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The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…

Astrophysics of Galaxies · Physics 2015-07-15 Th. Gerner , Y. Shirley , H. Beuther , D. Semenov , H. Linz , T. Abertsson , Th. Henning

Pre-stellar cores represent the earliest stage of the star- and planet-formation process. By characterizing the physical and chemical structure of these cores we can establish the initial conditions for star and planet formation and…

Astrophysics of Galaxies · Physics 2023-07-05 S. S. Jensen , S. Spezzano , P. Caselli , T. Grassi , T. Haugbølle

High deuterium fractionation is observed in various types of environment such as prestellar cores, hot cores and hot corinos. It has proven to be an efficient probe to study the physical and chemical conditions of these environments. The…

Astrophysics of Galaxies · Physics 2015-05-18 Karine Demyk , S. Bottinelli , Emmanuel Caux , Charlotte Vastel , Cecilia Ceccarelli , Claudine Kahane , Alain Castets

Methanol is the most complex molecule securely identified in interstellar ices and is a key chemical species for understanding chemical complexity in astrophysical environments. Important aspects of the methanol ice photochemistry are still…

Astrophysics of Galaxies · Physics 2023-05-10 W. R. M. Rocha , P. Woitke , S. Pilling , W. -F. Thi , J. K. Jørgensen , L. E. Kristensen , G. Perotti , I. Kamp

We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…

Astrophysics · Physics 2009-11-11 F. Fontani , P. Caselli , A. Crapsi , R. Cesaroni , S. Molinari , L. Testi , J. Brand

Methanol and formaldehyde are two simple organic molecules that are ubiquitously detected in the interstellar medium. An origin in the solid phase and a subsequent nonthermal desorption into the gas phase is often invoked to explain their…

Astrophysics of Galaxies · Physics 2016-04-20 R. Martín-Doménech , G. M. Muñoz Caro , G. A. Cruz-Díaz

Previous radio observations revealed widespread gas-phase methanol (CH$_3$OH) in the Central Molecular Zone (CMZ) at the Galactic center (GC), but its origin remains unclear. Here, we report the discovery of CH$_3$OH ice toward a star in…

Astrophysics of Galaxies · Physics 2017-07-26 Deokkeun An , Kris Sellgren , A. C. Adwin Boogert , Solange V. Ramírez , Tae-Soo Pyo

Icy grain mantles are commonly observed through infrared spectroscopy toward dense clouds, cloud cores, protostellar envelopes and protoplanetary disks. Up to 80% of the available oxygen, carbon and nitrogen are found in such ices; the most…

We have started a measurement campaign of numerous methanol isotopologs in low-lying torsional states in order to provide extensive line lists for radio astronomical observations from an adequate spectroscopic model and to investigate how…

Observations of low mass protostars which probe small enough size scales to be within likely CO depletion regions show the highest [NH2D]/[NH3] ratios yet measured, of 4--33%. These molecular D/H ratios are higher than those measured on…

Astrophysics · Physics 2011-05-23 Jennifer Hatchell

We sought to determine which are the main hydrogenation paths of acetaldehyde (CH3CHO). As a partially unsaturated molecule, CH3CHO can have links with more hydrogenated species, like ethanol (C2H5OH) or with more unsaturated ones, like…

Astrophysics of Galaxies · Physics 2025-02-26 Germán Molpeceres , Thanh Nguyen , Yasuhiro Oba , Naoki Watanabe

We present observations of methanol lines in a sample of Class 0 low mass protostars. Using a 1-D radiative transfer model, we derive the abundances in the envelopes. In two sources of the sample, the observations can only be reproduced by…

Astrophysics · Physics 2007-05-23 S. Maret , C. Ceccarelli , A. G. G. M. Tielens , E. Caux , B. Lefloch , A. Faure , A. Castets , D. R. Flower

1-propanol (CH3CH2CH2OH) is a three carbon-bearing representative of primary linear alcohols that may have its origin in the cold dark cores in interstellar space. To test this, we investigated in the laboratory whether 1-propanol ice can…

Solar and Stellar Astrophysics · Physics 2019-06-26 D. Qasim , G. Fedoseev , K. -J. Chuang , V. Taquet , T. Lamberts , J. He , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Deuterium enhancement of monodeuterated species has been recognized for more than 30 years as a result of the chemical fractionation that results from the difference in zero point energies of deuterated and hydrogenated molecules. The key…

Astrophysics · Physics 2009-11-11 Charlotte Vastel , T. G. Phillips , P. Caselli , C. Ceccarelli , L. Pagani

Formaldehyde (H$_2$CO) and methanol (CH$_3$OH) have served as traditional tracers of the star formation process for decades. Studies of the environments which produce these species, though, have pointed to significant differences in the…

Astrophysics of Galaxies · Physics 2025-05-23 K. -Y. Huang , E. Behrens , M. Bouvier , S. Viti , J. G. Mangum , C. Eibensteiner

Water in outflows from protostars originates either as a result of gas-phase synthesis from atomic oxygen at T > 200 K, or from sputtered ice mantles containing water ice. We aim to quantify the contribution of the two mechanisms that lead…

Astrophysics of Galaxies · Physics 2015-06-18 Aleksi N. Suutarinen , Lars E. Kristensen , Joseph C. Mottram , Helen J. Fraser , Ewine F. van Dishoeck

Despite the detection of numerous interstellar complex organic molecules (iCOMs) for decades, it is still a matter of debate whether they are synthesized in the gas-phase or on the icy surface of interstellar grains. In the past, molecular…

Chemical Physics · Physics 2022-11-22 F. Vazart , C. Ceccarelli , D. Skouteris , N. Balucani

The outer Galaxy is an environment with metallicity lower than the Solar one and, because of this, the formation and survival of molecules in star-forming regions located in the inner and outer Galaxy is expected to be different. To gain…

The initial stage of star formation is a complex area study because of its high density and low temperature. Under such conditions, many molecules become depleted from the gas phase by freezing out onto dust grains. However, the deuterated…

Methanol masers which are traditionally divided into two classes provide possibility to study important parts of the star forming regions: Class~II masers trace vicinities of the massive YSOs while class~I masers are likely to trace more…