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We present a review of the Unitary Coupled Cluster (UCC) ansatz and related ans\"atze which are used to variationally solve the electronic structure problem on quantum computers. A brief history of coupled cluster (CC) methods is provided,…

We propose an experimental scheme to simulate the fractionalization of particle number by using a one-dimensional spin-orbit coupled ultracold fermionic gas. The wanted spin-orbit coupling, a kink-like potential, and a…

Quantum Gases · Physics 2012-12-19 Dan-Wei Zhang , L. -B. Shao , Zheng-Yuan Xue , Hui Yan , Z. D. Wang , Shi-Liang Zhu

With a combination of the quantum repeater and the cluster state approaches, we show that efficient quantum computation can be constructed even if all the entangling quantum gates only succeed with an arbitrarily small probability $p$. The…

Quantum Physics · Physics 2009-11-11 L. -M. Duan , R. Raussendorf

This work provides a quantum-computing-first derivation of the Unitary Coupled Cluster ansatz, showing that its structure emerges naturally from fermionic algebra under unitary constraints. By explicitly connecting second quantization,…

Quantum Physics · Physics 2026-04-24 Yu-Hao Chen , Renata Wong

The Coupled-Cluster theory is one of the most successful high precision methods used to solve the stationary Schr\"odinger equation. In this article, we address the mathematical foundation of this theory with focus on the advances made in…

Chemical Physics · Physics 2019-09-04 Andre Laestadius , Fabian M. Faulstich

In the one-way model of quantum computing, quantum algorithms are implemented using only measurements on an entangled initial state. Much of the hard work is done up-front when creating this universal resource, known as a cluster state, on…

Quantum Physics · Physics 2009-05-19 Steven T. Flammia , Nicolas C. Menicucci , Oliver Pfister

We propose an orbital optimized method for unitary coupled cluster theory (OO-UCC) within the variational quantum eigensolver (VQE) framework for quantum computers. OO-UCC variationally determines the coupled cluster amplitudes and also…

Strongly Correlated Electrons · Physics 2020-09-23 Wataru Mizukami , Kosuke Mitarai , Yuya O. Nakagawa , Takahiro Yamamoto , Tennin Yan , Yu-ya Ohnishi

Non-unitary theories are commonly seen in the classical simulations of quantum systems. Among these theories, the method of moments of coupled-cluster equations (MMCCs) and the ensuing classes of the renormalized coupled-cluster (CC)…

Quantum Physics · Physics 2022-12-13 Bo Peng , Karol Kowalski

We formulate a parity-mixed coupled-cluster (PM-CC) approach for high-precision calculations of parity non-conserving amplitudes in mono-valent atoms. Compared to the conventional formalism which uses parity-proper (PP) one-electron…

Atomic Physics · Physics 2022-02-16 H. B. Tran Tan , Di Xiao , A. Derevianko

We describe a generalization of the cluster-state model of quantum computation to continuous-variable systems, along with a proposal for an optical implementation using squeezed-light sources, linear optics, and homodyne detection. For…

We propose a feasible scheme to achieve quantum computation based on geometric manipulation of ensembles of atoms, and analyze it for neutral rubidium atoms magnetically trapped in planoconcave microcavities on an atom chip. The geometric…

Quantum Physics · Physics 2013-08-20 Yicong Zheng , Todd A. Brun

We propose a practical scheme for one-way quantum computing based on efficient generation of 2D cluster state in thermal cavities. We achieve a controlled-phase gate that is neither sensitive to cavity decay nor to thermal field by adding a…

Quantum Physics · Physics 2011-02-09 Wen-Xing Yang , Zhe-Xuan Gong

Many-particle confinement (localization) is studied for a 1D system of spinless fermions with nearest-neighbor hopping and interaction, or equivalently, for an anisotropic Heisenberg spin-1/2 chain. This system is frequently used to model…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 M. I. Dykman , L. F. Santos , M. Shapiro

We detail a quantum circuit capable of efficiently encoding analytical approximations to gravitational wave signal waveforms of compact binary coalescences into the amplitudes of quantum bits using both quantum arithmetic operations and…

Quantum Physics · Physics 2023-06-21 Fergus Hayes , Sarah Croke , Chris Messenger , Fiona Speirits

The coupled cluster method (CCM) is a method of quantum many-body theory that may provide accurate results for the ground-state properties of lattice quantum spin systems even in the presence of strong frustration and for lattices of…

Strongly Correlated Electrons · Physics 2009-11-11 D. J. J. Farnell , J. Schulenburg , J. Richter , K. A. Gernoth

This paper aims to present a fairly accessible generalization of several symmetric Gauss-Seidel decomposition based multi-block proximal alternating direction methods of multipliers (ADMMs) for convex composite optimization problems. The…

Optimization and Control · Mathematics 2020-06-09 Liang Chen , Defeng Sun , Kim-Chuan Toh , Ning Zhang

The curse of dimensionality (COD) limits the current state-of-the-art {\it ab initio} propagation methods for non-relativistic quantum mechanics to relatively few particles. For stationary structure calculations, the coupled-cluster (CC)…

Quantum Physics · Physics 2015-06-03 Simen Kvaal

We consider the possibility of performing linear optical quantum computation making use of extra photonic degrees of freedom. In particular we focus on the case where we use photons as quadbits. The basic 2-quadbit cluster state is a…

Quantum Physics · Physics 2015-05-13 Jaewoo Joo , Peter L. Knight , Jeremy L. O'Brien , Terry Rudolph

We present a quantum-classical hybrid algorithm that simulates electronic structures of periodic systems such as ground states and quasiparticle band structures. By extending the unitary coupled cluster (UCC) theory to describe crystals in…

Quantum Physics · Physics 2022-02-16 Nobuyuki Yoshioka , Takeshi Sato , Yuya O. Nakagawa , Yu-ya Ohnishi , Wataru Mizukami

The measurement based, or one-way, model of quantum computation for continuous variables uses a highly entangled state called a cluster state to accomplish the task of computing. Cluster states that are universal for computation are a…

Quantum Physics · Physics 2019-12-11 Darren W. Moore