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We show that quantum interference-based coherent control is a highly efficient tool for tuning ultracold molecular collision dynamics, and is free from the limitations of commonly used methods that rely on external electromagnetic fields.…

Atomic Physics · Physics 2021-04-21 Adrien Devolder , Paul Brumer , Timur V. Tscherbul

It is shown that the atom-molecule collision problem in the presence of an external electric field can be solved using the total angular momentum representation in the body-fixed coordinated frame, leading to a computationally efficient…

Chemical Physics · Physics 2012-09-17 T. V. Tscherbul

Coherent control of atomic and molecular scattering relies on the preparation of colliding particles in superpositions of internal states, establishing interfering pathways that can be used to tune the outcome of a scattering process.…

Atomic Physics · Physics 2024-12-20 Adrien Devolder , Timur V. Tscherbul , Paul Brumer

The present study presents a comprehensive theoretical investigation of atom and asymmetric top molecule inelastic scattering based on the R-matrix formalism. The proposed methodology establishes a rigorous framework for treating inelastic…

We consider a method of sub-wavelength superlocalization and patterning of atomic matter waves via a two dimensional stimulated Raman adiabatic passage (2D STIRAP) process. An atom initially prepared in its ground level interacts with a…

Electron collisions with O$_2$ at scattering energies below 1 eV are studied in the fixed-nuclei approximation for a range of internuclear separations using the ab initio molecular R-matrix method. The $^2\Pi_g$ scattering eigenphases and…

Chemical Physics · Physics 2013-02-26 Michal Tarana , Chris H. Greene

Elastic scattering resonances occurring in ultracold collisions of either bosonic or fermionic polar molecules are investigated. The Born-Oppenheimer adiabatic representation of the two-bodydynamics provides both a qualitative…

Atomic and Molecular Clusters · Physics 2009-11-13 V. Roudnev , M. Cavagnero

It has recently become possible to form molecules in ultracold gases of trapped alkali metal atoms. Once formed, the molecules may undergo elastic, inelastic and reactive collisions. Inelastic and reactive collisions are particularly…

Atomic Physics · Physics 2010-03-09 Jeremy M. Hutson , Pavel Soldan

We present a theoretical formalism to treat the ultracold dynamics of a pair of colliding polar molecules submitted to two laser fields. We express the dressed Hamiltonian including the dipole-dipole interaction of the colliding molecular…

We describe a new method of coherent optical control of internal dynamics of atomic collisions by means of two correlated light beams having entangled polarizations. We show that if excitation of a colliding pair of atoms is by two photons…

Quantum Physics · Physics 2015-06-23 M. D. Havey , D. V. Kupriyanov , I. M. Sokolov

We prepare mixtures of ultracold CaF molecules and Rb atoms in a magnetic trap and study their inelastic collisions. When the atoms are prepared in the spin-stretched state and the molecules in the spin-stretched component of the first…

A (diatomic) shape resonance is a metastable state of a pair of colliding atoms quasi-bound by the centrifugal barrier imposed by the angular momentum involved in the collision. The temporary trapping of the atoms' scattering wavefunction…

We study two body dipolar scattering in two dimensions with a tilted polarization axis. This tilt reintroduces the anisotropic interaction in a controllable manner. As a function of this polarization angle we present the scattering results…

Atomic Physics · Physics 2011-10-20 Christopher Ticknor

We show theoretically that it is possible to form a cold molecular ion from a pair of colliding atom and ion at low energy by photoassociative two-photon Raman processes. We explore the possibility of stimulated Raman adiabatic passage…

Atomic Physics · Physics 2016-09-13 Dibyendu Sardar , Somnath Naskar , Arpita Pal , Bimalendu Deb

We investigate elastic, inelastic, and coalescent collisions between two-dimensional flat-top solitons supported by the cubic-quintic nonlinear Schr\"odinger equation. Numerical simulations reveal distinct collision regimes ranging from…

Pattern Formation and Solitons · Physics 2026-05-07 M. O. D. Alotaibi , Y. O. A. Abughnheim , L. Al Sakkaf , U. Al Khawaja

We report on experiments investigating the collisional properties of atoms at ultralow collision energies using an all-optical atom collider. By using a pair of optical tweezers, we can manipulate two ultracold atom clouds and collide them…

Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

Ultracold collisions of polar OH molecules are considered in the presence of an electrostatic field. The field exerts a strong influence on both elastic and state-changing inelastic collision rate constants, leading to clear experimental…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

We present a general theoretical treatment and calculations of the fine and hyperfine structures in the spectra of high-$n$ molecular Rydberg states in static uniform electric fields. The treatment combines (i) multichannel quantum-defect…

Atomic Physics · Physics 2026-04-22 Ioana Doran , Leon Jeckel , Maximilian Beyer , Christian Jungen , Frédéric Merkt

We show that ultracold chemical reactions can be manipulated and controlled by using Rydberg-dressed interactions. Scattering in the ultracold regime is sensitive to long-range interactions, especially when weakly bound (or quasi-bound)…

Atomic Physics · Physics 2015-06-19 Jia Wang , Jason N. Byrd , Ion Simbotin , R. Côté