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We present ab initio calculations of hidden magnetoelectric multipolar order in Cr$_2$O$_3$ and its iron-based analogue, $\alpha$-Fe$_2$O$_3$. First, we discuss the connection between the order of such hidden multipoles and the linear…

Materials Science · Physics 2023-11-14 Xanthe H. Verbeek , Andrea Urru , Nicola A. Spaldin

Extensive investigation has recently been conducted into a new class of antiferromagnetic order known as magnetic octupole order. However, the high rank of octupoles makes it difficult to detect and manipulate them by using conventional…

Materials Science · Physics 2024-11-14 Jun Ōiké , Koki Shinada , Robert Peters

We show that time-reversal symmetry broken, centrosymmetric antiferromagnets with nonrelativistic spin-splitting are conveniently described in terms of the ferroic ordering of magnetic octupoles. The magnetic octupoles are the lowest-order…

Strongly Correlated Electrons · Physics 2025-06-10 Sayantika Bhowal , Nicola A. Spaldin

We demonstrate computationally the existence of magnetoelectric multipoles, arising from the second order term in the multipole expansion of a magnetization density in a magnetic field, in noncentrosymmetric magnetic metals. While…

Materials Science · Physics 2021-03-09 Florian Thöle , Nicola A. Spaldin

Motivated by recent studies of odd-parity multipole order in condensed matter physics, we theoretically study magnetoelectric responses in an electric octupole state. Investigating the Edelstein effect and spin Hall effect in a locally…

Strongly Correlated Electrons · Physics 2019-05-22 Takanori Hitomi , Youichi Yanase

"Hidden"-order phases with high-rank multipolar order parameters have been recently detected in several cubic double perovskites of 5$d$ transition metals. Here, by constructing and solving an ab initio low-energy Hamiltonian, we show that…

Strongly Correlated Electrons · Physics 2025-04-02 Dario Fiore Mosca , Leonid V. Pourovskii

Noncollinear antiferromagnets can generate a transverse electrical response known as the anomalous Hall effect, even though they possess almost no net magnetization. The microscopic origin of this behaviour, however, has remained unclear…

Magneto-electric multiferroics exemplified by TbMnO3 possess both magnetic and ferroelectric long-range order. The magnetic order is mostly understood, whereas the nature of the ferroelectricity has remained more elusive. Competing models…

Strongly Correlated Electrons · Physics 2011-10-14 H. C. Walker , F. Fabrizi , L. Paolasini , F. de Bergevin , J. Herrero-Martin , A. T. Boothroyd , D. Prabhakaran , D. F. McMorrow

We report the discovery of linear magnetoelectric effect in the well-known green phase compound, Sm2BaCuO5, which crystallizes in the centrosymmetric orthorhombic (Pnma) structure. Magnetization and specific heat measurements reveal the…

Strongly Correlated Electrons · Physics 2019-10-02 Premakumar Yanda , N. V. Ter-Oganessian , A. Sundaresan

We observe a bilinear magnetic field-induced electric polarization of 50 $\mu C/m^2$ in single crystals of NiCl$_2$-4SC(NH$_2$)$_2$ (DTN). DTN forms a tetragonal structure that breaks inversion symmetry, with the highly polar thiourea…

Materials Science · Physics 2015-05-19 V. S. Zapf , F. Nasreen , F. Wolff-Fabris , A. Paduan-Filho

We study f-electron lattice models which are capable of supporting octupolar, as well dipolar and quadrupolar, order. Analyzing the properties of the Gamma8 ground state quartet, we find that (111)-type combinations of the Gamma5 octupoles…

Strongly Correlated Electrons · Physics 2009-11-10 Annamaria Kiss , P. Fazekas

An antiferro ordering of an electric hexadecapole moment is discussed as a promising candidate for the long standing mystery of the hidden order phase in URu$_{2}$Si$_{2}$. Based on localized $f$-electron picture, we discuss the rationale…

Strongly Correlated Electrons · Physics 2015-05-27 Hiroaki Kusunose , Hisatomo Harima

We use symmetry analysis and density functional theory to show that changes in magnetic order at a surface with respect to magnetic order in the bulk can be generically determined by considering local magnetoelectric responses of the…

Materials Science · Physics 2024-12-10 Sophie F. Weber , Andrea Urru , Nicola A. Spaldin

Using neutron diffraction, we have studied the magnetic field effect on charge structures in the charge-ordered multiferroic material LuFe$_2$O$_4$. An external magnetic field is able to change the magnitude and correlation lengths of the…

Strongly Correlated Electrons · Physics 2009-04-10 Jinsheng Wen , Guangyong Xu , Genda Gu , S. M. Shapiro Brookhaven National Laboratory

It is still under intensive discussion, how magnetoelectric coupling actually occurs at the atomic scale in multiferroic BiFeO3. Nuclear solid-state techniques monitor local fields at the atomic scale. Using such an approach, we show that,…

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

We theoretically investigate the magnetic-multipole orders in two-dimensional (2D) altermagnets, focusing on two representative models: a generic minimal three-site model, and a four-site model representative of monolayer FeSe. We construct…

Mesoscale and Nanoscale Physics · Physics 2025-11-12 Tenta Tani , Ulrich Zülicke

Magnetic multipoles have been recognized as order parameters characterizing magnetic structure in solids. Recently, magnetic octupoles have been proposed as the order parameters of time-reversal-symmetry breaking centrosymmetric…

Mesoscale and Nanoscale Physics · Physics 2026-02-06 Takumi Sato , Satoru Hayami

We revisit the description of the magnetic field around antiferromagnetic magnetoelectrics in the context of recent developments regarding magnetoelectric monopoles. Using Maxwell's equations, we calculate the magnetic and electric fields…

Materials Science · Physics 2014-05-28 Michael Fechner , Nicola A. Spaldin , I. E. Dzyaloshinskii

Order parameters not only characterize symmetry-broken equilibrium phases but also govern transport phenomena in the nonequilibrium regime. Altermagnets, a class of magnetic systems integrating ferromagnetic and antiferromagnetic features,…

Materials Science · Physics 2025-08-04 Hye-Won Ko , Kyung-Jin Lee
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