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There is accumulating evidence for the presence of complex molecules, including carbon-bearing and organic molecules, in the interstellar medium. Much of this evidence comes to us from studies of chemical composition, photo- and…

Earth and Planetary Astrophysics · Physics 2015-10-21 David W. Marshall , H. R. Sadeghpour

We describe a mechanism that explains the formation of hydrocarbons and hydrocarbyls from hydrogenated graphene/graphite; hard C-C bonds are weakened and broken by the synergistic effect of chemisorbed hydrogen and high temperature…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 Jose I. Martinez , Jose A. Martin-Gago , Jose Cernicharo , Pedro L. de Andres

Droplet vaporization has a great impact on combustion of liquid fuels and might greatly affects the engine performance. Physical understanding and theoretical interpretation of the droplet vaporization behavior are decisive to constitute…

Fluid Dynamics · Physics 2020-06-30 Dehai Yu , Zheng Chen

A reliable and compact chemical mechanism of gas-phase methane pyrolysis leading to formation of large polycyclic aromatic hydrocarbon (PAH) molecules has been developed. This model is designed for studies of carbon nanostructure synthesis…

Chemical Physics · Physics 2023-11-03 Alexander Khrabry , Igor D. Kaganovich , Yuri Barsukov , Sumathy Raman , Emre Turkoz , David Graves

This note presents a simulation method for investigating the relationship between porosity and particle size distribution in porous media characterization. The method simulates particle packing based on particle size distributions,…

Soft Condensed Matter · Physics 2024-09-25 Yuhe Wang

Using two extremely different models of glass formers in two and three dimensions we demonstrate how to encode the subtle changes in the geometric rearrangement of particles during the scenario of the glass transition. We construct a…

Statistical Mechanics · Physics 2015-05-13 Laurent Boue , Edan Lerner , Itamar Procaccia , Jacques Zylberg

Graph burning is a discrete process that models the spread of influence through a network using a fire as a proxy for the type of influence being spread. This process was recently extended to hypergraphs. We introduce a variant of…

Combinatorics · Mathematics 2024-08-13 Andrea C. Burgess , John A. Hawkin , Alexander J. M. Howse , Caleb W. Jones , David A. Pike

We examine several different simplified approaches for modelling the chemistry of CO in three-dimensional numerical simulations of turbulent molecular clouds. We compare the different models both by looking at the behaviour of integrated…

Astrophysics of Galaxies · Physics 2015-05-27 S. C. O. Glover , P. C. Clark

Motivated by a problem in heterogeneous catalysis, we study a model for irreversible first-order reactions in which gas transport occurs only by diffusion, and reaction occurs only at a small number of well-localized sites. The main problem…

Probability · Mathematics 2015-10-06 Renato Feres , Matt Wallace

Accurately charting the progress of oil production is a problem of great current interest. Oil production is widely known to be cyclical: in any given system, after it reaches its peak, a decline will begin. With this in mind, Marion King…

Methodology · Statistics 2024-01-31 Istoni da Luz Sant'Ana , Patricia Román-Román , Francisco Torres-Ruiz

Pyrosequencing is emerging as one of the important next-generation sequencing technologies. We derive the statistical distributions of this technique in terms of nucleotide probabilities of the target sequences. We give exact distributions…

Genomics · Quantitative Biology 2024-05-28 Yong Kong

Every time a chemical reaction occurs, an energy exchange between reactants and environment exists, which is defined as the enthalpy of the reaction. In the last decades, research has resulted in an increasing number of devices at the…

A model of key processes influencing the evolution of a hydrocarbon grain of an arbitrary size under astrophysical conditions corresponding to ionized hydrogen regions (HII regions) and supernova remnants is presented. The considered…

Astrophysics of Galaxies · Physics 2016-12-07 M. S. Murga , S. A. Khoperskov , D. S. Wiebe

Knowledge of bubble and drop size distributions in two-phase flows is important for characterizing a wide range of phenomena, including combustor ignition, sonar communication, and cloud formation. The physical mechanisms driving the…

Fluid Dynamics · Physics 2021-01-28 Wai Hong Ronald Chan , Michael S. Dodd , Perry L. Johnson , Parviz Moin

Understanding the molecular content of galaxies is a critical problem in star formation and galactic evolution. Here we present a new method, based on a Stromgren-type analysis, to calculate the amount of HI that surrounds a molecular cloud…

Astrophysics of Galaxies · Physics 2015-05-13 Christopher F. McKee , Mark R. Krumholz

We present a study of the chemistry of a dense photon-dominated region (PDR) using a time-dependent chemical model. Our major interest is to study the spatial distribution of complex molecules such as hydrocarbons and cyanopolyynes in the…

Astrophysics · Physics 2009-11-13 O. Morata , E. Herbst

In warm (equilibrium temperature <1000 K) gas giant exoplanet atmospheres, the observation of trace species in abundances deviating from thermochemical equilibrium predictions could be used as an indicator of disequilibrium chemical…

Earth and Planetary Astrophysics · Physics 2023-10-18 Benjamin Fleury , Yves Benilan , Olivia Venot , Bryana L. Henderson , Mark Swain , Murthy S. Gudipati

The dynamics of the particle-size distribution (PSD) of the polydispersed fuel is important for evaluation of the combustion process. In this paper we unfold the mystery of the dynamics represented by the PSD and gain new insight for the…

Soft Condensed Matter · Physics 2020-02-20 Shlomo Hareli , OPhir Nave , Vladimir Gol'dshtein

Among the numerous questions that arise concerning the exploitation of petroleum from unconventional reservoirs, lie the questions of the composition of hydrocarbons present in deep seated HP-HT reservoirs or produced during in-situ…

Colloidosomes are created in the laboratory from a Pickering emulsion of water droplets in oil. The colloidosomes have approximately the same diameter and by choosing (hairy) particles of different diameters it is possible to control the…

Chemical Physics · Physics 2012-11-20 Riccardo Fantoni , Johannes W. O. Salari , Bert Klumperman