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A variational solution procedure is reported for the many-particle no-pair Dirac-Coulomb-Breit Hamiltonian aiming at a parts-per-billion (ppb) convergence of the atomic and molecular energies, described within the fixed nuclei…

Quantum Physics · Physics 2024-06-19 Péter Jeszenszki , Dávid Ferenc , Edit Mátyus

We use previously developed radiative potential method to calculate quantum electrodynamic (QED) corrections to energy levels and electric dipole transition amplitudes for atoms which are used for the study of the parity non-conservation…

Atomic Physics · Physics 2014-03-20 B. M. Roberts , V. A. Dzuba , V. V. Flambaum

The relativistic corrections for the Dirac-Coulomb system are derived through the method of non-relativistic expansion. By expanding the large and small components of the Dirac wave function and the energy eigenvalues in terms of the square…

Atomic Physics · Physics 2024-12-03 Wanping Zhou , Sanjiang Yang , Haoxue Qiao

The leading relativistic and QED corrections to the ground state energy of the three-body system (epe) are calculated numerically using a Hylleraas correlated basis set. The accuracy of the nonrelativistic variational ground state wave…

Atomic Physics · Physics 2007-05-23 M. Grigorescu , G. W. F. Drake

The simplest, algebraic quantum-electrodynamical corrections, due to the double-negative energy subspace and instantaneous interactions, are computed to the no-pair energy of two-spin-1/2-fermion systems. Numerical results are reported for…

Chemical Physics · Physics 2025-12-09 Péter Jeszenszki , Edit Mátyus

The variational method, within the Hamiltonian formalism of reformulated QED is used to determine relativistic wave equations for a system of three fermions of arbitrary mass interacting electromagnetically. The interaction kernels of the…

Atomic Physics · Physics 2007-06-21 Mark Barham , Jurij W. Darewych

The sixteen-component, no-pair Dirac--Coulomb--Breit equation, derived from the Bethe--Salpeter equation, is solved in a variational procedure using Gaussian-type basis functions for the example of positronium, muonium, hydrogen atom, and…

Quantum Physics · Physics 2023-05-24 Dávid Ferenc , Edit Mátyus

In this paper we review the different relativistic and QED contributions to energies, ionic radii, transition probabilities and Land\'e $g$-factors in super-heavy elements, with the help of the MultiConfiguration Dirac-Fock method (MCDF).…

Atomic Physics · Physics 2009-11-13 Paul Indelicato , J. P. Santos , S. Boucard , J. P. Desclaux

The Breit interaction is implemented in the no-pair variational Dirac-Coulomb (DC) framework using an explicitly correlated Gaussian basis reported in the previous paper [Paper I: P. Jeszenszki, D. Ferenc, and E. M\'atyus (2022)]. Both a…

Chemical Physics · Physics 2022-03-14 Dávid Ferenc , Péter Jeszenszki , Edit Mátyus

The triplet contribution is computed to the 1 and 2 $^1S^\text{e}_0$ states of the He atom, to the $1\ ^1S^\text{e}_0$ state of the Li$^+$ and Be${^{2+}}$ ions, and to the $X\ ^1\Sigma_\text{g}^+$ ground state of the H$_2$ molecule by…

Atomic Physics · Physics 2023-01-25 Péter Jeszenszki , Edit Mátyus

Accurate results for nonrelativistic energy, relativistic, QED, and finite nuclear mass corrections are obtained for $2^1S_{1/2}$, $3^1S_{1/2}$ and $2^1P_{1/2}$ states of the Li atom and Be$^+$ ion. Our computational approach uses the…

Atomic Physics · Physics 2009-11-13 Mariusz Puchalski , Krzysztof Pachucki

The ability to achieve ultra-strong coupling between light and matter promises to bring about new means to control material properties, new concepts for manipulating light at the atomic scale, and fundamentally new insights into quantum…

Quantum Physics · Physics 2019-05-22 Nicholas Rivera , Johannes Flick , Prineha Narang

The efficiency of the variational perturbation theory [Phys. Rev. C {\bf 62}, 045503 (2000)] formulated recently for many-particle systems is examined by calculating the ground state correlation energy of the 3D electron gas with the…

Strongly Correlated Electrons · Physics 2009-11-07 Sang Koo You , Noboru Fukushima

We analyse a modified Dirac equation based on a noncommutative structure in phase space. The noncommutative structure induces generalised momenta and contributions to the energy levels of the standard Dirac equation. Using techniques of…

Mathematical Physics · Physics 2019-09-16 Marco Maceda , Jairo Villafuerte-Lara

We calculate the nonadiabatic relativistic correction to rovibrational energy levels of H$_2$, D$_2$, and HD molecules using the nonadiabatic perturbation theory. This approach allows one to obtain nonadiabatic corrections to all the…

Atomic Physics · Physics 2018-12-03 Pawel Czachorowski , Mariusz Puchalski , Jacek Komasa , Krzysztof Pachucki

This work is a collection of initial calculations and formal considerations within the Salpeter-Sucher exact equal-time relativistic quantum electrodynamics framework. The calculations are carried out as preparation for the computation of…

Chemical Physics · Physics 2024-06-11 Adám Margócsy , Edit Mátyus

The Dirac-Coulomb equation with positive-energy projection is solved using explicitly correlated Gaussian functions. The algorithm and computational procedure aims for a parts-per-billion convergence of the energy to provide a starting…

Chemical Physics · Physics 2022-03-14 Péter Jeszenszki , Dávid Ferenc , Edit Mátyus

Power corrections to hadronic event shapes are estimated using a recently suggested relationship between perturbative and non-perturbative effects in QCD. The infrared cutoff dependence of perturbative calculations is related to…

High Energy Physics - Phenomenology · Physics 2009-10-28 B. R. Webber

The technique of quantum electrodynamics (QED) calculations of energy levels in the helium atom is reviewed. The calculations start with the solution of the Schr\"odinger equation and account for relativistic and QED effects by perturbation…

Atomic Physics · Physics 2021-07-14 Vladimir A. Yerokhin , Vojtech Patkos , Krzysztof Pachucki

Measurements of energy separations in highly charged ions can in many cases nowadays be performed with very high accuracy, an accuracy that sometimes cannot be matched by the corresponding theoretical calcula- tions. Furthermore, it has…

Atomic Physics · Physics 2013-01-01 Ingvar Lindgren , Sten Salomonson , Johan Holmberg
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