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Retrosynthetic planning aims to devise a complete multi-step synthetic route from starting materials to a target molecule. Current strategies use a decoupled approach of single-step retrosynthesis models and search algorithms, taking only…

Machine Learning · Computer Science 2023-06-01 Songtao Liu , Zhengkai Tu , Minkai Xu , Zuobai Zhang , Lu Lin , Rex Ying , Jian Tang , Peilin Zhao , Dinghao Wu

There is an intuitive analogy of an organic chemist's understanding of a compound and a language speaker's understanding of a word. Consequently, it is possible to introduce the basic concepts and analyze potential impacts of linguistic…

Machine Learning · Computer Science 2017-11-16 Philippe Schwaller , Theophile Gaudin , David Lanyi , Costas Bekas , Teodoro Laino

Retrosynthesis plays a crucial role in the fields of organic synthesis and drug development, where the goal is to identify suitable reactants that can yield a target product molecule. Although existing methods have achieved notable success,…

Machine Learning · Computer Science 2025-10-20 Jiaxi Zhuang , Yu Zhang , Yan Zhang , Ying Qian , Aimin Zhou

Retrosynthesis prediction is a core task in organic synthesis that aims to predict reactants for a given product molecule. Traditionally, chemists select a plausible bond disconnection and derive corresponding reactants, which is…

Machine Learning · Computer Science 2026-03-16 Hanbum Ko , Chanhui Lee , Ye Rin Kim , Rodrigo Hormazabal , Sehui Han , Sungbin Lim , Sungwoong Kim

Organic synthesis stands as a cornerstone of the chemical industry. The development of robust machine learning models to support tasks associated with organic reactions is of significant interest. However, current methods rely on…

Machine Learning · Computer Science 2025-01-06 Kaipeng Zeng , Xianbin Liu , Yu Zhang , Xiaokang Yang , Yaohui Jin , Yanyan Xu

Motivation: Retrosynthesis planning poses a formidable challenge in the organic chemical industry. Single-step retrosynthesis prediction, a crucial step in the planning process, has witnessed a surge in interest in recent years due to…

Chemical Physics · Physics 2024-04-22 Kaipeng Zeng , Bo yang , Xin Zhao , Yu Zhang , Fan Nie , Xiaokang Yang , Yaohui Jin , Yanyan Xu

Retrosynthesis consists of breaking down a chemical compound recursively step-by-step into molecular precursors until a set of commercially available molecules is found with the goal to provide a synthesis route. Its two primary research…

Artificial Intelligence · Computer Science 2024-03-12 Paula Torren-Peraire , Alan Kai Hassen , Samuel Genheden , Jonas Verhoeven , Djork-Arne Clevert , Mike Preuss , Igor Tetko

Synthesis planning is the process of recursively decomposing target molecules into available precursors. Computer-aided retrosynthesis can potentially assist chemists in designing synthetic routes, but at present it is cumbersome and…

Chemical Physics · Physics 2019-07-04 Shuangjia Zheng , Jiahua Rao , Zhongyue Zhang , Jun Xu , Yuedong Yang

While inorganic retrosynthesis planning is essential in the field of chemical science, the application of machine learning in this area has been notably less explored compared to organic retrosynthesis planning. In this paper, we propose…

Machine Learning · Computer Science 2025-10-14 Heewoong Noh , Namkyeong Lee , Gyoung S. Na , Chanyoung Park

The reaction center consists of atoms in the product whose local properties are not identical to the corresponding atoms in the reactants. Prior studies on reaction center identification are mainly on semi-templated retrosynthesis methods.…

Machine Learning · Computer Science 2023-01-31 Zixun Lan , Zuo Zeng , Binjie Hong , Zhenfu Liu , Fei Ma

Structured chemical reaction information plays a vital role for chemists engaged in laboratory work and advanced endeavors such as computer-aided drug design. Despite the importance of extracting structured reactions from scientific…

Computation and Language · Computer Science 2023-07-06 Ming Zhong , Siru Ouyang , Minhao Jiang , Vivian Hu , Yizhu Jiao , Xuan Wang , Jiawei Han

Computer-assisted synthesis planning aims to help chemists find better reaction pathways faster. Finding viable and short pathways from sugar molecules to value-added chemicals can be modeled as a retrosynthesis planning problem with a…

Other Computer Science · Computer Science 2019-11-19 Peihong Jiang , Hieu Doan , Sandeep Madireddy , Rajeev Surendran Assary , Prasanna Balaprakash

Single-step retrosynthesis is the cornerstone of retrosynthesis planning, which is a crucial task for computer-aided drug discovery. The goal of single-step retrosynthesis is to identify the possible reactants that lead to the synthesis of…

Quantitative Methods · Quantitative Biology 2022-08-12 Huarui He , Jie Wang , Yunfei Liu , Feng Wu

We propose a new model for making generalizable and diverse retrosynthetic reaction predictions. Given a target compound, the task is to predict the likely chemical reactants to produce the target. This generative task can be framed as a…

Machine Learning · Computer Science 2019-10-23 Benson Chen , Tianxiao Shen , Tommi S. Jaakkola , Regina Barzilay

From medicines to materials, small organic molecules are indispensable for human well-being. To plan their syntheses, chemists employ a problem solving technique called retrosynthesis. In retrosynthesis, target molecules are recursively…

Artificial Intelligence · Computer Science 2018-04-17 Marwin H. S. Segler , Mike Preuss , Mark P. Waller

A fundamental problem in computational chemistry is to find a set of reactants to synthesize a target molecule, a.k.a. retrosynthesis prediction. Existing state-of-the-art methods rely on matching the target molecule with a large set of…

Machine Learning · Computer Science 2021-08-23 Chence Shi , Minkai Xu , Hongyu Guo , Ming Zhang , Jian Tang

Retrosynthesis, of which the goal is to find a set of reactants for synthesizing a target product, is an emerging research area of deep learning. While the existing approaches have shown promising results, they currently lack the ability to…

Machine Learning · Computer Science 2021-06-04 Hankook Lee , Sungsoo Ahn , Seung-Woo Seo , You Young Song , Eunho Yang , Sung-Ju Hwang , Jinwoo Shin

Retrosynthesis is the process of determining the set of reactant molecules that can react to form a desired product. Semi-template-based retrosynthesis methods, which imitate the reverse logic of synthesis reactions, first predict the…

Machine Learning · Computer Science 2024-04-01 Frazier N. Baker , Ziqi Chen , Daniel Adu-Ampratwum , Xia Ning

Organic synthesis is one of the key stumbling blocks in medicinal chemistry. A necessary yet unsolved step in planning synthesis is solving the forward problem: given reactants and reagents, predict the products. Similar to other work, we…

Chemical Physics · Physics 2019-09-13 Philippe Schwaller , Teodoro Laino , Théophile Gaudin , Peter Bolgar , Costas Bekas , Alpha A Lee

We cast retrosynthesis as a machine translation problem by introducing a special Tensor2Tensor, an entire attention-based and fully data-driven model. Given a data set comprising about 50,000 diverse reactions extracted from USPTO patents,…

Chemical Physics · Physics 2019-08-05 Hongliang Duan , Ling Wang , Chengyun Zhang , Jianjun Li