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In recent experiments on ultracold matter, molecules have been produced from ultracold atoms by photoassociation, Feshbach resonances, and three-body recombination. The created molecules are translationally cold, but vibrationally highly…

Quantum Physics · Physics 2007-05-23 Christiane P. Koch , José P. Palao , Ronnie Kosloff , Françoise Masnou-Seeuws

Genetic algorithms, as implemented in optimal control strategies, are currently successfully exploited in a wide range of problems in molecular physics. In this context, laser control of molecular alignment and orientation remains a very…

Chemical Physics · Physics 2007-05-23 O. Atabek , C. M. Dion

The transfer of weakly bound KRb molecules from levels just below the dissociation threshold into the vibrational ground state with shaped laser pulses is studied. Optimal control theory is employed to calculate the pulses. The complexity…

Atomic Physics · Physics 2011-04-15 Mamadou Ndong , Christiane P. Koch

We propose a methodology to design optimal pulses for achieving quantum optimal control on molecular systems. Our approach constrains pulse shapes to linear combinations of a fixed number of experimentally relevant pulse functions. Quantum…

Quantum Physics · Physics 2015-10-28 Ruben D. Guerrero , Carlos A. Arango , Andres Reyes

We formulate a robust optimal control algorithm to synthesize minimum energy pulses that can transfer a cold atom system into various momentum states. The algorithm uses adaptive linearization of the evolution operator and sequential…

The lack of a direct map between control fields and desired control objectives poses a significant challenge in applying quantum control theory to quantum technologies. Here, we propose an analytical framework to precisely control a limited…

Quantum Physics · Physics 2025-03-05 Qian-Qian Hong , Daoyi Dong , Niels E. Henriksen , Franco Nori , Jun He , Chuan-Cun Shu

We develop an hybrid quantum-classical algorithm to solve an optimal population transfer problem for a molecule subject to a laser pulse. The evolution of the molecular wavefunction under the laser pulse is simulated on a quantum computer,…

Quantum Physics · Physics 2021-02-25 Davide Castaldo , Marta Rosa , Stefano Corni

We develop an optimization framework for high-efficiency quantum cycles implemented with a trapped Bose-Einstein condensate, whose control parameters are the trap stiffness and the interaction strength tuned via a Feshbach resonance.…

Quantum Physics · Physics 2026-05-22 Aaron Wandhammer , Vincent Hardel , Paul-Antoine Hervieux , Giovanni Manfredi

We consider the formation of cold ground-state polar molecules in a low vibrational level by laser fields. Starting from a pair of cold colliding atoms of dissimilar species, we propose a strategy consisting of three steps. In the first…

Atomic Physics · Physics 2026-01-14 Emanuel F. de Lima

We report the creation and characterization of a near quantum-degenerate gas of polar $^{40}$K-$^{87}$Rb molecules in their absolute rovibrational ground state. Starting from weakly bound heteronuclear KRb Feshbach molecules, we implement…

On the basis of optimal control theory, we numerically study how to optimally manipulate molecular vibrational dynamics by using cycle-averaged polarizability interactions induced by mildly intense non-resonant laser (NR) pulses. As the…

Quantum Physics · Physics 2024-09-05 Reon Ishii , Tomotaro Namba , Hiroyuki Katsuki , Kenji Ohmori , Yukiyoshi Ohtsuki

We present a combined analytical and numerical investigation to show how an optimal control field can be designed to generate maximum field-free orientation of molecules for three populated rotational states. Based on a model involving pure…

Quantum Physics · Physics 2021-07-28 Qian-Qian Hong , Li-Bao Fan , Chuan-Cun Shu , Niels E. Henriksen

Achieving high-fidelity control of quantum systems is of fundamental importance in physics, chemistry and quantum information sciences. However, the successful implementation of a high-fidelity quantum control scheme also requires…

Quantum Physics · Physics 2018-06-05 Yu Guo , Daoyi Dong , Chuan-Cun Shu

Starting from an initial pure quantum state, we present a strategy for reaching a target state corresponding to the extremum (maximum or minimum) of a given observable. We show that a sequence of pulses of moderate intensity, applied at…

Quantum Physics · Physics 2016-08-16 D. Sugny , A. Keller , O. Atabek , D. Daems , C. M. Dion , S. Guérin , H. R. Jauslin

We report on the efficient design of quantum optimal control protocols to manipulate the motional states of an atomic Bose-Einstein condensate (BEC) in a one-dimensional optical lattice. Our protocols operate on the momentum comb associated…

Quantum Gases · Physics 2021-10-13 N. Dupont , G. Chatelain , L. Gabardos , M. Arnal , J. Billy , B. Peaudecerf , D. Sugny , D. Guéry-Odelin

A strong inhomogeneous static electric field is used to spatially disperse a supersonic beam of polar molecules, according to their quantum state. We show that the molecules residing in the lowest-lying rotational states can be selected and…

Coherent carrier control in quantum nanostructures is studied within the framework of Optimal Control. We develop a general solution scheme for the optimization of an external control (e.g., lasers pulses), which allows to channel the…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Alfio Borzi , Georg Stadler , Ulrich Hohenester

We show that weakly-bound molecules can be probed by "shaking" in a pulsed nonresonant laser field. The field introduces a centrifugal term which expels the highest vibrational level from the potential that binds it. Our numerical…

Atomic Physics · Physics 2009-08-03 Mikhail Lemeshko , Bretislav Friedrich

Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…

Quantum Physics · Physics 2017-11-15 S. Kallush , J. L. Carini , P. L. Gould , R. Kosloff

We study the control by electromagnetic fields of molecular alignment and orientation, in a linear, rigid rotor model. With the help of a monotonically convergent algorithm, we find that the optimal field is in the microwave part of the…

Chemical Physics · Physics 2007-05-23 Julien Salomon , Claude M. Dion , Gabriel Turinici
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