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We consider the nonlinear Poisson-Boltzmann equation in the context of electrostatic models for a biological macromolecule, embedded in a bounded domain containing a solution of an arbitrary number of ionic species which is not necessarily…

Analysis of PDEs · Mathematics 2022-04-26 José A. Iglesias , Svetoslav Nakov

The interfacial tension of a liquid droplet surrounded by another liquid in the presence of microscopic ions is studied as a function of the droplet radius. An analytical expression for the interfacial tension is obtained within a linear…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Joost de Graaf , Jos Zwanikken , Rene van Roij

An accurate force calculation with the Poisson-Boltzmann equation is challenging, as it requires the electric field on the molecular surface. Here, we present a calculation of the electric field on the solute-solvent interface that is exact…

Chemical Physics · Physics 2023-01-13 Ian Addison-Smith , Horacio V. Guzmán , Christopher D. Cooper

A lattice Boltzmann scheme able to model the hydrodynamics of phase separation and two-phase flow is described. Thermodynamic consistency is ensured by introducing a non-ideal pressure tensor directly into the collision operator. We also…

comp-gas · Physics 2009-10-28 Michael R. Swift , W. R. Osborn , J. M. Yeomans

The energy functional, the governing partial differential equation(s) (PDE), and the boundary conditions need to be consistent with each other in a modeling system. In electrolyte solution study, people usually use a free energy form of an…

Soft Condensed Matter · Physics 2017-02-07 Xuejiao Liu , Yu Qiao , Benzhuo Lu

A model of a finite cylindrical ion channel through a phospholipid membrane of width $L$ separating two electrolyte reservoirs is studied. Analytical solution of the Poisson equation is obtained for an arbitrary distribution of ions inside…

Soft Condensed Matter · Physics 2009-11-11 Yan Levin

Electrostatic correlations and fluctuations in ionic systems can be described within an extended Poisson-Boltzmann theory using a Gaussian variational form. The resulting equations are challenging to solve because they require the solution…

Computational Physics · Physics 2015-06-17 Zhenli Xu , A. C. Maggs

The hydrodynamic Burnett equations and the associated transport coefficients are exactly evaluated for generalized inelastic Maxwell models. In those models, the one-particle distribution function obeys the inelastic Boltzmann equation,…

Soft Condensed Matter · Physics 2014-05-07 Nagi Khalil , Vicente Garzó , Andrés Santos

The Ebin-Marsden theory is a powerful geometric framework for many PDEs from fluid dynamics. In this paper we provide a toolbox to apply the Ebin-Marsden approach to stochastic PDEs, combining tools from infinite-dimensional geometry and…

Probability · Mathematics 2023-12-08 Zdzisław Brzeźniak , Mario Maurelli , Alexander Schmeding

Classical theory of the electric double layer is based on the fundamental assumption of a dilute solution of point ions. There are a number of situations such as high applied voltages, high concentration of electrolytes, systems with…

Fluid Dynamics · Physics 2015-06-11 Brian D. Storey , Martin Z. Bazant

In recent works, we proposed a hypothesis that the turbulence in gases could be produced by particles interacting via a potential, and examined the proposed mechanics of turbulence formation in a simple model of two particles for a variety…

Fluid Dynamics · Physics 2024-06-12 Rafail V. Abramov

The standard model for diffuse charge phenomena in colloid science, electrokinetics and biology is the Poisson-Boltzmann mean-field theory, which breaks down for multivalent ions and large surface charge densities due to electrostatic…

Soft Condensed Matter · Physics 2020-02-14 J. Pedro de Souza , Martin Z. Bazant

This study introduces a novel fluctuating lattice Boltzmann (LB) method for simulating viscoelastic fluid flows governed by the Oldroyd-B model. In contrast to conventional LB approaches that explicitly compute the divergence of the polymer…

Fluid Dynamics · Physics 2025-06-17 Juanyong Wang , Xinyue Liu , Lei Wang , Yuan Yu , Yiran Ji

Starting with a microscopic (individual-based) Brownian dynamics model of charged particles (ions), its macroscopic description is derived as a system of partial differential equations that govern the evolution of ion concentrations in…

Computational Physics · Physics 2025-06-25 Jinyuan Zhang , Radek Erban

We study the Poisson-Boltzmann equation in the context of dense charged fluids where steric effects become important. We generalise the lattice gas theory by introducing a Flory-Huggins entropy for ions of differing volumes and then compare…

Soft Condensed Matter · Physics 2015-07-17 A. C. Maggs , R. Podgornik

We consider ionic electrodiffusion in fluids, described by the Nernst-Planck-Navier-Stokes system in bounded domains, in two dimensions, with Dirichlet boundary conditions for the Navier-Stokes and Poisson equations, and blocking (vanishing…

Analysis of PDEs · Mathematics 2018-12-26 Peter Constantin , Mihaela Ignatova

We consider the system of equations describing the flow of incompressible fluids in bounded domain. In the considered setting, the Cauchy stress tensor is a monotone mapping and has asymptotically $(s-1)$-growth with the parameter $s$…

Analysis of PDEs · Mathematics 2022-09-23 Miroslav Buliček , Piotr Gwiazda , Jakub Skrzeczkowski , Jakub Woźnicki

We theoretically investigate an electric-field-driven system of charged spheres as a primitive model of concentrated electrolytes under an applied electric field. First, we provide a unified formulation for the stochastic charge and density…

Soft Condensed Matter · Physics 2025-01-15 Hiroshi Frusawa

We derive an expression for the tensor polarization of a system of massive spin-1 particles in a hydrodynamic framework. Starting from quantum kinetic theory based on the Wigner-function formalism, we employ a modified method of moments…

Nuclear Theory · Physics 2023-03-09 David Wagner , Nora Weickgenannt , Enrico Speranza

The two-dimensional ideal (Euler) fluids can be described by the classical fields of streamfunction, velocity and vorticity and, in an equivalent manner, by a model of discrete point-like vortices interacting in plane by a self-generated…

Fluid Dynamics · Physics 2010-01-05 Florin Spineanu , Madalina Vlad
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