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The optical properties of infinite planar array of scattering particles, metasurfaces and metagratings, are attracting special attention lately for their rich phenomenology, including both plasmonic and high-refractive-index dielectric…

We present a general theoretical treatment and calculations of the fine and hyperfine structures in the spectra of high-$n$ molecular Rydberg states in static uniform electric fields. The treatment combines (i) multichannel quantum-defect…

Atomic Physics · Physics 2026-04-22 Ioana Doran , Leon Jeckel , Maximilian Beyer , Christian Jungen , Frédéric Merkt

Within the finite-field Kohn-Sham framework, static electric response properties of diatomic molecules are presented. The electronic energy, dipole moment ({\boldmath$\mu$}), static dipole polarizability ({\boldmath$\alpha$}) and…

Chemical Physics · Physics 2019-04-26 Abhisek Ghosal , Tanmay Mandal , Amlan K. ~Roy

By making use of the quantization rule of Raab and Friedrich [P. Raab and H. Friedrich, Phys. Rev. A 78, 022707 (2008)], we derive simple and accurate formulae for the number of rotational states supported by a weakly-bound vibrational…

Atomic Physics · Physics 2009-06-08 Mikhail Lemeshko , Bretislav Friedrich

Random Phase Approximation (RPA) is the basic method for calculation of excited states of nuclei over the Hartree-Fock ground state, suitable also for energy density functionals (EDF or DFT). We developed a convenient formalism for…

Nuclear Theory · Physics 2025-06-19 Anton Repko , Jan Kvasil , V. O. Nesterenko , P. -G. Reinhard

We investigate the dynamics of a rotating Morse wave packet, appropriate for a ro-vibrating diatomic molecule. The coupling between vibrational and rotational degrees of freedom is explicated in real position space as well as in phase space…

Quantum Physics · Physics 2009-07-20 Utpal Roy , Suranjana Ghosh

An analogy between asymmetric rotor molecules and anisotropic cosmology can be used to calculate new centrifugal distortion terms in the effective potential of asymmetric rotor molecules which have no internal 3-fold symmetry. The torsional…

Chemical Physics · Physics 2013-03-26 Ian G. Moss

Boron subphthalocyanine chloride is an electron donor material used in small molecule organic photovoltaics with an unusually large molecular dipole moment. Using first-principles calculations, we investigate enhancing the electronic and…

Materials Science · Physics 2017-05-08 Michael J. Waters , Daniel Hashemi , Guangsha Shi , Emmanouil Kioupakis , John Kieffer

A new numerical method is introduced for calculating the polarizability of an arbitrary dielectric object with position dependent complex permittivity. Three separate numerical approaches are provided to calculate the dipole moment of a…

Materials Science · Physics 2022-03-18 Daniel B. Murray , Caleb H. Netting , Robin D. Mercer , Lucien Saviot

An inhomogeneous electric field is used to study the deflection of a supersonic beam of water molecules. The deflection profiles show strong broadening accompanied by a small net displacement towards higher electric fields. The profiles are…

Chemical Physics · Physics 2009-11-13 Ramiro Moro , Jaap Bulthuis , Jonathon Heinrich , Vitaly V. Kresin

We study polar alkali dimer scattering in a quasi-1D geometry for both reactive and non-reactive species. Elastic and reactive rates are computed as a function of the amplitude of a static electric field within a purely long-range model…

Atomic Physics · Physics 2019-09-19 Romain Vexiau , Jean-Michel Launay , Andrea Simoni

We present the results of our quantum annealing computations of the permanent electric dipole moments of several molecules. By applying an electric field as a perturbation and measuring the corresponding energy responses, the molecular…

Quantum Physics · Physics 2025-12-08 Pradyot Pritam Sahoo , V. S. Prasannaa , B. P. Das

We utilize the gradient flow to define and calculate electric dipole moments induced by the strong QCD $\theta$-term and the dimension-6 Weinberg operator. The gradient flow is a promising tool to simplify the renormalization pattern of…

High Energy Physics - Lattice · Physics 2018-04-18 Jack Dragos , Thomas Luu , Andrea Shindler , Jordy de Vries

We consider a bound system of particles interacting via electromagnetic forces in an external electromagnetic field, including leading relativistic corrections. Each particle has a definite mass, charge, spin, and charge radius. We…

Atomic Physics · Physics 2015-06-22 Albert Wienczek , Mariusz Puchalski , Krzysztof Pachucki

Measuring the Hamiltonian of dipolar coupled spin systems is usually a difficult task due to the high complexity of their spectra. Currently, molecules with unknown geometrical structure and low symmetry are extremely tedious or impossible…

Quantum Physics · Physics 2013-12-10 Denis-Alexandre Trottier , Virginia Jauregui-Villanueva , Jingfu Zhang

We present a unified variational treatment of the electric quadrupole (E2) matrix elements, Einstein coefficients, and line strengths for general open-shell diatomic molecules in the general purpose diatomic code \Duo. Transformation…

Atomic and Molecular Clusters · Physics 2021-11-11 Wilfrid Somogyi , Sergey N. Yurchenko , Andrey Yachmenev

In recent years, ultracold atoms in optical lattices have proven their great value as quantum simulators for studying strongly correlated phases and complex phenomena in solid-state systems. Here we reveal their potential as quantum…

Quantum Gases · Physics 2015-11-24 Dirk-Sören Lühmann , Christof Weitenberg , Klaus Sengstock

The prospects for shielding ultracold, paramagnetic, dipolar molecules from inelastic and chemical collisions are investigated. Molecules placed in their first rotationally excited states are found to exhibit effective long-range repulsion…

Atomic Physics · Physics 2016-01-20 Goulven Quéméner , John L. Bohn

A procedure for calculation of rotation-vibration states of medium sized molecules is presented. It combines the advantages of variational calculations and perturbation theory. The vibrational problem is solved by diagonalizing a…

Chemical Physics · Physics 2015-04-13 A. I. Pavlyuchko , S. N. Yurchenko , Jonathan Tennyson

In this study, we investigate the structure of the polar alkali-Strontium diatomic molecules as possible candidates for the realization of samples of new species of ultracold polar molecules. Using a quantum chemistry approach based on…

Atomic and Molecular Clusters · Physics 2015-05-19 Romain Guérout , Mireille Aymar , Olivier Dulieu
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