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An exact general theory of heteronuclear decoupling is presented for spin-1/2 IS systems. RF irradiation applied to the I spins decouples the S spins by reversing the sign of antiphase magnetization. A one-to-one correspondence is…

Chemical Physics · Physics 2015-06-19 Thomas E. Skinner

Magnetic resonance with ensembles of electron spins is nowadays performed in frequency ranges up to 240 GHz and in corresponding magnetic fields of up to 10 T. However, experiments with single electron and nuclear spins so far only reach…

Ethyl cyanide is an abundant molecule in hot molecular clouds. Lines from 13C isotopically substituted ethyl cyanide were identified in Orion. To enable the search and the possible detection of other isotopologues of ethyl cyanide in…

We theoretically propose a multidimensional high-harmonic echo spectroscopy technique which utilizes strong optical fields to resolve coherent electron dynamics spanning an energy range of multiple electron Volts. Using our recently…

Analysis of 1H-NMR spectra is often hindered by large variations that occur during the collection of these spectra. Large solvent and standard peaks, base line drift and negative peaks (due to improper phasing) are among some of these…

Signal Processing · Electrical Eng. & Systems 2020-12-18 Homayoun Valafar , Faramarz Valafar

We report the coherent coupling of two electron spins at a distance via virtual microwave photons. Each spin is trapped in a silicon double quantum dot at either end of a superconducting resonator, achieving spin-photon couplings up to…

Mesoscale and Nanoscale Physics · Physics 2022-05-13 Patrick Harvey-Collard , Jurgen Dijkema , Guoji Zheng , Amir Sammak , Giordano Scappucci , Lieven M. K. Vandersypen

We propose and characterize experimentally a new source of optical frequency combs for performing multi-heterodyne spectrometry. This comb modality is based on a frequency shifting loop seeded with a CW monochromatic laser. The comb lines…

Optics · Physics 2018-07-04 V. Duran , C. Schnebelin , H. Guillet De Chatellus

We present single- and multiple-quantum correlation $J$-spectroscopy detected in zero ($<\!\!1$~$\mu$G) magnetic field using a \Rb vapor-cell magnetometer. At zero field the spectrum of ethanol appears as a mixture of \carbon isotopomers,…

Chemical Physics · Physics 2020-08-26 Tobias F. Sjolander , John W. Blanchard , Dmitry Budker , Alexander Pines

The 150Sm nucleus has been studied to high spins in a measurement of gamma radiation following the 136Xe(18O,4n)150Sm, compound-nucleus reaction at beam energy of 76 MeV. The measurement was performed at NBI Riso using the NORDBALL array.…

Nuclear Theory · Physics 2007-05-23 W. Urban , J. C. Bacelar , J. Nyberg

We demonstrate a method to quantify and manipulate nuclear spin decoherence mechanisms that are active in zero to ultralow magnetic fields. These include: (i) non-adiabatic switching of spin quantization axis, due to residual background…

Chemical Physics · Physics 2022-06-28 Sven Bodenstedt , Morgan W. Mitchell , Michael C. D. Tayler

Nuclear magnetic resonance (NMR) is a powerful tool for applications ranging from chemical analysis to quantum information processing. Achieving optical initialization and detection of molecular nuclear spins promises new opportunities -…

We experimentally disentangle the contributions of different quantum paths in high-order harmonic generation (HHG) from the spectrally and spatially resolved harmonic spectra. By adjusting the laser intensity and focusing position, we…

Atomic Physics · Physics 2015-10-08 Lixin He , Pengfei Lan , Qingbin Zhang , Chunyang Zhai , Feng Wang , Wenjing Shi , Peixiang Lu

We describe a quasi-optical multifrequency ESR spectrometer operating in the 75-225 GHz range and optimized at 210 GHz for general use in condensed matter physics, chemistry and biology. The quasi-optical bridge detects the change of mm…

Materials Science · Physics 2012-10-23 Kalman L Nagy , Dario Quintavalle , Titusz Feher , Andras Janossy

For future quantum technologies the combination of a long quantum state lifetime and an efficient interface with external optical excitation are required. In solids, the former is for example achieved by individual spins, while the latter…

Spin ensemble based hybrid quantum systems suffer from a significant degree of decoherence resulting from the inhomogeneous broadening of the spin transition frequencies in the ensemble. We demonstrate that this strongly restrictive…

Quantum Physics · Physics 2015-07-15 Dmitry O. Krimer , Benedikt Hartl , Stefan Rotter

In this work, we experimentally manipulate the spectrum and phase of a biphoton wave packet in a two-dimensional frequency space. The spectrum is shaped by adjusting the temperature of the crystal, and the phase is controlled by tilting the…

Quantum Physics · Physics 2018-08-14 Rui-Bo Jin , Ryoji Shiina , Ryosuke Shimizu

With increasing energy the diamagnetic hydrogen atom undergoes a transition from regular to chaotic classical dynamics, and the closed orbits pass through various cascades of bifurcations. Closed orbit theory allows for the semiclassical…

Chaotic Dynamics · Physics 2007-05-23 T. Fabcic , J. Main , T. Bartsch , G. Wunner

Spectroscopy is a powerful tool for studying molecules and is commonly performed on large thermal molecular ensembles that are perturbed by motional shifts and interactions with the environment and one another, resulting in convoluted…

The formation of diatomic molecules with rotational and vibrational coherence is demonstrated experimentally in free-to-bound two-photon femtosecond photoassociation of hot atoms. In a thermal gas at a temperature of 1000 K, pairs of…

Coupling a single spin to high-frequency mechanical motion is a fundamental bottleneck of applications such as quantum sensing, intermediate and long-distance spin-spin coupling, and classical and quantum information processing. Previous…