Related papers: Modified Poisson-Boltzmann equations and macroscop…
The paper presents a mean field theory of electrolyte solutions, extending the classical Debye-H\"{u}ckel-Onsager theory to provide a detailed description of the electrical conductivity in strong electrolyte solutions. The theory…
We develop a modified Poisson-Nernst-Planck model which includes both the long-range Coulomb and short-range hard-sphere correlations in its free energy functional such that the model can accurately describe the ion transport in complex…
In this paper within a field-theoretical approach taking into account explicitly a co-solvent with a nonzero dipole and a polarizability tensor, we derive a modified Poisson-Boltzmann equation. Applying the modified Poisson-Boltzmann…
Using the recently developed ``Maximum Entropy'' (or ``least biased'') distribution function to truncate the moment hierarchy arising from kinetic theory, we formulate a far-from-equilibrium macroscopic theory that provides the possibility…
The non-equilibrium contributions to the post-Newtonian hydrodynamic equations are determined from a relaxation-time model of the post-Newtonian Boltzmann equation. The Chapman-Enskog method is used to calculate the non-equilibrium…
We extend our previous study of surface tension of ionic solutions and apply it to the case of acids (and salts) with strong ion-surface interactions. These ion-surface interactions yield a non-linear boundary condition with an effective…
We investigate structural and thermodynamic properties of aqueous dispersions of ionic microgels -- soft colloidal gel particles that exhibit unusual phase behavior. Starting from a coarse-grained model of microgel macroions as charged…
The cell-model and its treatment on the Poisson-Boltzmann level are two important concepts in the theoretical description of charged macromolecules. In this brief contribution to the Proceedings of the NATO-ASI on ``Electrostatic Effects in…
We present a semi-analytical framework to compute the suspension stress in dilute particle-laden non-Newtonian fluids, separating Newtonian and non-Newtonian contributions. The ensemble-averaged stress includes both the particle-induced…
In this paper we derive asymptotically the macroscopic bulk stress of a suspension of small inertial particles in an incompressible Newtonian fluid. We apply the general asymptotic framework to the special case of ellipsoidal particles and…
Thermodynamic properties of charge-stabilised colloidal suspensions are commonly modeled by implementing the mean-field Poisson-Boltzmann (PB) theory within a cell model. This approach models a bulk system by a single macroion, together…
In this paper, on the basis of the Onsager--Wilson theory of strong binary electrolyte solutions we completely work out the solutions of the governing equations (Onsager-Fuoss equations and Poisson equations) for nonequilibrium pair…
A nonlinear Poisson--Boltzmann equation with transmission boundary conditions at the interface between two materials is investigated. The model describes the electrostatic potential generated by a vector of ion concentrations in a periodic…
The Boltzmann equation for $d$-dimensional inelastic Maxwell models is considered to analyze transport properties for monodisperse gas-solid suspensions. The influence of the interstitial gas phase on the dynamics of solid particles is…
We justify the global-in-time validity of Hilbert expansion for the ionic Vlasov-Poisson-Boltzmann system in $\mathbb{R}^3$, a fundamental model describing ion dynamics in dilute collisional plasmas. As the Knudsen number approaches zero,…
A new modified Poisson-Boltzmann equation accounting for the finite size of the ions valid for realistic salt-free concentrated suspensions has been derived, extending the formalism developed for pure salt-free suspensions [Roa et al.,…
We propose a model for the liquid-liquid phase transition observed in osmotic pressure measurements of certain charged lamellae-forming amphiphiles. The model free energy combines mean-field electrostatic and phenomenological…
The energy--momentum tensor and the tensor continuity equation serve as the conservation laws of energy, linear momentum, and angular momentum for a continuous flow. Previously, we derived equations of motion for macroscopic electromagnetic…
Ionic polymer-metal composites consist in a thin film of electro-active polymers (Nafion R for example) sandwiched between two metallic electrodes. They can be used as sensors or actuators. The polymer is saturated with water, which causes…
Recent theoretical work has developed the Hamilton's-principle analog of Lie-Poisson Hamiltonian systems defined on semidirect products. The main theoretical results are twofold: (1) Euler-Poincar\'e equations (the Lagrangian analog of…