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We present a unified theory of luminescence spectra for highly excited semiconductors, which is applicable both to the electron-hole BCS state and to the exciton Bose-Einstein condensate. The crossover behavior between electron-hole BCS…

Strongly Correlated Electrons · Physics 2009-10-31 T. J. Inagaki , M. Aihara , A. Takahashi

We study the optical response of VO2 in the M1 insulating phase using methods based on density functional theory in its most recent developments. We start from a hybrid functional approach which may be a good starting point to carry out…

Strongly Correlated Electrons · Physics 2012-07-26 Adam Gali , John E. Coulter , Efstratios Manousakis

The lowest electronic excitations of benzene and a set of donor-acceptor molecular complexes are calculated for the gas phase and on the Al(111) surface using the many-body Bethe-Salpeter equation (BSE). The energy of the charge-transfer…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 J. M. Garcia-Lastra , K. S. Thygesen

High-resolution angle-resolved photoemission measurements were taken on FeSe$_{1-x}$S$_x$ (x=0, 0.04, and 0.08) superconductors. With an ultrahigh energy resolution of 0.4 meV, unusual two hole bands near the Brillouin-zone center, which…

A formally exact Bethe-Salpeter-like equation for the linear-response function is introduced with a kernel which depends only on the one frequency of the applied field. This is in contrast with the standard Bethe-Salpeter equation (BSE)…

Chemical Physics · Physics 2019-03-18 Valerio Olevano , Julien Toulouse , Peter Schuck

We apply the renormalized singles (RS) Green's function in the Bethe-Salpeter equation (BSE)/$GW$ approach to predict accurate neutral excitation energies of molecular systems. The BSE calculations are performed on top of the…

Chemical Physics · Physics 2022-10-26 Jiachen Li , Dorothea Golze , Weitao Yang

The phenomenon of orbital relaxation upon excitation of core electrons is a major problem in the linear-response treatment of core-hole spectroscopies. Rather than addressing relaxation through direct dynamical correlation of the excited…

Chemical Physics · Physics 2025-03-26 Megan Simons , Devin A. Matthews

We applied localized orbital scaling correction (LOSC) in Bethe-Salpeter equation (BSE) to predict accurate excitation energies for molecules. LOSC systematically eliminates the delocalization error in the density functional approximation…

Chemical Physics · Physics 2022-07-04 Jiachen Li , Ye Jin , Neil Qiang Su , Weitao Yang

We present a unified theory for pump-probe spectra in highly excited semiconductors, which is applicable throughout the whole density regime including the high-density electron-hole BCS state and the low-density excitonic Bose-Einstein…

Materials Science · Physics 2009-10-31 T. J. Inagaki , T. Iida , M. Aihara

Room-temperature Bose--Einstein condensates (BECs) of exciton polaritons have been realized in organic molecular systems owing to the strong light--matter interaction, strong exciton binding energy, and low effective mass of a polaritonic…

Chemical Physics · Physics 2022-06-17 Nguyen Thanh Phuc

We study x-ray absorption spectra of azobenzene-functionalized self-assembled monolayers (SAMs), investigating excitations from the nitrogen K edge. Azobenzene with H-termination and functionalized with CF3 groups is considered. The…

Mesoscale and Nanoscale Physics · Physics 2015-11-06 Caterina Cocchi , Claudia Draxl

We present an approach to calculate the optical absorption spectra that combines the quasiparticle self-consistent GW method [Phys. Rev. B, 76 165106 (2007)] for the electronic structure with the solution of the ladder approximation to the…

Materials Science · Physics 2018-03-21 Brian Cunningham , Pooya Azarhoosh , Dimitar Pashov , Myrta Gruening , Mark van Schilfgaarde

Carbon $1s$ core-hole excitation of the molecular anion C$_2^-$ has been experimentally studied at high resolution by employing the photon-ion merged-beams technique at a synchrotron light source. The experimental cross section for…

Excitons are promising candidates for generating superfluidity and Bose-Einstein Condensation (BEC) in solid state devices, but an enabling material platform with in-built bandstructure advantages and scaling compatibility with industrial…

Phosphorene is a bidimensional material that has properties useful for semiconductor devices. In this work we studied the electronic and optical properties of this material using the $GW$ approximation and the Bethe-Salpeter equation (BSE)…

Mesoscale and Nanoscale Physics · Physics 2017-11-16 Fábio Ferreira , Ricardo Mendes Ribeiro

Solving the Bethe-Salpeter equation (BSE) for the optical polarization functions is a first principles means to model optical properties of materials including excitonic effects. One almost ubiquitously used approximation neglects the…

Materials Science · Physics 2023-07-11 Xiao Zhang , Joshua A. Leveillee , André Schleife

We present a first-principles method for the calculation of optical excitations in nanosystems. The method is based on solving the Bethe-Salpeter equation (BSE) for neutral excitations. The electron self-energy is evaluated within the GW…

Materials Science · Physics 2009-11-11 Murilo L. Tiago , James R. Chelikowsky

We present a reciprocal-space pseudopotential scheme for calculating X-ray absorption near-edge structure (XANES) spectra. The scheme incorporates a recursive method to compute absorption cross section as a continued fraction. The continued…

Condensed Matter · Physics 2009-11-07 Mathieu Taillefumier , Delphine Cabaret , Anne-Marie Flank , Francesco Mauri

We study the core hole-electron correlation in coherently coupled molecules by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In a transient phase, which exists during the transition between two bulk arrangements,…

Materials Science · Physics 2013-12-03 M. Scholz , F. Holch , C. Sauer , M. Wiessner , A. Schöll , F. Reinert

The improvement of light absorption in Si/BeSe$_{0.41}$Te$_{0.59}$ heterostructures for solar cell applications is studied theoretically. First, using simple approaches we found that light absorption could be improved in a single…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 T. Sandu , W. P. Kirk