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We investigate the fracture of Li-ion battery cathodic particles using a thermodynamically consistent phase-field approach that can describe arbitrarily complex crack paths and captures the full coupling between Li-ion diffusion, stress,…

Materials Science · Physics 2019-08-23 Ataollah Mesgarnejad , Alain Karma

Fracture of lithium-ion battery electrodes is found to contribute to capacity fade and reduce the lifespan of a battery. Traditional fracture models for batteries are restricted to consideration of a single, idealised particle; here,…

Core-shell electrode particles are a promising morphology control strategy for high-performance lithium-ion batteries. However, experimental observations reveal that these structures remain prone to mechanical failure, with shell fractures…

Computational Engineering, Finance, and Science · Computer Science 2025-11-14 Y. Tu , B. Wu , E. Martínez-Pañeda

A novel FFT-based phase-field fracture framework for modelling fatigue crack initiation and propagation at the microscale is presented. A damage driving force is defined based on the stored energy and dislocation density, relating…

Computational Engineering, Finance, and Science · Computer Science 2023-04-04 Sergio Lucarini , Fionn P. E. Dunne , Emilio Martínez-Pañeda

In this study, a multiphysics model fully coupling mass transport, deformation, phase field, and fatigue damage was developed to investigate the cracking and fracturing behaviours of Si particles during the single lithiation-delithiation…

Applied Physics · Physics 2026-01-06 Jie Yang , Wei Tan

Cathode particle fracture is widely recognised as a major degradation mechanism in lithium-ion batteries, yet cracking also permits electrolyte wetting of newly exposed internal surfaces, modifying interfacial reaction pathways. The…

Computational Engineering, Finance, and Science · Computer Science 2026-05-05 S. Luza-Vega , Y. Zhao , E. Martínez-Pañeda

For the fatigue life of thin-walled components, not only fatigue crack initiation, but also crack growth is decisive. The phase-field method for fracture is a powerful tool to simulate arbitrary crack phenomena. Recently, it has been…

Materials Science · Physics 2021-04-07 Martha Seiler , Sören Keller , Nikolai Kashaev , Benjamin Klusemann , Markus Kästner

Lithium-ion batteries (LIBs) of high energy density and light-weight design, have found wide applications in electronic devices and systems. Degradation mechanisms that caused by lithiation is a main challenging problem for LIBs with high…

Computational Engineering, Finance, and Science · Computer Science 2020-06-26 Masoud Ahmadi

We introduce a class of models based on near crack tip degradation of materials that can account for fracture growth under cyclic loads below the Griffith threshold. We incorporate the gradual degradation due to a cyclic load through a flow…

Materials Science · Physics 2019-06-26 Ataollah Mesgarnejad , Anahita Imanian , Alain Karma

Fatigue fracture is one of the main causes of failure in structures. However, the simulation of fatigue crack growth is computationally demanding due to the large number of load cycles involved. Metals in the low cycle fatigue range often…

Computational Physics · Physics 2024-11-11 Martha Kalina , Tom Schneider , Haim Waisman , Markus Kästner

This paper presents a modeling framework to describe the driving mechanisms of cyclic failure in brittle and ductile materials, including cyclic plasticity and fatigue crack growth. A variational model is devised using the energetic…

Numerical Analysis · Mathematics 2020-11-10 Jacinto Ulloa , Jef Wambacq , Roberto Alessi , Geert Degrande , Stijn François

This article presents a novel, robust and efficient framework for fatigue crack-propagation that combines the principles of Linear Elastic Fracture Mechanics (LEFM) with phase-field fracture (PFF). Contrary to cycle-by-cycle PFF approaches,…

Materials Science · Physics 2025-09-12 M. Castillón , I. Romero , J. Segurado

Phase-field approaches to fracture based on energy minimization principles have been rapidly gaining popularity in recent years, and are particularly well-suited for simulating crack initiation and growth in complex fracture networks. In…

Materials Science · Physics 2018-03-14 Juan Michael Sargado , Eirik Keilegavlen , Inga Berre , Jan Martin Nordbotten

Crack growth in lithium-ion battery electrodes is typically detrimental and undesirable. However, recent experiments suggest that stabilized fracture of cathode active materials in liquid electrolytes can increase electrochemically active…

Fracture is a fundamental mechanism of materials failure. Propagating cracks can exhibit a rich dynamical behavior controlled by a subtle interplay between microscopic failure processes in the crack tip region and macroscopic elasticity. We…

Materials Science · Physics 2015-05-18 R. Spatschek , E. Brener , A. Karma

Phase field fracture models have seen widespread application in the last decade. Among these applications, its use to model the evolution of fatigue cracks has attracted particular interest, as fatigue damage behaviour can be predicted for…

Computational Engineering, Finance, and Science · Computer Science 2023-04-26 P. K. Kristensen , A. Golahmar , E. Martínez-Pañeda , C. F. Niordson

We present a new theoretical and numerical phase field-based formulation for predicting hydrogen-assisted fatigue. The coupled deformation-diffusion-damage model presented enables predicting fatigue crack nucleation and growth for arbitrary…

Computational Engineering, Finance, and Science · Computer Science 2021-10-02 Alireza Golahmar , Philip K. Kristensen , Christian F. Niordson , Emilio Martínez-Pañeda

In the last ten years, the phase-field method has gained much attention as a novel method to simulate fracture due to its straightforward way allowing to cover crack initiation and propagation without additional conditions. More recently,…

Materials Science · Physics 2023-05-31 Martha Kalina , Tom Schneider , Jörg Brummund , Markus Kästner

We present a new theoretical and computational framework for modelling electro-chemo-mechanical fracture. The model combines a phase field description of fracture with a fully coupled characterisation of electrolyte behaviour, surface…

Computational Engineering, Finance, and Science · Computer Science 2023-08-02 T. Hageman , E. Martínez-Pañeda

Li-ion battery performance is strongly influenced by their cathodes' properties and consequently by the 3D microstructure of the particles the cathodes are comprised of. During calendaring and cycling, cracks develop within cathode…

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