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Using the technique of stimulated Raman adiabatic passage (STIRAP) we have coherently transferred ultracold 87Rb2 Feshbach molecules into a more deeply bound vibrational quantum level. Our measurements indicate a high transfer efficiency of…

Other Condensed Matter · Physics 2009-11-11 K. Winkler , F. Lang , G. Thalhammer , P. v. d. Straten , R. Grimm , J. Hecker Denschlag

Quantum state control is a fundamental tool for quantum technologies. In this work, we propose and analyze the use of quantum optimal control to exploit the dipolar interaction of ultracold atoms on a lattice ring, focusing on the…

We theoretically explore the precise control of a molecular polariton by strongly coupling the lowest three rotational states of a single molecule with a single-mode cavity. We examine two distinct cavity resonance configurations: a…

Quantum Physics · Physics 2025-02-17 Li-Bao Fan , Hai-Ji Li , Qi Chen , Hang Zhou , Heng Liu , Chuan-Cun Shu

By means of optimal control techniques we model and optimize the manipulation of the external quantum state (center-of-mass motion) of atoms trapped in adjustable optical potentials. We consider in detail the cases of both non interacting…

Control over the quantum states of individual molecules is crucial in the quest to harness their rich internal structure and dipolar interactions for applications in quantum science. In this paper, we develop a toolbox of techniques for the…

Atomic Physics · Physics 2024-08-28 Daniel K. Ruttley , Alexander Guttridge , Tom R. Hepworth , Simon L. Cornish

A strong inhomogeneous static electric field is used to spatially disperse a rotationally cold supersonic beam of 2,6-difluoroiodobenzene molecules according to their rotational quantum state. The molecules in the lowest lying rotational…

We explore the possibility of forming a oriented polar molecule directly from a pair of colliding atoms. The process comprises the photoassociation and vibrational stabilization along with the molecular orientation. These processes are…

Quantum Physics · Physics 2026-01-14 Murilo D. Forlevesi , Edson Denis Leonel , Emanuel F. de Lima

A gradient-based optimization approach combined with automatic differentiation is employed to ensure high accuracy and scalability when working with high-dimensional parameter spaces. Numerical simulations confirm the effectiveness of the…

Quantum Physics · Physics 2025-07-15 Roman Sahakyan , Romik Sargsyan , Edgar Pogosyan , Karen Arzumanyan , Emil A. Gazazyan

Laser cooling of molecules employing broadband optical pumping involves a timescale separation between laser excitation and spontaneous emission. Here, we optimize the optical pumping step using shaped laser pulses. We derive two…

Quantum Physics · Physics 2013-12-24 Daniel M. Reich , Christiane P. Koch

We investigate two classes of quantum control problems by using frequency-domain optimization algorithms in the context of ultrafast laser control of quantum systems. In the first class, the system model is known and a frequency-domain…

Quantum Physics · Physics 2022-01-19 Daoyi Dong , Chuan-Cun Shu , Jiangchao Chen , Xi Xing , Hailan Ma , Yu Guo , Herschel Rabitz

We discuss the production of ultracold molecules in their electronic ground state by photoassociation employing electronically excited states with ion-pair character and strong spin-orbit interaction. A short photoassociation laser pulse…

A robust control over quantum dynamics is of paramount importance for quantum technologies. Many of the existing control techniques are based on smooth Hamiltonian modulations involving repeated calculations of basic unitaries resulting in…

Quantum Physics · Physics 2016-05-04 Gaurav Bhole , Anjusha V. S. , T. S. Mahesh

In this work, we investigate how and to which extent a quantum system can be driven along a prescribed path in Hilbert space by a suitably shaped laser pulse. To calculate the optimal, i.e., the variationally best pulse, a properly defined…

Quantum Physics · Physics 2007-05-23 I. Serban , J. Werschnik , E. K. U. Gross

We study three methods of obtaining an approximation of unitary evolution of a quantum system under decoherence. We use three methods of optimizing the control pulses: genetic optimization, approximate evolution method and approximate…

Quantum Physics · Physics 2020-11-10 Łukasz Pawela , Przemysław Sadowski

We present some approaches to the computation of ultra-fast laser pulses capable of selectively breaking molecular bonds. The calculations are based on a mixed quantum-classical description: The electrons are treated quantum mechanically…

Atomic and Molecular Clusters · Physics 2015-05-27 Kevin Krieger , Alberto Castro , E. K. U. Gross

Short-pulse fibre lasers are a complex dynamical system possessing a broad space of operating states that can be accessed through control of cavity parameters. Determination of target regimes is a multi-parameter global optimisation…

Optics · Physics 2017-06-15 R. I. Woodward , E. J. R. Kelleher

We demonstrate, numerically, the possibility of manipulating the spin states of molecular nanomagnets with shaped microwave pulses designed with quantum optimal control theory techniques. The state-to-state or full gate transformations can…

Quantum Physics · Physics 2021-12-01 Alberto Castro , Adrian Garcia Carrizo , David Zueco , Fernando Luis

We propose a method for achieving highly efficient transfer between the vibrational states in a diatomic molecule. The process is mediated by strong laser pulses and can be understood in terms of light-induced potentials. In addition to…

Quantum Physics · Physics 2009-11-06 M. Rodriguez , K. -A. Suominen , B. M. Garraway

We present an analysis of two experimental approaches to controlling the directionality of molecular rotation with ultrashort laser pulses. The two methods are based on the molecular interaction with either a pair of pulses (a "double kick"…

Optics · Physics 2015-06-11 C. Bloomquist , S. Zhdanovich , A. A. Milner , V. Milner

In this work, we study strategies for the optical control, within the dipole approximation, of a qubit encoded in the three-electron states of a triple quantum dot. The system is described by effective confining potentials, and its…

Mesoscale and Nanoscale Physics · Physics 2019-01-30 Diego S. Acosta Coden , Sergio S. Gomez , Rodolfo H. Romero , Omar Osenda , Alejandro Ferrón