Related papers: H2CS deuteration maps towards the pre-stellar core…
We have observed the deuterated gas in the high-mass star formation region IRAS 05345+3157 at high-angular resolution, in order to determine the morphology and the nature of such gas. We have mapped the N2H+ (1-0) line with the Plateau de…
We investigate deuterium chemistry coupled with the nuclear spin-state chemistry of H$_2$ and H$_3^+$ in protoplanetary disks. Multiple paths of deuterium fractionation are found; exchange reactions with D atoms, such as HCO$^+$ + D, are…
Disentangling the different stages of the star-formation process, in particular in the high-mass regime, is a challenge in astrophysics. Chemical clocks could help alleviating this problem, but their evolution strongly depends on many…
[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…
Context: The $^{15}$N fractionation has been observed to show large variations among astrophysical sources, depending both on the type of target and on the molecular tracer used. These variations cannot be reproduced by the current chemical…
Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply…
The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…
We have undertaken a survey of N2H+ and N2D+ towards 31 low-mass starless cores using the IRAM 30m telescope. Our main objective has been to determine the abundance ratio of N2D+ and N2H+ towards the nuclei of these cores and thus to obtain…
Pre-stellar cores are the first steps in the process of star and planet formation. However, the dynamical and chemical evolution of pre-stellar cores is still not well understood. We aim at estimating the central density of the pre-stellar…
Pre-stellar cores represent the earliest stage of the star- and planet-formation process. By characterizing the physical and chemical structure of these cores we can establish the initial conditions for star and planet formation and…
Our understanding of the physical and chemical structure of pre-stellar cores, the simplest star-forming sites, has significantly improved since the last IAU Symposium on Astrochemistry (South Korea, 1999). Research done over these years…
UltraCompact HII regions are signposts of high mass star formation. Since high-mass star formation occurs in clusters, one expects to find even earlier phases of massive star formation in the vicinity of UltraCompact HII regions. Here, we…
We present the results of our studies of deuterated molecules (DCN, DNC, DCO$^+$, N$_2$D$^+$ and NH$_2$D) in regions of high-mass star formation, which include a survey of such regions with the 20-m Onsala radio telescope and mapping of…
We have carried out calculations of ionization equilibrium and deuterium fractionation for conditions appropriate to a completely depleted, low mass pre--protostellar core, where heavy elements such as C, N, and O have vanished from the gas…
The abundances of deuterated molecules with respect to their main isotopologue counterparts have been determined to be orders of magnitude higher than expected from the cosmic abundance of deuterium relative to hydrogen. The increasing…
Deuterated molecules and their molecular D/H-ratios (RD(D)) are important diagnostic tools to study the physical conditions of star-forming regions. The degree of deuteration, RD(D), can be significantly enhanced over the elemental…
We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…
The initial stage of star formation is a complex area study because of its high density and low temperature. Under such conditions, many molecules become depleted from the gas phase by freezing out onto dust grains. However, the deuterated…
Isotopic ratios have been used as chemical diagnostics to investigate the origin of the material in the Solar System. We have determined the HCN, HNC, and N2H+ isotopic ratios and the chemical age in a large sample of 23 starless cores…
High degrees of deuterium fractionation are commonly found in cold prestellar cores and in the envelopes around young protostars. As it brings strong constraints to chemical models, deuterium chemistry is often used to infer core history or…