S. Trippel , M. Stei , J. A. Cox , R. Wester

Whereas collisions between atoms and molecules are largely understood, collisions between two molecules have proven much harder to study. In both experiment and theory, our ability to determine quantum state-resolved bimolecular cross…

We study polar molecule scattering in quasi-one-dimensional geometries. Elastic and reactive collision rates are computed as a function of collision energy and electric dipole moment for different confinement strengths. The numerical…

Intriguing quantum effects that result from entangled molecular rovibrational states are shown to provide a novel means for controlling both differential and total collision cross sections in identical particle diatom-diatom scattering.…

Quantum Physics · Physics 2009-11-07 Jiangbin Gong , Moshe Shapiro , Paul Brumer

Techniques for producing cold and ultracold molecules are enabling the study of chemical reactions and scattering at the quantum scattering limit, with only a few partial waves contributing to the incident channel, leading to the…

Chemical Physics · Physics 2016-09-21 Jonathan Tennyson , Laura K. McKemmish , Tom Rivlin

We report numerically exact quantum scattering calculations on magnetic Feshbach resonances in ultracold, strongly anisotropic atom-molecule [Rb($^2$S) + SrF($^2\Sigma^+$)] collisions based on state-of-the-art ab initio potential energy…

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