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The physical conditions in a collapsing cloud can be traced by observations of molecular lines. To correctly interpret these observations the abundance distributions of the observed species need to be derived. The chemistry in a collapsing…

Solar and Stellar Astrophysics · Physics 2009-11-13 R. J. van Weeren , C. Brinch , M. R. Hogerheijde

General characteristics of methanol (CH3OH) maser emission are summarized. It is shown that methanol maser sources are concentrated in the spiral arms. Most of the methanol maser sources from the Perseus arm are associated with embedded…

We present an extensive review of gas phase reactions producing methylacetylene and propene showing that these relatively abundant unsaturated hydrocarbons cannot be synthesized through gas-phase reactions. We explain the formation of…

Astrophysics of Galaxies · Physics 2016-03-10 Kevin M. Hickson , Valentine Wakelam , Jean-Christophe Loison

We report on a search for Interstellar CH2D+. Four transitions occur in easily accessible portions of the spectrum; we report on emission at the frequencies of these transitions toward high column density star-forming regions. While the…

Astrophysics · Physics 2019-02-12 Alwyn Wootten , Barry E. Turner

Context. Millimetric observations have measured high degrees of molecular deuteration in several species seen around low-mass protostars. The Herschel Space Telescope, launched in 2009, is now providing new measures of the deuterium…

Astrophysical observations show complex organic molecules (COMs) in the gas phase of protoplanetary disks. X-rays emitted from the central young stellar object (YSO) that irradiate interstellar ices in the disk, followed by the ejection of…

Earth and Planetary Astrophysics · Physics 2021-02-22 R. Basalgète , R. Dupuy , G. Féraud , C. Romanzin , L. Philippe , X. Michaut , J. Michoud , L. Amiaud , A. Lafosse , J. -H. Fillion , M. Bertin

The millimeter-wave rotational transition line ($J_K = 1_0 - 0_0$) of deuterated methane CH$_3$D has tentatively been detected toward the low-mass Class 0 protostar IRAS 04368+2557 in L1527 with the Heinrich Hertz Submillimeter Telescope.…

Solar and Stellar Astrophysics · Physics 2015-06-11 Nami Sakai , Yancy L. Shirley , Takeshi Sakai , Tomoya Hirota , Yoshimasa Watanabe , Satoshi Yamamoto

Based on recent work, formamide might be a potentially very important molecule in the emergence of terrestrial life. Although detected in the interstellar medium for decades, its formation route is still debated, whether in the gas phase or…

Solar and Stellar Astrophysics · Physics 2017-07-19 D. Skouteris , F. Vazart , C. Ceccarelli , N. Balucani , C. Puzzarini , V. Barone

We report the detection of interstellar methoxymethanol (CH$_3$OCH$_2$OH) in ALMA Bands 6 and 7 toward the MM1 core in the high-mass star-forming region NGC 6334I at ~0.1" - 1" spatial resolution. A column density of 4(2) x $10^{18}$…

Propargyl alcohol (HC2CH2OH, PA) has yet to be observed in the interstellar medium (ISM) although one of its stable isomers, propenal (CH2CHCHO), has already been detected in Sagittarius B2(N) with the 100-meter Green Bank Telescope in the…

Astrophysics of Galaxies · Physics 2017-01-24 Prasanta Gorai , Ankan Das , Liton Majumdar , Sandip Kumar Chakrabarti , Bhalamurugan Sivaraman , Eric Herbst

Disentangling the different stages of the star-formation process, in particular in the high-mass regime, is a challenge in astrophysics. Chemical clocks could help alleviating this problem, but their evolution strongly depends on many…

Astrophysics of Galaxies · Physics 2020-01-08 S. Bovino , S. Ferrada-Chamorro , A. Lupi , G. Sabatini , A. Giannetti , D. R. G. Schleicher

Aims: The gas-phase abundance of methanol in dark quiescent cores in the interstellar medium cannot be explained by gas-phase chemistry. In fact, the only possible synthesis of this species appears to be production on the surfaces of dust…

Astrophysics · Physics 2009-11-13 R. T. Garrod , V. Wakelam , E. Herbst

This research found that when an acidic solution with a low surface tension spread on the surface of a glycerol solution mixed with milk, a star shaped pattern was spontaneously formed on the surface in the horizontal plane during the…

Soft Condensed Matter · Physics 2021-02-03 Michiko Shimokawa , Hiroyuki Kitahata , Hidetsugu Sakaguchi

Deuterated molecules are a useful diagnostic tool to probe the evolution and the kinematics in the earliest stages of star formation. Due to the low temperatures and high densities in the centre of pre-stellar cores, the deuterium fraction…

Astrophysics of Galaxies · Physics 2026-01-23 K. Giers , S. Spezzano , Y. Lin , P. Caselli , O. Sipilä

The aim of the presented work is to analyze the impact of experimentally evaluated reactions of hydrogen abstraction on surfaces of interstellar grains on the chemical evolution of methanol and its precursors on grains and in the gas phase…

Astrophysics of Galaxies · Physics 2021-03-24 V. A. Sokolova

We present the detection of ethanol (C2H5OH), acetone (CH3COCH3), and propanal (C2H5CHO) toward the cyanopolyyne peak of TMC-1. These three O-bearing complex organic molecules are known to be present in warm interstellar clouds, but had…

Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…

Solar and Stellar Astrophysics · Physics 2009-06-15 G. W. Fuchs , H. M. Cuppen , S. Ioppolo , C. Romanzin , S. E. Bisschop , S. Andersson , E. F. van Dishoeck , H. Linnartz

Gas-phase complex organic molecules have been detected toward a range of high- and low-mass star-forming regions at abundances which cannot be explained by any known gas-phase chemistry. Recent laboratory experiments show that UV…

Astrophysics of Galaxies · Physics 2015-05-18 Karin I. Oberg , Sandrine Bottinelli , Jes K. Jorgensen , Ewine F. van Dishoeck

Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the…