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We present an efficient implementation of the Bethe-Salpeter equation (BSE) method for obtaining core-level spectra including x-ray absorption (XAS), x-ray emission (XES), and both resonant and non-resonant inelastic x-ray scattering…

Computational Physics · Physics 2016-01-29 K. Gilmore , John Vinson , E. L. Shirley , D. Prendergast , C. D. Pemmaraju , J. J. Kas , F. D. Vila , J. J. Rehr

We present a hybrid approach for GW/Bethe-Salpeter Equation (BSE) calculations of core excitation spectra, including x-ray absorption (XAS), electron energy loss spectra (EELS), and non-resonant inelastic x-ray scattering (NRIXS). The…

Materials Science · Physics 2015-05-20 J. Vinson , E. L. Shirley , J. J. Rehr , J. J. Kas

The Bethe-Salpeter equation for the electron-hole correlation function is the state-of-the-art formalism for optical and core spectroscopy in condensed matter. Solutions of this equation yield the full dielectric response, including both…

Materials Science · Physics 2019-04-12 Christian Vorwerk , Benjamin Aurich , Caterina Cocchi , Claudia Draxl

The Bethe-Salpeter equation (BSE) can provide an accurate description of low-energy optical spectra of insulating crystals - even when excitonic effects are important. However, due to high computational costs it is only possible to include…

The Bethe-Salpeter equation (BSE) is a powerful theoretical approach that is capable to accurately treat electron-hole interactions in materials in an excited state. We developed an ab initio framework based on the BSE to describe a…

Materials Science · Physics 2026-05-19 Nasrin Farahani , Daria Popova-Gorelova

We present an energy-specific Bethe-Salpeter equation (BSE) implementation for efficient core and valence optical spectrum calculations. In energy-specific BSE, high-lying excitation energies are obtained by constructing trial vectors and…

Materials Science · Physics 2025-01-29 Christopher Hillenbrand , Jiachen Li , Tianyu Zhu

We delineate an ab initio approach for obtaining x-ray absorption spectra as provided by many-body perturbation theory, together with its realization within an all-electron framework. Employing the Bethe-Salpeter equation, we address…

Materials Science · Physics 2017-09-08 Claudia Draxl , Caterina Cocchi

The Bethe-Salpeter equation (BSE) is the key equation in many-body perturbation theory based on Green's functions to access response properties. Within the $GW$ approximation to the exchange-correlation kernel, the BSE has been successfully…

Chemical Physics · Physics 2023-02-15 Roberto Orlando , Pina Romaniello , Pierre-François Loos

We present an efficient implementation of the Bethe-Salpeter equation (BSE) for optical properties of materials in the projector augmented wave method GPAW. Single-particle energies and wave functions are obtained from the GLLBSC functional…

Materials Science · Physics 2012-07-20 Jun Yan , Karsten W. Jacobsen , Kristian S. Thygesen

We present an efficient way to solve the Bethe-Salpeter equation (BSE), a model for the computation of absorption spectra in molecules and solids that includes electron-hole excitations. Standard approaches to construct and diagonalize the…

Computational Physics · Physics 2018-02-01 Wei Hu , Meiyue Shao , Andrea Cepellotti , Felipe H. da Jornada , Lin Lin , Kyle Thicke , Chao Yang , Steven G. Louie

We present a massively parallel, GPU-accelerated implementation of the Bethe-Salpeter equation (BSE) for the calculation of the vertical excitation energies (VEEs) and optical absorption spectra of condensed and molecular systems, starting…

Materials Science · Physics 2024-12-25 Victor Wen-zhe Yu , Yu Jin , Giulia Galli , Marco Govoni

The GW plus Bethe-Salpeter equation (GW-BSE) formalism is a well-established approach for calculating excitation energies and optical spectra of molecules, nanostructures, and crystalline materials. We implement GW-BSE in the CP2K code and…

Computational Physics · Physics 2026-05-29 Maximilian Graml , Jan Wilhelm

The Bethe-Salpeter equation (BSE) based on GW quasiparticle levels is a successful approach for calculating the optical gaps and spectra of solids and also for predicting the neutral excitations of small molecules. We here present an…

Materials Science · Physics 2020-02-19 Chi Liu , Jan Kloppenburg , Xinguo Ren , Heiko Appel , Yosuke Kanai , Volker Blum

The Bethe-Salpeter Equation (BSE) can be applied to compute from first-principles optical spectra that include the effects of screened electron-hole interactions. As input, BSE calculations require single-particle states, quasiparticle…

Materials Science · Physics 2020-01-01 Joshua Elliott , Nicola Colonna , Margherita Marsili , Nicola Marzari , Paolo Umari

A time-dependent formulation for electron-hole excitations in extended finite systems, based on the Bethe-Salpeter equation (BSE), is developed using a stochastic wave function approach. The time-dependent formulation builds on the…

Materials Science · Physics 2015-02-11 Eran Rabani , Roi Baer , Daniel Neuhauser

The $GW$-Bethe-Salpeter Equation (BSE) method is promising for calculating the low-lying excited states of molecular systems. So far, it has only been applied to rather small molecules, and in the commonly implemented diagonal…

Chemical Physics · Physics 2022-08-10 Arno Förster , Lucas Visscher

Excitonic effects in optical spectra and electron-hole pair excitations are described by solutions of the Bethe-Salpeter equation (BSE) that accounts for the Coulomb interaction of excited electron-hole pairs. Although for the computation…

Other Condensed Matter · Physics 2008-08-20 F. Fuchs , C. Rödl , A. Schleife , F. Bechstedt

The Bethe-Salpeter equation (BSE) is a reliable model for estimating the absorption spectra in molecules and solids on the basis of accurate calculation of the excited states from first principles. This challenging task includes calculation…

Numerical Analysis · Mathematics 2016-05-04 Peter Benner , Venera Khoromskaia , Boris N. Khoromskij

The Bethe-Salpeter equation (BSE) is currently the state of the art in the description of neutral electron excitations in both solids and large finite systems. It is capable of accurately treating charge-transfer excitations that present…

The Bethe-Salpeter Equation (BSE) is the workhorse method to study excitons in materials. The BSE Hamiltonian size, which depends on how many valence-to-conduction band transitions are considered, needs to be chosen to be sufficiently large…

Materials Science · Physics 2025-10-20 Rafael R. Del Grande , David A. Strubbe
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