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Rechargeable lithium, sodium, and aluminum metal-based batteries are among the most versatile platform for high-energy, cost effective electrochemical energy storage. Non-uniform metal deposition and dendrite formation on the negative…

Materials Science · Physics 2015-01-27 Yingying Lu , Zhengyuan Tu , Lynden Archer

The world is at the cusp of a new era where pivotal importance is being attached to the development of sustainable and high-performance energy storage systems. Potassium-ion batteries are deemed not only as cheap battery candidates, but…

Chemical Physics · Physics 2021-11-12 Kazuki Yoshii , Titus Masese , Minami Kato , Keigo Kubota , Hiroshi Senoh , Masahiro Shikano

Next-generation high-energy-density batteries require ideally stable metal anodes, for which smooth metal deposits during battery recharging are considered a sign of interfacial stability that can ensure high efficiency and long cycle life.…

Materials Science · Physics 2022-01-11 Bingyuan Ma , Peng Bai

Future lithium-based batteries are expected to use solid electrolytes to achieve higher energy density and fast charge capabilities. The majority of solid electrolytes are thermodynamically unstable against layered oxide cathodes. Here, the…

Solid-state batteries (SSBs) are promising next-generation batteries due to their high energy density and enhanced thermal stability and safety. However, their sluggish kinetics and transport at room temperature results in high internal…

Applied Physics · Physics 2024-11-18 Buyi Zhang , Divya Chalise , Yuqiang Zeng , Sumanjeet Kaur , Chris Dames , Ravi S. Prasher

Density-functional-theory (DFT) calculations have been performed on the Li-Si and Li-Ge systems. Lithiated Si and Ge, including their metastable phases, play an important technological r\^ole as Li-ion battery (LIB) anodes. The calculations…

Materials Science · Physics 2015-06-18 Andrew J. Morris , C. P. Grey , C. J Pickard

We report a neutral salt water based battery which uses p-type and n-type solution processed polymer films as the cathode and the anode of the cell. The specific capacity of the electrodes (approximately 30 mAh cm-3) is achieved via…

Lithium-sulfur technology garners significant interest due to sulfur's higher specific capacity, cost-effectiveness, and environmentally friendly aspects. However, sulfur's insulating nature and poor cycle life hinder practical application.…

Materials Science · Physics 2024-09-06 Mariam Ezzedine , Fatme Jardali , Ileana Florea , Costel-Sorin Cojocaru

Enhancing the ion conduction in solid electrolytes is critically important for the development of high-performance all-solid-state lithium-ion batteries (LIBs). Lithium thiophosphates are among the most promising solid electrolytes, as they…

Materials Science · Physics 2024-01-11 Zhimin Chen , Tao Du , N. M. Anoop Krishnan , Yuanzheng Yue , Morten M. Smedskjaer

Blend solid polymer electrolyte based on PEO, PVP complexed with lithium LiBOB were synthesized by solution cast technique and impact of LiBOB on the morphology, structure, and electrochemical properties is examined. The XRD and FESEM…

Materials Science · Physics 2018-07-05 Anil Arya , Mohd Sadiq , A. L. Sharma

The performance of modern lithium-sulfur (Li/S) battery systems critically depends on the electrolyte and solvent compositions. For fundamental molecular insights and rational guidance of experimental developments, efficient and…

Management of heat during charging and discharging of Li-ion batteries is critical for their safety, reliability, and performance. Understanding the thermal conductivity of the materials comprising batteries is crucial for controlling the…

Materials Science · Physics 2021-03-17 Zhe Cheng , Beniamin Zahiri , Xiaoyang Ji , Chen Chen , Darshan Chalise , Paul V. Braun , David G. Cahill

Recently some critical problems and challenges have been exposed, hindering the development and practical application of SSLBs, such as the low room temperature ionic conductivity of solid electrolyte, the risk of short circuit caused by…

Materials Science · Physics 2023-08-01 L. J. Zhang

Fabricating electrochemical energy storage devices demands significant energy for drying cell components to ensure optimal performance. The development of new, water-tolerant materials would represent a tremendous advance in cost savings…

Phosphorus has received recent attention in the context of high-capacity and high-rate anodes for lithium and sodium-ion batteries. Here, we present a first principles structure prediction study combined with NMR calculations which gives us…

Materials Science · Physics 2015-10-13 Martin Mayo , Kent J. Griffith , Chris J. Pickard , Andrew J. Morris

Lithium fluoride (LiF) is a critical component for stabilizing lithium metal anode and high-voltage cathodes towards the next-generation high-energy-density lithium batteries. Recent modeling study reported the formation of wurtzite LiF…

Materials Science · Physics 2025-04-21 Boyuan Xu , Liyi Bai , Shenzhen Xu , Qisheng Wu

Highly conductive solid electrolytes are one key component for the development of safe and high-power all-solid-state batteries. Enormous progress has been achieved in the field of lithium solid electrolytes. Meanwhile, their ion…

Materials Science · Physics 2017-12-14 Marc Duchardt , Uwe Ruschewitz , Stefanie Dehnen , Bernhard Roling

In solid-state batteries (SSBs), improving the physical contact at the electrode-electrolyte interface is essential for achieving better performance and durability. On the one hand, it is necessary to look for solid-state electrolytes…

Materials Science · Physics 2024-10-22 Qifan Yang , Jing Xu , Xiao Fu , Jingchen Lian , Liqi Wang , Xuhe Gong , Zibin Wang , Ruijuan Xiao , Hong Li

In order to replace the conventional liquid electrolytes by solid electrolytes, high room temperature ionic conductivity is required. To achieve such high ionic conductivity, the series Li7-3xGaxLa3Zr1.9Ge0.1O12 was prepared by solid-state…

Materials Science · Physics 2024-05-09 Muktai Aote , A. V. Deshpande , Anuj Khapekar , Kajal Parchake

A crucial ingredient in lithium (Li) and sodium (Na)-ion batteries (LIBs and NIBs) is the electrolytes. The use of Li-metal (Na-metal) as anode in liquid electrolyte LIBs (NIBs) is constrained by several issues including thermal runway and…

Materials Science · Physics 2022-12-14 Juefan Wang , Abhishek A. Panchal , Gopalakrishnan Sai Gautam , Pieremanuele Canepa