Related papers: Modified Poisson-Boltzmann equations and macroscop…
Starting from the stochastic equation for the density operator, we formulate the exact (instantaneous) stress tensor for interacting Brownian particles, whose average value agrees with expressions derived previously. We analyze the relation…
We develop a geometric formulation of fluid dynamics, valid on arbitrary Riemannian manifolds, that regards the momentum-flux and stress tensors as 1-form valued 2-forms, and their divergence as a covariant exterior derivative. We review…
A generalized Hydrodynamics, referred to as Mesoscopic Hydro-Thermodynamics, of phonons in semiconductors is presented. It involves the descriptions of the motion of the quasi-particle density and of the energy density. The hydrodynamic…
A model is presented for the solution of electrokinetic phenomena of colloidal suspensions in fluid mixtures. We solve the discrete Boltzmann equation with a BGK collision operator using the lattice Boltzmann method to simulate binary fluid…
We present a nonlocal statistical field theory of a dilute electrolyte solution with small additive of dipolar particles. We postulate that every dipolar particle is associated with an arbitrary probability distribution function (PDF) of…
When ions are crowded, the effect of steric repulsion between ions (which can produce oscillations in charge density profiles) becomes significant and the conventional Poisson-Boltzmann (PB) equation should be modified. Several modified PB…
Room temperature ionic liquids are attractive to numerous applications and particularly, to renewable energy devices. As solvent free electrolytes, they demonstrate a paramount connection between the material morphology and Coulombic…
The Barker-Henderson perturbation theory is a bedrock of liquid-state physics, providing quantitative predictions for the bulk thermodynamic properties of realistic model systems. However, this successful method has not been exploited for…
We present theoretical and numerical studies on stiff, linear polyelectrolytes within the framework of the cell model. We first review analytical results obtained on a mean-field Poisson-Boltzmann level, and then use molecular dynamics…
This review explores the number of mean-field constructions for ions whose structure goes beyond the point-charge description, a representation used in the standard Poisson-Boltzmann equation. The exploration is motivated by a body of…
Kinetic theory describes a dilute monatomic gas using a distribution function $f(q,p,t)$, the expected phase-space density of particles. The distribution function evolves according to the collisionless Boltzmann equation in the high Knudsen…
We introduce an anisotropic mean-field approach for the dynamics of semiflexible polymers under intermediate tension, the force range where a chain is partially extended but not in the asymptotic regime of a nearly straight contour. The…
Equations governing the flow of a polar fluid, with pressure-dependent Newtonian viscosity, through a variable-porosity medium are developed. Averaged equations are obtained using intrinsic volume averaging. A drag function is introduced to…
We study discrete solvent effects on the interaction of two parallel charged surfaces in ionic aqueous solution. These effects are taken into account by adding a bilinear non-local term to the free energy of Poisson-Boltzmann theory. We…
If a thermal gradient is applied along a fluid-solid interface, the fluid experiences a thermo-osmotic force. In steady state this force is balanced by the gradient of the shear stress. Surprisingly, there appears to be no unique…
A transient Poisson-Nernst-Planck system with steric effects is analyzed in a bounded domain with no-flux boundary conditions for the ion concentrations and mixed Dirichlet-Neumann boundary conditions for the electric potential. The steric…
We expand previous work on an inverse approach to Einstein Field Equations where we include fluids with energy flux and consider the vanishing of the anisotropic stress tensor. We consider the approach using warped product spacetimes of…
We propose a nonlocal Poisson-Fermi model for ionic solvent that includes ion size effects and polarization correlations among water molecules in the calculation of electrostatic potential. It includes the previous Poisson-Fermi models as…
Expressions are obtained for force and couple densities and stress tensors in macroscopic models for nematic liquid crystals subjected to electric fields. The coupling between the liquid crystal orientational properties and the electric…
We are concerned with a mixture of Boltzmann and McKean-Vlasov type equations, this means (in probabilistic terms) equations with coefficients depending on the law of the solution itself,and driven by a Poisson point measure with the…